S
Sheldon Hiebert
Researcher at University of Toronto
Publications - 16
Citations - 837
Sheldon Hiebert is an academic researcher from University of Toronto. The author has contributed to research in topics: Ring (chemistry) & Enantioselective synthesis. The author has an hindex of 8, co-authored 16 publications receiving 802 citations. Previous affiliations of Sheldon Hiebert include University of California, Irvine & Universidade Federal do Rio Grande do Sul.
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Journal ArticleDOI
Transition metal-catalyzed enantioselective ring-opening reactions of oxabicyclic alkenes.
TL;DR: This Account covers the work by the group and by others toward the development of new metal-catalyzed asymmetric ring-opening reactions of oxabicyclic alkenes.
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Palladium-Catalyzed Enantioselective Alkylative Ring Opening
Journal ArticleDOI
Scope of palladium-catalyzed alkylative ring opening.
Mark Lautens,Sheldon Hiebert +1 more
TL;DR: The scope of the palladium-catalyzed nucleophilic ring opening methodology has been explored and the addition of various alkyl nucleophiles to oxabenzonorbornadiene has been achieved.
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Total synthesis of ionomycin using ring-opening strategies.
TL;DR: The total synthesis of the polyether antibiotic ionomycin, a calcium ionophore, is described, demonstrating the utility of ring-opening methodologies as applied to the synthesis of polypropionate and deoxypolyPropionate subunits.
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Enantioselective Ring Opening of Aza and Oxabicyclic Alkenes with Dimethylzinc
TL;DR: A system for efficient, asymmetric alkylative ring opening of azabenzonorbornadienes and oxabicyclic alkenes and chiral phosphinooxazoline ligands gives the dihydronaphthalenes, cyclohexenols, and cycloheptenols in excellent yields and enantiomeric excesses.