S
Stephen Philip Fearnley
Researcher at City University of New York
Publications - 12
Citations - 91
Stephen Philip Fearnley is an academic researcher from City University of New York. The author has contributed to research in topics: Oxazolone & Intramolecular force. The author has an hindex of 6, co-authored 12 publications receiving 89 citations. Previous affiliations of Stephen Philip Fearnley include York College, City University of New York & Pennsylvania State University.
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Journal ArticleDOI
Oxazolone Cycloadducts as Heterocyclic Scaffolds for Alkaloid Construction – Synthesis of (±)-2-epi-Pumiliotoxin C
TL;DR: Intramolecular Diels-Alder cycloaddition of N-substituted oxazolone triene I allows direct entry to the functionalized octahydroquinoline II and yields (+/-)-2-epi-pumiliotoxin C.
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Preparation of 2-Alkyl- and 2-Acylpropenals from 5-(Trifluoromethanesulfonyloxy)-4H-1,3-dioxin: A Versatile Acrolein α-Cation Synthon
TL;DR: In this paper, the 2-acylacroleins can be generated using this methodology and trapped with enol ethers to afford 5 -acyl-3,4-dihydro-2 H -pyrans (6g, h ), a substructural unit common to many natural products.
Journal ArticleDOI
Intramolecular Diels–Alder reactions of N-substituted oxazolones
TL;DR: The first intramolecular Diels-Alder reactions of simple trienes featuring an N-substituted oxazolone as the dienophilic component have been investigated and are reported herein.
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Intramolecular Vinylsilane−Oxocarbenium Condensations: Concise Assembly of Cis-Bicyclic Ether Arrays†
TL;DR: Lewis acid-mediated intramolecular attack of vinylsilanes at tethered oxonium precursors 1 results in a rapid assembly of the cis-fused bicyclic ether species 3, with complete regio- and stereospecific control, and in some cases near-quantitative yield.