Mechanical alloying (MA) is a solid-state powder processng technique involving repeated welding, fracturing, and rewelding of powder particles in a high-energy ball mill. Originally developed to produce oxide-dispersion strengthened (ODS) nickel- and iron-base superalloys for applications in the aerospace industry, MA has now been shown to be capable of synthesizing a variety of equilibrium and non-equilibrium alloy phases starting from blended elemental or prealloyed powders. The non-equilibrium phases synthesized include supersaturated solid solutions, metastable crystalline and quasicrystalline phases, nanostructures, and amorphous alloys. Recent advances in these areas and also on disordering of ordered intermetallics and mechanochemical synthesis of materials have been critically reviewed after discussing the process and process variables involved in MA. The often vexing problem of powder contamination has been analyzed and methods have been suggested to avoid/minimize it. The present understanding of the modeling of the MA process has also been discussed. The present and potential applications of MA are described. Wherever possible, comparisons have been made on the product phases obtained by MA with those of rapid solidification processing, another non-equilibrium processing technique.

Mechanical Alloying And Milling

In the present review we try to give a comprehensive and most up to date view to the field, with an emphasis on the currently most investigated anodic TiO2 nanotube arrays. We will first give an overview of different synthesis approaches to produce TiO2 nanotubes and TiO2 nanotube arrays, and then deal with physical and chemical properties of TiO2 nanotubes and techniques to modify them. Finally, we will provide an overview of the most explored and prospective applications of nanotubular TiO2.

One-dimensional titanium dioxide nanomaterials: nanotubes.

Texture evolution in equal-channel angular extrusion

The evolution of microstructure and texture during cold rolling of commercial-purity titanium (CP-Ti) was studied with particular reference to deformation twinning and dislocation slip. For low to intermediate deformation up to 40% in thickness reduction, the external strain was accommodated by slip and deformation twinning. In this stage, both compressive ( { 1 1 2 ¯ 2 } 〈 1 1 2 ¯ 3 ¯ 〉 ) and tensile ( { 1 0 1 ¯ 2 } 〈 1 0 1 ¯ 1 ¯ 〉 ) twins, as well as, secondary twins and tertiary twins were activated in the grains of favorable orientation, and this resulted in a heterogeneous microstructure in which grains were refined in local areas. For heavy deformation, between 60 and 90%, slip overrode twinning and shear bands developed. The crystal texture of deformed specimens was weakened by twinning but was strengthened by slip, resulting in a split-basal texture in heavily deformed specimens.

Effect of deformation twinning on microstructure and texture evolution during cold rolling of CP-titanium

Current status of materials development of nuclear fuel cladding tubes for light water reactors

Effects of grain shape and texture on the yield strength anisotropy of Al-Li alloy sheet

The effects of process control agents on mechanical alloying mechanisms in the TiAl system

Microstructures and strength of variously heat treated eutectoid steel were evaluated by magnetic property measurements. Isothermal transformation, continuous cooling or spheroidization heat treatment was performed to produce various microstructures. Microstructural parameters (phase, pearlite interlamellar spacing), mechanical properties (fracture strength) and magnetic parameters (coercivity, remanence, hysteresis loss, saturation magnetization) were measured to investigate the relationships among these parameters. Coercivity and remanence were observed to be high in order of martensite, pearlite and ferrite phase. The linear decrease of coercivity and remanence with the interlamellar spacing and the linear increase of those with fracture strength of pearlitic eutectoid steel were found. Coercivity and remanence were suggested as potential magnetic parameters for discriminating phases and quantitatively assessing the pearlite interlamellar spacing as well as strength of eutectoid steel.

Magnetic Evaluation of Microstructures and Strength of Eutectoid Steel

Effect of Mo on recrystallization characteristics of Zr-Nb-(Sn)-Mo experimental alloys

Highly ordered TiO2 nanotube arrays were prepared using a self-templating multi-step anodic oxidation process in a fluoride-containing electrolyte. The microstructures, chemical compositions, and phases of the self-organized TiO2 nanotube arrays were analyzed by FESEM, XPS, and XRD, respectively. Hexagonal packing density in TiO2 nanotube arrays significantly improved after the the multi-step anodic oxidation. The area densities of the hexagonal TiO2 nanotube arrays increased approximately 3 times from the first to second step in the anodic oxidation steps process (4.9 μm−2 to 16.4 μm−2), but there was no difference between the second and third step (16.4 μm−2 to 16.0 μm−2). The as-anodized TiO2 nanotube array had an amorphous structure and it transformed to an anatase phase during the annealing process at 450 °C for 1 h. The as-anodized TiO2 nanotube arrays adsorbed the fluoride, hydrocarbon groups (CH), hydroxyl groups (OH, C-OH), and carboxyl groups (O = C-OH) on their surfaces.

S.I. Kwun

Papers

Effects of grain shape and texture on the yield strength anisotropy of Al-Li alloy sheet

The effects of process control agents on mechanical alloying mechanisms in the TiAl system

Magnetic Evaluation of Microstructures and Strength of Eutectoid Steel

Effect of Mo on recrystallization characteristics of Zr-Nb-(Sn)-Mo experimental alloys

Highly Ordered Self-Organized TiO2 Nanotube Arrays Prepared by a Multi-Step Anodic Oxidation Process