Sridhar A. Lahankar

TL;DR: Quasi-classical trajectory calculations performed on a global potential energy surface for H2CO suggest that this second channel represents an intramolecular hydrogen abstraction mechanism: One hydrogen atom explores large regions of the potentialEnergy surface before bonding with the second H atom, bypassing the saddle point entirely.

TL;DR: Chang et al. as discussed by the authors presented an ion imaging approach employing a real-time ion counting method with standard video, which employs a center-of-mass calculation of each ion spot (more than 3x3 pixels spread) prior to integration.

TL;DR: The correlations between the vibrationalStates of H(2) and rotational states of CO formed following excitation on the 2(1)4(3) transition allow us to determine the relative contribution to molecular products from the roaming atom channel versus the conventional molecular channel.

TL;DR: This paper focuses on an investigation of the energy dependence of the roaming atom mechanism up to 1500 cm(-1) above the threshold of the radical channel, H(2)CO-->H+HCO, and the influence of excitation energy on the roamingatom and molecular elimination pathways is reported.

TL;DR: The time-resolved measurements suggest that the two important processes affecting the nonlinear optical properties in the trimer system, charge transfer stabilization and initial electronic delocalization, occur on two different time scales.