Recent advances in gas storage and separation using metal–organic frameworks

Energy resources and their utilization intimately relate to sustainable development. In attaining sustainable development, increasing the energy efficiencies of processes utilizing sustainable energy resources plays an important role. The utilization of renewable energy offers a wide range of exceptional benefits. There is also a link between exergy and sustainable development. A sustainable energy system may be regarded as a cost-efficient, reliable, and environmentally friendly energy system that effectively utilizes local resources and networks. Exergy analysis has been widely used in the design, simulation and performance evaluation of energy systems. The present study comprehensively reviews exergetic analysis and performance evaluation of a wide range of renewable energy resources (RERs) for the first time to the best of the author's knowledge. In this regard, general relations (i.e., energy, exergy, entropy and exergy balance equations along with exergy efficiency, exergetic improvement potential rate and some thermodynamic parameters, such as fuel depletion ratio, relative irreversibility, productivity lack and exergetic factor) used in the analysis are presented first. Next, exergetically analyzed and evaluated RERs include (a) solar energy systems; (a1) solar collector applications such as solar water heating systems, solar space heating and cooling, solar refrigeration, solar cookers, industrial process heat, solar desalination systems and solar thermal power plants), (a2) photovoltaics (PVs) and (a3) hybrid (PV/thermal) solar collectors, (b) wind energy systems, (c) geothermal energy systems, (c1) direct utilization (district heating, geothermal or ground-source heat pumps, greenhouses and drying) and (c2) indirect utilization (geothermal power plants), (d) biomass, (e) other renewable energy systems, and (f) country based RERs. Studies conducted on these RERs are then compared with the previously ones in tabulated forms, while the Grassmann (or exergy flow) diagrams, which are a very useful representation of exergy flows and losses, for some RERs are given. Finally, the conclusions are presented. It is expected that this comprehensive study will be very beneficial to everyone involved or interested in the exergetic design, simulation, analysis and performance assessment of RERs.

A key review on exergetic analysis and assessment of renewable energy resources for a sustainable future

A state-of-the-art review is presented of the different technologies that are available to deliver refrigeration from solar energy. The review covers solar electric, solar thermal and some new emerging technologies. The solar thermal systems include thermo-mechanical, absorption, adsorption and desiccant solutions. A comparison is made between the different solutions both from the point of view of energy efficiency and economic feasibility. Solar electric and thermo-mechanical systems appear to be more expensive than thermal sorption systems. Absorption and adsorption are comparable in terms of performance but adsorption chillers are more expensive and bulkier than absorption chillers. The total cost of a single-effect LiBr–water absorption system is estimated to be the lowest.

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Solar refrigeration options – a state-of-the-art review

Adsorption refrigeration- : An efficient way to make good use of waste heat and solar energy

Sorption thermal storage for solar energy

Performance limitations of adsorption cycles for solar cooling

The history of adsorption cycles and the basic cycle are briefly described. The major refrigerants used are water, methanol, and ammonia. ‘Physical’ adsorbents include zeolites, active carbons, silica gels, and salts in mesoporous silica or alumina. Means of improving heat and mass transfer in both low (water, methanol) and high (ammonia) pressure systems are discussed. These include the use of conventional adsorbents that have been consolidated and more novel materials and approaches. There are a range of new thermodynamic cycles under development which have the varying goals of either using low temperature driving heat or maximizing the energy efficiency when using high temperature heat. In all machines there is a design compromise to be made between compactness (related to capital cost) and energy efficiency.

Review of trends in solid sorption refrigeration and heat pumping technology

A comparison of thermodynamic performances of sorption systems (liquid absorption, adsorption, ammonia salts and metal hydrides) is carried out for typical applications (deep-freezing, ice making, air-conditioning and heat pumping) with either air-cooled or water-cooled heat sink. The results are given in terms of cooling coefficient of performance (COP) (heating COP or coefficient of amplification (COA) for the heat pump), cooling (heating) power versus reactor volume or weight and thermodynamic efficiency. LiBr–water systems show the best results for air-conditioning except when small units are required (metal hydride systems lead to more compact units). Other systems, however, show better results for other applications (chemical reaction with ammonia salts for deep-freezing, adsorption for heat pumping).

Thermodynamic based comparison of sorption systems for cooling and heat pumping

A thermodynamic cycle model is used to select an optimum adsorbent-refrigerant pair in respect of a chosen figure of merit that could be the cooling production (MJ m(-3)), the heating production (MJ m(-3)) or the coefficient of performance (COP). This model is based mainly on the adsorption equilibrium equations of the adsorbent-refrigerant pair and heat flows. The simulation results of 26 various activated carbon-ammonia pairs for three cycles (single bed, two-bed and infinite number of beds) are presented at typical conditions for ice making, air conditioning and heat pumping applications. The driving temperature varies from 80 degrees C to 200 degrees C. The carbon absorbents investigated are mainly coconut shell and coal based types in multiple forms: monolithic, granular, compacted granular, fibre, compacted fibre, cloth, compacted cloth and powder. Considering a two-bed cycle, the best thermal performances based on power density are obtained with the monolithic carbon KOH-AC, with a driving temperature of 100 degrees C; the cooling production is about 66 MJ m(-3) (COP = 0.45) and 151 MJ m(-3) (COP = 0.61) for ice making and air conditioning respectively; the heating production is about 236 MJ m(-3) (COP = 1.50).

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Robert E. Critoph

Papers

Performance limitations of adsorption cycles for solar cooling

Review of trends in solid sorption refrigeration and heat pumping technology

Thermodynamic based comparison of sorption systems for cooling and heat pumping

Carbon-ammonia pairs for adsorption refrigeration applications: ice making, air conditioning and heat pumping

The use of psychrometric charts for the optimisation of a thermal swing desiccant wheel