Porous silicon biosensor: current status.

The red shift and the broadening of the Raman signal from microcrystalline silicon films is described in terms of a relaxation in the q-vector selection rule for the excitation of the Raman active optical phonons. The relationship between width and shift calculated from the known dispersion relation in c-Si is in good agreement with available data. An increase in the decay rate of the optical phonons predicted on the basis of the same model is confirmed experimentally.

The one phonon raman spectrum in microcrystalline silicon

Core-shell Fe3O4 polydopamine nanoparticles as sorbent for magnetic dispersive solid-phase extraction of copper from food samples.

A course on the emerging topic “Smart Sensors and Internet of Things (IoT)” has been designed, developed, and delivered from 21st March 2016 to 31st March 2016 in the Department of Electrical Engineering, Jamia Millia Islamia (Central University), New Delhi-110025, India. This course was organized under a program initiated by the Government of India, entitled “Global Initiative of Academic Networks” for higher education. The basic objective is to bring the internationally and nationally acclaimed scientists on a single platform to motivate young minds of India so that India’s scientific and technological capacity reach global excellence. The course was designed to develop the technical skills for the students, the researchers, the engineers, and the faculties, who desire to address some of the issues faced by the people around the world in the fields of smart sensors and IoTs with applications in smart homes, smart cities, smart grids, smart environment, smart transport, and so on. The assessment of the course by the participants shows extreme usefulness of it.

Smart Sensors and Internet of Things: A Postgraduate Paper

The use of porous silicon (PS) as an electrochemical biosensor has been reviewed. For electrochemical biosensing, the enhanced surface area is not the only advantage of using PS. In fact, depending on the transduction mechanisms, various issues like modulation of electric field lines through the pores and its interface with the biomolecules and ions of the analytes, nature of PS–metal contacts, orientation of the molecules within the pores and modification of the effective spring constant of the structure leading to a change in the resonant frequency have significant impact on sensitivity, reproducibility and longevity. In this review, we provide a critical assessment of the various factors which are actually responsible for enhanced performance of PS electrochemical biosensors. Formation procedures of PS for electrochemical biosensing have been mentioned. The mechanism of surface modification and derivatization has been briefly discussed. The contact formation techniques have been outlined. Four different categories of electrochemical biosensors using PS have been analysed in details with emphasis on equivalent circuit models and the specific role of PS in the electrical transduction mechanisms. Finally the existing challenges and the future prospects of such devices for commercial use are highlighted.

A review on porous silicon based electrochemical biosensors: Beyond surface area enhancement factor

Spectroscopic investigation (FT-IR, FT-Raman), HOMO-LUMO, NBO, and molecular docking analysis of N-ethyl-N-nitrosourea, a potential anticancer agent

A column sorbent for arsenic was obtained through immobilization of highly branched polyethylenimine (PEI) on graphene oxide (GO). The composite material enables speciation of arsenic by tuning the pH of the sample solution which governs the surface charge of the sorbent, depending on whether amino groups (-NH2) are present (at high pH) or ammonium groups (-NH3+; at low pH). The composite can be applied to improved speciation of arsenic (compared to unmodified GO). There is no need for oxidation or reduction of arsenic. A column procedure was applied for the sequestered extraction and speciation of As(III) and As(V) from environmental water samples before their determination by hydride generation-microwave induced plasma-atomic emission spectrometry. The method has a preconcentration factor of 440 for As(III) and of 400 for As(V). The limits of detection (at 3 S/N) are extremely low, being 1.8 ± 0.2 ngL−1 for As(III) and 1.3 ± 0.08 ngL−1 for As(V). This is much lower than the arsenic guideline value of 10 μgL−1 as given by the WHO.

Preconcentration and speciation of arsenic by using a graphene oxide nanoconstruct functionalized with a hyperbranched polyethyleneimine

The authors describe magnetic nanoparticles consisting of an Fe3O4 core and a poly(methacrylic acid) coating for dispersive solid phase extraction (DSPE) of arsenic prior to its determination by hydride-generation microwave plasma AES (HG-MP-AES). The particles have an average size of 25 nm, can be prepared at low costs, and provide improved operational safety in combination with plasma generation. The methods allows arsenic to be determined with detection limits (at 3σ/m) of 3.0 ng⋅L−1 for As(III) and of 10.0 ng⋅L−1 of As(V). Recoveries of (spiked) samples range from 99.0 to 102%. This is the first report on the use of HG-MP-AES for speciation and preconcentration of arsenic using DSPE. The method displays detection limits that come close to those of ICP-OES and ICP-MS.

S. S. Islam

Papers

Spectroscopic investigation (FT-IR, FT-Raman), HOMO-LUMO, NBO, and molecular docking analysis of N-ethyl-N-nitrosourea, a potential anticancer agent

Preconcentration and speciation of arsenic by using a graphene oxide nanoconstruct functionalized with a hyperbranched polyethyleneimine

Magnetic Fe3O4@poly(methacrylic acid) particles for selective preconcentration of trace arsenic species

Transfer of microstructure pattern of CNTs onto flexible substrate using hot press technique for sensing applications

Synthesis of highly reproducible CdTe nanotubes on anodized alumina template and confinement study by photoluminescence and Raman spectroscopy