There is, I think, something ethereal about i —the square root of minus one. I remember first hearing about it at school. It seemed an odd beast at that time—an intruder hovering on the edge of reality.

Usually familiarity dulls this sense of the bizarre, but in the case of i it was the reverse: over the years the sense of its surreal nature intensified. It seemed that it was impossible to write mathematics that described the real world in …

I and i

Here, we present a review of the antibacterial effects of silver nanomaterials, including proposed antibacterial mechanisms and possible toxicity to higher organisms. For purpose of this review, silver nanomaterials include silver nanoparticles, stabilized silver salts, silver–dendrimer, polymer and metal oxide composites, and silver-impregnated zeolite and activated carbon materials. While there is some evidence that silver nanoparticles can directly damage bacteria cell membranes, silver nanomaterials appear to exert bacteriocidal activity predominantly through release of silver ions followed (individually or in combination) by increased membrane permeability, loss of the proton motive force, inducing de-energization of the cells and efflux of phosphate, leakage of cellular content, and disruption DNA replication. Eukaryotic cells could be similarly impacted by most of these mechanisms and, indeed, a small but growing body of literature supports this concern. Most antimicrobial studies are performed in simple aquatic media or cell culture media without proper characterization of silver nanomaterial stability (aggregation, dissolution, and re-precipitation). Silver nanoparticle stability is governed by particle size, shape, and capping agents as well as solution pH, ionic strength, specific ions and ligands, and organic macromolecules—all of which influence silver nanoparticle stability and bioavailability. Although none of the studies reviewed definitively proved any immediate impacts to human health or the environment by a silver nanomaterial containing product, the entirety of the science reviewed suggests some caution and further research are warranted given the already widespread and rapidly growing use of silver nanomaterials.

https://link.springer.com/content/pdf/10.1007%2Fs11051-010-9900-y.pdf

A review of the antibacterial effects of silver nanomaterials and potential implications for human health and the environment

Green synthesis of metal nanoparticles using plants

Synthesis of metallic nanoparticles using plant extracts.

In materials science, “green” synthesis has gained extensive attention as a reliable, sustainable, and eco-friendly protocol for synthesizing a wide range of materials/nanomaterials including
 metal/metal oxides nanomaterials, hybrid materials, and bioinspired materials. As such, green synthesis is regarded as an important tool to reduce the destructive effects associated with the traditional methods of synthesis for nanoparticles commonly utilized in laboratory and industry. In this review, we summarized the fundamental processes and mechanisms of “green” synthesis approaches, especially for metal and metal oxide [e.g., gold (Au), silver (Ag), copper oxide (CuO), and zinc oxide (ZnO)] nanoparticles using natural extracts. Importantly, we explored the role of biological components, essential phytochemicals (e.g., flavonoids, alkaloids, terpenoids, amides, and aldehydes) as reducing agents and solvent systems. The stability/toxicity of nanoparticles and the associated surface engineering techniques for achieving biocompatibility are also discussed. Finally, we covered applications of such synthesized products to environmental remediation in terms of antimicrobial activity, catalytic activity, removal of pollutants dyes, and heavy metal ion sensing.

/pdf/green-synthesis-of-metals-and-their-oxide-nanoparticles-4onh2g0i4w.pdf

‘Green’ synthesis of metals and their oxide nanoparticles: applications for environmental remediation

Unimolecular initiator end-capped and anchored dendrimers with an initiator functionality of up to 48 for G4 dendrimer were prepared quantitatively in a single-step reaction. Polymerization of styrene using these initiators yielded multi arm star polymers with mol. weight (Mw) in the order of 105 g mol−1 and polydispersity of arm in the range of 1.01 to 1.09.

Successful synthesis of distinct dendritic unimolecular initiators suitable for topologically attractive star polymers

Dendritic‐Linear Hybrid Multiarm Star Polymers: A Straightforward Synthesis of Polymer as Molecular Nanoparticles

Deformable printed electronic array devices are expected to revolutionize next-generation electronics. However, although remarkable technological advances in printable inks and deformable electronic array devices have recently been achieved, technical challenges remain to commercialize these technologies. In this review article a brief introduction to printing methods highlighting significant research studies on ink formation for conductors, semiconductors, and insulators is provided, and the structural design and successful printing strategies of deformable electronic array devices are described. Successful device demonstrations are presented in the applications of passive- and active-matrix array devices. Finally, perspectives and technological challenges to be achieved are pointed out to print practically available deformable devices.

Printable inks and deformable electronic array devices.

Moisture barriers are essential for ionic sensors because moisture has a direct impact on the stability and reliability of electrochemical properties. So far, stretchable moisture barriers that can maximize the advantage of using deformable ion gel as the active material have been rarely investigated and remain as a technological challenge. This study proposes a four-layer (4L) stretchable moisture barrier alternatively composed of a poly(styrene-isobutylene-styrene) copolymer (SiBS) film (2 μm in thickness) and a eutectic gallium-indium liquid metal (LM) film (1 μm in thickness). This multilayer barrier has a low water permeability of 9.09 × 10-20 m2/Pa s at 50% uniaxial strain (ε) and retains the barrier properties at repeated stretchable cycles at ε = 50%. This study demonstrates a skin-attached precise ion gel-based temperature sensor that is independent of moisture change (even dipping in water) and body motions.

Selvaraj Veerapandian

Papers

Successful synthesis of distinct dendritic unimolecular initiators suitable for topologically attractive star polymers

Dendritic‐Linear Hybrid Multiarm Star Polymers: A Straightforward Synthesis of Polymer as Molecular Nanoparticles

Printable inks and deformable electronic array devices.

High-Precision Stretchable Ionic Temperature Sensor Passivated with a Liquid Metal/Block Copolymer Multilayer Film.

Two‐Terminal Deformable Induction Array Sensor Capable of Recognizing Non‐Contact Dynamic Motions of Various Objects