S
Stefan Schneiderbauer
Researcher at Ludwig Maximilian University of Munich
Publications - 16
Citations - 484
Stefan Schneiderbauer is an academic researcher from Ludwig Maximilian University of Munich. The author has contributed to research in topics: Metalation & Trimethylsilyl. The author has an hindex of 12, co-authored 16 publications receiving 466 citations.
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Journal ArticleDOI
Organocalcium Compounds with Catalytic Activity for the Ring-Opening Polymerization of Lactones
Matthias Westerhausen,Stefan Schneiderbauer,Alexander N. Kneifel,Yvonne Söltl,Peter Mayer,Heinrich Nöth,Zhiyuan Zhong,Pieter J. Dijkstra,Jan Feijen +8 more
TL;DR: The equimolar reaction of calcium bis[bis(trimethylsilyl)amide] with 2,2,6,6-tetramethylheptane-3,5-dione (Htmhd) in THF yields liquid mononuclear [Ca(tmhd){N(SiMe3)2}(THF)3] as discussed by the authors.
Journal ArticleDOI
Single-site calcium initiators for the controlled ring-opening polymerization of lactides and lactones
TL;DR: In this paper, single-site calcium initiators containing chelating tmhd (H-tmhd = 2,2,6,6-tetramethylheptane-33-dione) ligands were synthesized and applied for the ring-opening polymerization of L-lactide and e-caprolactone.
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Fast and Living Ring-Opening Polymerization of l-Lactide Initiated with In-situ–Generated Calcium Alkoxides
TL;DR: The ring-opening polymerization of l-lactide with calcium alkoxides generated in-situ from bis(tetrahydrofuran)calcium bis[bis(trimethylsilyl)amide] and 2-propanol is presented in this article.
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Zinc- and Tin-Mediated C−C Coupling Reactions of Metalated (2-Pyridylmethyl)(trialkylsilyl)amines − Mechanistic, NMR Spectroscopic, and Structural Studies
Matthias Westerhausen,Tobias Bollwein,Nikolaos Makropoulos,Stefan Schneiderbauer,Max Suter,Heinrich Nöth,Peter Mayer,Holger Piotrowski,Kurt Polborn,Arno Pfitzner +9 more
TL;DR: In this paper, the authors examined the importance of the pyridyl ligandide and NER reactions for coupling reactions, and showed that the coupling product [1,2-bis(tert-butyldimethylsilyl)(2-pyrIDylmethyl) amido]-1-azacyclohexa-3,5dien-1-ide (8) is produced.
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Synthesis of alkaline earth metal bis(2-phosphaethynolates)
TL;DR: In this article, the reaction of dimethyl carbonate with magnesium bis(triisopropylsilyl phosphanide) or the alkaline earth metal bis[bis(trimethyl silyl)phosphanide] in 1,2-dimethoxyethane yields the corresponding bis(2-phosphaethynolate) of magnesium (1), calcium (2), strontium (3), and barium (4), which decomposes upon isolation and have to be stored in an etheral solution at low temperatures.