Kenji Sumida, David L. Rogow, Jarad A. Mason, Thomas M. McDonald, Eric D. Bloch, Zoey R. Herm, Tae-Hyun Bae, Jeffrey R. Long

Carbon Dioxide Capture in Metal–Organic Frameworks

Post-combustion CO2 capture from the flue gas is one of the key technology options to reduce greenhouse gases, because this can be potentially retrofitted to the existing fleet of coal-fired power stations. Adsorption processes using solid sorbents capable of capturing CO2 from flue gas streams have shown many potential advantages, compared to other conventional CO2 capture using aqueous amine solvents. In view of this, in the past few years, several research groups have been involved in the development of new solid sorbents for CO2 capture from flue gas with superior performance and desired economics. A variety of promising sorbents such as activated carbonaceous materials, microporous/mesoporous silica or zeolites, carbonates, and polymeric resins loaded with or without nitrogen functionality for the removal of CO2 from the flue gas streams have been reviewed. Different methods of impregnating functional groups, including grafting techniques and modifying the support materials, have been discussed to en...

Post-Combustion CO2 Capture Using Solid Sorbents: A Review

Carbon dioxide (CO2) capture using solid sorbents has been recognized as a very promising technology that has attracted intense attention from both academic and industrial fields in the last decade. It is astonishing that around 2000 papers have been published from 2011 to 2014 alone, which is less than three years after our first review paper in this journal on solid CO2 sorbents was published. In this short period, much progress has been made and the major research focus has more or less changed. Therefore, we feel that it is necessary to give a timely update on solid CO2 capture materials, although we still have to keep some important literature results published in the past years so as to keep the good continuity. We believe this work will benefit researchers working in both academic and industrial areas. In this paper, we still organize the CO2 sorbents according to their working temperatures by classifying them as such: (1) low-temperature ( 400 °C). Since the sorption capacity, kinetics, recycling stability and cost are important parameters when evaluating a sorbent, these features will be carefully considered and discussed. In addition, due to the huge amounts of cost-effective CO2 sorbents demanded and the importance of waste resources, solid CO2 sorbents prepared from waste resources and their performance are reviewed. Finally, the techno-economic assessments of various CO2 sorbents and technologies in real applications are briefly discussed.

Recent advances in solid sorbents for CO2 capture and new development trends

A review of separation technologies in current and future biorefineries

Food and Agriculture Organization (FAO) The Food and Agriculture Organization (FAO), established in 1945, is a UN specialized agency that provides global data and expertise on agri­ culture and nutrition, fisheries, forestry, and other food and agriculture– related issues. FAO is the UN system’s largest autonomous agency, with headquarters in Rome, 78 country offices and 15 regional, sub–regional, and liaison offices, including one located in Washington, D.C. FAO’s highest policy–making body, the biennial General Conference, comprises all 183 FAO member countries plus the European Commission. The General Conference determines FAO policy and approves FAO’s reg­ ular program of work and budget. The 31st Conference, meeting in November 1999, re–elected Director–General Jacques Diouf (Senegal) to a second six–year term through December 2005. Each biennial Confer­ ence elects a 49–member Council that meets semi–annually to make rec­ ommendations to the General Conference on budget and policy issues. The North America region, which comprises the United States and Can­ ada, is allocated two seats on the Council and one seat each on FAO’s Program, Finance, and Constitutional and Legal Matters (CCLM) Com­ mittees. The United States holds the North American seats on the Finance and Joint Staff Pension Committees through December 2003. Canada holds the North American seat on the CCLM and Program Committees through December 2003. The United States participated at the World Food Summit: Five Years Later meeting held at FAO headquarters June 10–13, 2002, to discuss progress towards attaining the 1996 World Food Summit target of reduc­ ing the world’s number of hungry and malnourished by half by 2015. The United States presented new initiatives to improve agriculture productivity as a significant contribution toward meeting that goal. U.S. Secretary of Agriculture Ann Veneman, leading the U.S. delegation, joined other min­ isters and heads of state and government in adopting a Declaration, “The International Alliance Against Hunger,” which reiterated the goals of the 1996 World Food Summit and stated, inter alia, “we are committed to

https://www.jstage.jst.go.jp/article/jve1997/7/2/7_2_107/_pdf

Food and Agriculture Organization (FAO) ホームページの活用法

Crosslinking of chitosan membranes using glutaraldehyde: Effect on ion permeability and water absorption

Copper, mercury and chromium adsorption on natural and crosslinked chitosan films: An XPS investigation of mechanism

Dynamic and static adsorption and desorption of Hg(II) ions on chitosan membranes and spheres.

Interaction of natural and crosslinked chitosan membranes with Hg(II) ions

Adsorption may be a potentially attractive alternative to capturing CO2 from stationary sources in the context of Carbon Capture and Sequestration (CCS) technologies. Activated carbon and zeolites are state-of-art adsorbents which may be used for CO2 adsorption, however physisorption alone tends to be insignificant at high temperatures. In the present work, commercial adsorbents have been impregnated with monoethanolamine (MEA) and triethanolamine (TEA) in order to investigate the effect of the modified surface chemistry on CO2 adsorption, especially above room temperature. Adsorption isotherms for CO2, N2 and CH4 were measured in a gravimetrically system in the pressure range of UHV to 10 bar, at 298 and 348 K for activated carbon and zeolite 13X supports. The adsorbed concentration of CO2 was significantly higher than those of CH4 and N2 for both adsorbents in the whole pressure range studied, zeolite 13X showing a remarkable affinity for CO2 at very low pressures. However, at 348 K, the adsorbed concentration of CO2 decreases significantly. The supports impregnated with concentrated amine solutions and dried in air suffered a detrimental effect on the textural properties, although CO2 uptake became much less susceptible to temperature increase. Impregnations carried out with dilute solution followed by drying in inert atmosphere yielded materials with very similar textural characteristics as compared to the parent support. CO2 isotherms in such materials showed a significant change with similar capacities at 348 K as compared to the original support at 298 K in the case of activated carbons. The impregnated zeolite showed a decrease in adsorbed phase concentration in low pressures for a given temperature, but the adsorbed amount also seemed to be less affected by temperature. These results are promising and indicate that CO2 adsorption may be enhanced despite high process temperatures (e.g. 348 K), if convenient impregnation and drying methods are applied.

Rodrigo Silveira Vieira

Papers

Crosslinking of chitosan membranes using glutaraldehyde: Effect on ion permeability and water absorption

Copper, mercury and chromium adsorption on natural and crosslinked chitosan films: An XPS investigation of mechanism

Dynamic and static adsorption and desorption of Hg(II) ions on chitosan membranes and spheres.

Interaction of natural and crosslinked chitosan membranes with Hg(II) ions

Adsorption of CO2 on nitrogen-enriched activated carbon and zeolite 13X