S
Silvano Geremia
Researcher at University of Trieste
Publications - 215
Citations - 6352
Silvano Geremia is an academic researcher from University of Trieste. The author has contributed to research in topics: Crystal structure & Ligand. The author has an hindex of 40, co-authored 211 publications receiving 5822 citations. Previous affiliations of Silvano Geremia include University of Pennsylvania & Charles University in Prague.
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Journal ArticleDOI
Polyoxometalate Embedding of a Tetraruthenium(IV)-oxo-core by Template-Directed Metalation of [γ-SiW10O36]8−: A Totally Inorganic Oxygen-Evolving Catalyst
Andrea Sartorel,Mauro Carraro,Gianfranco Scorrano,Rita De Zorzi,Silvano Geremia,Neal D. McDaniel,Stefan Bernhard,Marcella Bonchio +7 more
TL;DR: Solid state and solution evidence confirms the embedding of an adamantane-like, Ru4O6 fragment by the divacant, gamma-decatungstosilicate ligand in the resulting complex catalyzes water oxidation to oxygen with TON up to 500 and TOF > 450 h-1.
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Tyrosinase Models. Synthesis, Structure, Catechol Oxidase Activity, and Phenol Monooxygenase Activity of a Dinuclear Copper Complex Derived from a Triamino Pentabenzimidazole Ligand.
Enrico Monzani,Luisa Quinti,Angelo Perotti,Luigi Casella,Michele Gullotti,Lucio Randaccio,Silvano Geremia,Giorgio Nardin,Paolo Faleschini,Giovanni Tabbì +9 more
TL;DR: Kinetic experiments show that [Cu(2)(L-55)](4+) is the most efficient catalyst (rate constant 140 M(-1) s(-1)), followed by [Cu (2)(LB5)]( 4+) (60 M(- 1) s (-1)), in this oxidation, while [ Cu(2(L-66)] (4+) undergoes an extremely fast stoichiometric phase followed by a slow and substrate-concentration-independent catalytic phase.
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Retrostructural analysis of metalloproteins: Application to the design of a minimal model for diiron proteins
Angela Lombardi,Christopher M. Summa,Silvano Geremia,Lucio Randaccio,Vincenzo Pavone,William F. DeGrado +5 more
TL;DR: The backbone geometries comprising the metal-binding sites of zinc fingers, diiron proteins, and rubredoxins may be described to within approximately 1 A rms deviation by using a simple geometric model with only six adjustable parameters.
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Relationship between the Zirconia-Promoted Reduction in the Rh-Loaded Ce0.5Zr0.5O2Mixed Oxide and the Zr–O Local Structure
TL;DR: In this paper, the authors investigated the Zr-O and Ce-O local structure in Rh/Ce0.5Zr0.6O2 by means of EXAFS and Raman spectroscopy.
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Structural basis for mammalian vitamin B12 transport by transcobalamin
Jochen Wuerges,Gianpiero Garau,Silvano Geremia,Sergey N. Fedosov,Torben E. Petersen,Lucio Randaccio +5 more
TL;DR: Structural information is used to predict the overall fold of haptocorrin and intrinsic factor and permits a rational approach to the design of new Cbl-based bioconjugates for diagnostic or therapeutic drug delivery.