Showing papers by "Shinji Murai published in 1996"
TL;DR: The treatment of 1,6- and 1,7-enynes with a catalytic amount of PtCl2 in toluene at 80 °C results in skeletal reorganization (cyclorearrangement) of the enynes to give 1-vinylcycloalkenes in high yields as discussed by the authors.
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TL;DR: The ruthenium and rhodium-catalyzed intramolecular C-H/olefin coupling reactions of 1-(2-pyridyl)-1,5- and 1,6-dienes proceeded regio- and stereoselecively to give 5- or 6-membered ring products as mentioned in this paper.
Abstract: The ruthenium- and rhodium-catalyzed intramolecular C-H/olefin coupling reactions of 1-(2-pyridyl)-1,5- and 1,6-dienes proceeded regio- and stereoselecively to give 5- or 6-membered ring products.
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TL;DR: In this article, a rare α-selective C−C bond formation for an ambident 1-silylallyl anion was shown for α,β-unsaturated acylsilanes.
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TL;DR: The reaction of aliphatic aldehydes with hydrosilanes under CO as 1 atm results in incorporation of CO into the carbonyl carbon atom of aldehyde to give arylethane-1,2-diol disilyl ethers as the main product as discussed by the authors.
Abstract: Co2(CO)8-catalyzed reaction of aromatic aldehydes with hydrosilanes under CO as 1 atm results in incorporation of CO into the carbonyl carbon atom of aldehydes to give arylethane-1,2-diol disilyl ethers as the main product. The reaction of aliphatic aldehydes gives similar products, only with low yields.