Plasmonic colours are structural colours that emerge from resonant interactions between light and metallic nanostructures. The engineering of plasmonic colours is a promising, rapidly emerging research field that could have a large technological impact. We highlight basic properties of plasmonic colours and recent nanofabrication developments, comparing technology-performance indicators for traditional and nanophotonic colour technologies. The structures of interest include diffraction gratings, nanoaperture arrays, thin films, and multilayers and structures that support Mie resonances and whispering-gallery modes. We discuss plasmonic colour nanotechnology based on localized surface plasmon resonances, such as gap plasmons and hybridized disk–hole plasmons, which allow for colour printing with sub-diffraction resolution. We also address a range of fabrication approaches that enable large-area printing and nanoscale lithography compatible with complementary metal-oxide semiconductor technologies, including nanoimprint lithography and self-assembly. Finally, we review recent developments in dynamically reconfigurable plasmonic colours and in the laser-induced post-processing of plasmonic colour surfaces. Plasmonic colours can be used to colour large surfaces, can be mass-produced and dynamically reconfigured, and can provide sub-diffraction resolution. In this Review, basic properties of plasmonic colours, different platforms supporting them and recent developments in the field are discussed.

Plasmonic colour generation

The ability to tune material properties using gating by electric fields is at the heart of modern electronic technology. It is also a driving force behind recent advances in two-dimensional systems, such as the observation of gate electric-field-induced superconductivity and metal-insulator transitions. Here, we describe an ionic field-effect transistor (termed an iFET), in which gate-controlled Li ion intercalation modulates the material properties of layered crystals of 1T-TaS2. The strong charge doping induced by the tunable ion intercalation alters the energetics of various charge-ordered states in 1T-TaS2 and produces a series of phase transitions in thin-flake samples with reduced dimensionality. We find that the charge-density wave states in 1T-TaS2 collapse in the two-dimensional limit at critical thicknesses. Meanwhile, at low temperatures, the ionic gating induces multiple phase transitions from Mott-insulator to metal in 1T-TaS2 thin flakes, with five orders of magnitude modulation in resistance, and superconductivity emerges in a textured charge-density wave state induced by ionic gating. Our method of gate-controlled intercalation opens up possibilities in searching for novel states of matter in the extreme charge-carrier-concentration limit.

http://absimage.aps.org/image/MAR15/MWS_MAR15-2014-020259.pdf

Gate-tunable phase transitions in thin flakes of 1T-TaS$_{2}$

Publisher Summary This chapter updates former reviews on locust polyphenism and also discusses recent findings. Over 200 articles were published in scientific journals on various aspects of locust phase polyphenism, markedly advancing the knowledge of the subject. However, the chapter refers to the older literature when background information is necessary for complementary and better treatment, or because of historical importance. Some of the recent publications report contradictory findings, and such contradictions have been emphasized in the chapter. Substantial progress has been made in the study of locust phase polyphenism over the past several years. The topic has well and truly emerged from the realms of applied entomology to assume a prominent position in the modern study of phenotypic plasticity, whereby adaptive phenotypes arise during development as a result of plastic interactions between genes and the environment. The study of behavioral gregarization has seen some of the most far-reaching progress. The involvement of locust-emitted volatiles in aspects of phase biology has generated substantial research and its fair share of productive controversy. It has been especially heartening to see that some of the major areas of controversy, such as the role of phenylacetonitrile, appear to have been at least partially resolved during the past year. New genetic resources also offer a solution to a more prosaic problem in locust research. There has been a growing realization that some of the differences reported between laboratories in aspects of phase polyphenism most likely reflect effects of rearing locusts in long-term culture in the laboratory.

Locust Phase Polyphenism: An Update

How common is speciation-with-gene-flow? How much does gene flow impact on speciation? To answer questions like these requires understanding of the common obstacles to evolving reproductive isolation in the face of gene flow and the factors that favour this crucial step. We provide a common framework for the ways in which gene flow opposes speciation and the potential conditions that may ease divergence. This framework is centred on the challenge shared by most scenarios of speciation-with-gene-flow, i.e. the need for coupling among different components of reproductive isolation. Using this structure, we review and compare the factors favouring speciation with the intention of providing a more integrated picture of speciation-with-gene-flow.

https://onlinelibrary.wiley.com/doi/pdf/10.1111/j.1365-294X.2011.05350.x

A framework for comparing processes of speciation in the presence of gene flow.

Solar-thermal desalination (STD) is a potentially low-cost, sustainable approach for providing high-quality fresh water in the absence of water and energy infrastructures. Despite recent efforts to advance STD by improving heat-absorbing materials and system designs, the best strategies for maximizing STD performance remain uncertain. To address this problem, we identify three major steps in distillation-based STD: (i) light-to-heat energy conversion, (ii) thermal vapor generation, and (iii) conversion of vapor to water via condensation. Using specific water productivity as a quantitative metric for energy efficiency, we show that efficient recovery of the latent heat of condensation is critical for STD performance enhancement, because solar vapor generation has already been pushed toward its performance limit. We also demonstrate that STD cannot compete with photovoltaic reverse osmosis desalination in energy efficiency. We conclude by emphasizing the importance of factors other than energy efficiency, including cost, ease of maintenance, and applicability to hypersaline waters.

/pdf/pathways-and-challenges-for-efficient-solar-thermal-5enc3oewet.pdf

Pathways and challenges for efficient solar-thermal desalination

In the nearest decades, the rapidly increasing demand of wireless connectivity has resulted in the ubiquitous deployment of wireless systems as well as heavily congested wireless spectrum. Owing to the various inherent advantages, such as spectral and bandwidth relief, no healthy concern, high security, low cost, and low interference with Radio Frequency (RF) waves, visible light communication (VLC) has been an emerging optical wireless data transmission approach that can act as a good complement to and substitute for Radio Frequency. How to achieve a high-speed data transmission is a key problem to be solved in the VLC system. This review mainly focuses on the enabling technologies for high-speed VLC systems, including novel transmitter architectures, blue filters and advanced modulation, and equalization technologies. And the inherent advantages, potential applications, and some issues of VLC that need further study are presented as well. Finally, a comprehensive survey on the recent developments and the key contributions by research groups involved in the field of high-speed VLC is provided.

High-Speed Visible Light Communications: Enabling Technologies and State of the Art

Use of MODIS data to monitor the oriental migratory locust plague

Architecturally integrated solar thermal technologies such as solar water heaters and solar thermoelectric generators (STEGs) rely on spectrally selective solar absorbers. These solar absorbers need to have simultaneous high solar absorptivity (α) and low thermal emissivity (e), which always makes them look dark blue or black and so blocks architectural integrated solar applications. A colorful appearance should be taken into account for integration into architectural applications. Herein, colored absorbers with a TiNxOy absorbing layer and a TiO2/Si3N4/SiO2 dielectric stack are elaborately designed and can be fabricated with only two targets, Ti and Si, by using reactive magnetron sputtering. Both the theoretical and experimental results show that the color can be tuned a huge amount, while keeping solar absorptivity higher than 95% and thermal emissivity lower than 5%. The highest absorptivity and energy efficiency (α/e) values are 97.6% and 27.2, respectively. These materials can also be fabricated onto thermoelectric generators to demonstrate the conversion of solar energy into electricity. The open circuit voltage dramatically increases from 171 mV to 523 mV (3.1 times) when using the absorbers. Additionally, the colored solar absorbers can be deposited onto most types of substrate, even flexible substrates. They can simultaneously satisfy the aesthetic requirements and excellent energy performance required for architecturally integrated solar thermal and thermoelectric applications, as well as applications in other fields.

High performance colored selective absorbers for architecturally integrated solar applications

In this paper, a three-layered sandwiched metamaterial is proposed to achieve giant and broadband asymmetric transmission of circularly polarized waves at the near-infrared communication band. The metamaterial consists of two layers of identical 45° tilted chiral S-shaped metasurfaces sandwiched with a subwavelength metallic grating. Based on the delicate combination of broadband polarization conversion and a cavity-enhanced effect, the asymmetric parameter can reach a maximum value of 0.87 and over 0.6 in a wide range from 1.2 to 2.0 μm, which has not been found in previous reports. Furthermore, a perfect robustness to misalignments is obtained as the effect originated from function-independent cascading cavities, which effectively reduce the requirement of alignment precision in layer-by-layer photolithography processes. The proposed nanostructure has a great potential to be used as a circular polarization rotator or diode-like device in optical communication systems.

Giant and broadband circular asymmetric transmission based on two cascading polarization conversion cavities

In this paper, one kind of helix-like chiral metamaterial which can be realized by multiple conventional lithography or electron beam lithographic techniques is proposed to have a broadband bianisotropic optical response analogous to helical metamaterials. On the basis of twisted metamaterials, via tailoring the relative orientation within the lattice, the anisotropy of arcs is converted into magneto-electric coupling of closely spaced arc pairs, which leads to a broad bianisotropic optical response. By connecting the adjacent upper and lower arcs, the coupling of metasurface pairs is transformed into the coupling of the three-dimensional inclusions, and provides a much broader and higher bianisotropic optical response. For only a four-layer helix-like metamaterial, the maximum extinction ratio can reach 19.7. The operation band is in the wavelength range of 4.69 μm to 8.98 μm with an average extinction ratio of 6.9. And the transmittance for selective polarization is above 0.8 in the entire operation band. Such a structure is a promising candidate for integratable and scalable broadband circular polarizers, especially it has great potential to act as a broadband circular micropolarizer in the field of the full-Stokes division of focal plane polarimeters.

Ruonan Ji

Papers

High-Speed Visible Light Communications: Enabling Technologies and State of the Art

Use of MODIS data to monitor the oriental migratory locust plague

High performance colored selective absorbers for architecturally integrated solar applications

Giant and broadband circular asymmetric transmission based on two cascading polarization conversion cavities

Broadband circular polarizers constructed using helix-like chiral metamaterials