Showing papers by "T. N. Guru Row published in 2004"
TL;DR: The green colored complexes of the type Re(V)O(L(SB))Cl(2), 1, have been synthesised by reacting NBu(4)[ReOCl(4)] with HL(SB) in dry ethanol and the X-ray structures of the complexes are reported.
Abstract: The green colored complexes of the type ReVO(LSB)Cl2, 1, have been synthesised by reacting NBu4[ReOCl4] with HLSB in dry ethanol. Here, LSB− are the deprotonated forms of N-(2-hydroxybenzyl)-2-picolylamine (HLSB1); N-(2-hydroxybenzyl)-N′,N′-dimethylethylenediamine (HLSB2) and N-(2-hydroxybenzyl)-N′,N′-diethylethylenediamine (HLSB3). Similarly, NBu4[ReOCl4] reacted with N,N-bis(2-hydroxybenzyl)-2-picolylamine (H2L1); N,N-bis(2-hydroxybenzyl)-N′,N′-dimethylethylenediamine (H2L2); N,N-bis(2-hydroxybenzyl)-N′,N′-diethylethylenediamine (H2L3); {N-(2-hydroxybenzyl)-N-(2-pyridylmethyl)}-2-aminoethanol (H2L4); {N-(2-hydroxybenzyl)-N-(2-pyridylmethyl)}-2-methyl-2-amino-1-propanol (H2L5); N,N-bis(1-hydroxyethyl)-2-picolylamine (H2L6), to give the monochloro complexes ReVO(L)Cl, 2. The X-ray structures of the complexes are reported. The molecular structures observed in the solid state are preserved in solution (1H NMR). In acetonitrile solution the ReVO(L)Cl, 2, display a one-electron couple, ReVIO(L)Cl+–ReVO(L)Cl, near 1.0 V vs SCE. The electrogenerated hexavalent complexes [ReVIO(L)Cl]ClO4, 3, are paramagnetic and display sextet EPR spectra in solution at room temperature (Aav
∼ 417 (G), g
∼ 1.914).
26 citations
TL;DR: The crystal structures of 1-(4-fluorophenyl)-2-phenyl-4,5,6,7-tetrahydro-1H-indole, C20H18FN, and 1-6-dimethyl-2- phenyl-3,4, 5, 6, 7-teticarbon-1-indoles, C22H22FN are determined in order to study the role of 'organic fluorine' in crystal engineering.
Abstract: The crystal structures of 1-(4-fluorophenyl)-2-phenyl-4,5,6,7- tetrahydro-1H-indole, $C_{20}H_{18}FN$, and 1-(4-fluorophenyl)-6,6- dimethyl-2-phenyl-4,5,6,7-tetrahydro-1H-indole,$C_{22}H_{22}FN$, have been determined in order to study the role of `organic fluorine' in crystal engineering. These molecules pack in the crystal structure via different types of molecular motifs utilizing weak C–H...F and C–H...\pi interactions.
18 citations
TL;DR: In this paper, the dihedral angle between the mean planes passing through the pyridine ring and the imidazolidine ring is 76.9(1)°.
Abstract: The title compd. (also known as imidachloprid), $C_9H_1_0ClN_5O_2$, is an active agrochem. possessing insecticidal activity. Crystallog. data are given. The dihedral angle between the mean planes passing through the pyridine ring and the imidazolidine ring is 76.9(1)°. There are intramol. and intermol. $N-H\cdot\cdot\cdot\cdotO O$ bonds and $C-H\cdot\cdot\cdot\cdotO$$O$ intermol. interactions.
15 citations
TL;DR: The title compound, C7H5FO3, is nearly planar and the dihedral angle between the phenyl and carboxyl groups is 4.0 (1) as mentioned in this paper.
Abstract: The title compound, C7H5FO3, is nearly planar, and the dihedral angle between the phenyl and carboxyl groups is 4.0 (1). There are intramolecular O–H O and intermolecularO–H...O and O–H...F hydrogen bonds, forming ribbons along the c axis.
11 citations
TL;DR: In this article, high-resolution NMR and single crystal X-ray structural analyses of N-acetamido-3,4,6-tri-O-acetyl-2-azido-2deoxy-$\alpha$-D-galactopyranosylamine (1) are reported.
9 citations
TL;DR: The kresoxim-methyl is an active agrochem exhibiting fungicidal activity as discussed by the authors and the dihedral angle between the two rings is 65.9(1)°.
Abstract: The title compd. (also known as kresoxim-methyl), $C_1_8H_1_9NO_4$, is an active agrochem. exhibiting fungicidal activity. Crystallog. data are given. The dihedral angle between the two rings is 65.9(1)°. The crystal structure is stabilized by weak but highly directional $C-H\cdot\cdot\cdotO$ and $C-H\cdot\cdot\cdot\pi$ intermolecular interactions.
5 citations
TL;DR: The title compound (also known as thiamethaxam), $C_8H_1_0ClN_5O_3S$$,$ is a potent agrochemical exhibiting insecticidal activity.
Abstract: The title compound (also known as thiamethaxam), $C_8H_1_0ClN_5O_3S$$,$ is a potent agrochemical exhibiting insecticidal activity. The crystal structure is stabilized by intermolecular C-H...N and C-H...O interactions.
5 citations
TL;DR: The title compound (also known as pyrazosulfuron-ethyl), C14H18N6O7S, is a potent agrochemical exhibiting herbicidal activity.
Abstract: The title compound ( also known as pyrazosulfuron-ethyl), C14H18N6O7S, is a potent agrochemical exhibiting herbicidal activity There are intramolecular N - H N and C - H O hydrogen bonds Molecules are linked via cyclic hydrogen bonds, forming zigzag chains along the b axis
5 citations
TL;DR: The hexaconazole (also known as hexadecaneazole) as discussed by the authors is a potent agrochemical exhibiting fungicidal activity, whose molecular conformation is stabilized by two intramolecular interactions.
Abstract: The title compound (also known as hexaconazole), $C_1_4H_1_7Cl_2N_3_O_,$ is a potent agrochemical exhibiting fungicidal activity. The molecular conformation is stabilized by two intramolecular $C-H\cdot\cdot\cdot{Cl}$ interactions. Molecules are linked via $O-H\cdot\cdot\cdot{N}$hydrogen bonds, forming zigzag chains along the b axis.
4 citations
TL;DR: The title compound, C10H11ClN4, also known as acetamiprid, is a potent chemical found to exhibit insecticidal activity as mentioned in this paper, and the dihedral angle between the planes passing through the 6-chloro-pyridine ring and the N′-cyano-N-methyl-imidoformamide moiety is 76.7
Abstract: The title compound, C10H11ClN4, also known as acetamiprid, is a potent chemical found to exhibit insecticidal activity. The dihedral angle between the planes passing through the 6-chloropyridine ring and the N′-cyano-N-methylimidoformamide moiety is 76.7 (1) A. The crystal structure is stabilized by C—H⋯N intermolecular interactions.
4 citations
TL;DR: The crystal and molecular structures of the three 4-ketotetrahydroindoles have been determined via single-crystal X-ray diffraction in order to study the intermolecular interactions therein.
Abstract: The crystal and molecular structures of the three 4-ketotetrahydroindoles 2-(4-chlorophenyl)-1-(4-fluorophenyl)-6,6-dimethyl-4,5,6,7-tetrahydro-1H-indol-4-one (C22H19ClFNO), (I), 1-(4-fluorophenyl)-2-(4-methoxyphenyl)-6,6-dimethyl-4,5,6,7-tetrahydro-1H-indol-4-one (C23H22FNO2), (II), and 6,6-dimethyl-1,2-diphenyl-4,5,6,7-tetrahydro-1H-indol-4-one (C22H21NO), (III), have been determined via single-crystal X-ray diffraction in order to study the intermolecular interactions therein. All three structures are stabilized via intermolecular C-H...O and C-H...pi interactions, generating different molecular motifs.
TL;DR: In this article, two new compounds, Ca0.5Bi3V2O10 and Sr 0.5BV2E10, have been synthesized in the ternary system: MO-Bi2O3-v2O5 system (M=M2+), and their crystal structure has been determined from single crystal X-ray diffraction data.
TL;DR: In this paper, a single crystal X-ray analysis of an aminoethyl mannopyranoside, namely, N -(benzyloxycarbonyl)aminoethyl-2,3,4,6- tetra -O -benzoyl-α-d -mannopyranoide (1), showed that the compound crystallizes in the monoclinic space group P 2 1 with two molecules in the unit cell.
TL;DR: In this paper, the hexa-methyl-eneter-amine molecules have no direct coordination to the MnII atom, and the intermolecular hydrogen bonds form a three-dimensional network.
Abstract: In the title compound, [Mn(H2O)6](NO3)2·2C6H12N4·4H2O, the hexamethyleneteramine molecules have no direct coordination to the MnII atom. O—H⋯O and O—H⋯N intermolecular hydrogen bonds form a three-dimensional network.
TL;DR: The crystal structure of 2H-1-benzothiopyran-2-thione, also known as dithiocoumarin, has been determined as mentioned in this paper.
Abstract: The crystal structure of the title compound (systematic name: 2H-1-benzothiopyran-2-thione), $C_9H_6S_2$, also known as dithiocoumarin, has been determined. The molecule is essentially planar and the structure is stabilized via $S\cdot\cdot\cdot S $ and $C- H\cdot\cdot\cdot\pi$ interactions.
TL;DR: The title compound, $C_1_2H_1-4F_3N_3S,$ is a biologically active antiimplantation agent as mentioned in this paper, whose crystal structure is stabilized by intermolecular hydrogen bonds.
Abstract: The title compound, $C_1_2H_1_4F_3N_3S,$ is a biologically active antiimplantation agent. Its crystal structure is stabilized by intermolecular $N-H\cdot\cdot\cdot\cdot S $ hydrogen bonds, which form dimmers in a head-to-tail arrangement and link them into a polymeric chain.
TL;DR: The title compound, $C_1_6H_1.5F_3N_2S, is a biologically active antiimplantation agent as discussed by the authors, whose dihedral angle between the phenyl and triOuoromethylphenyl rings is 15.9 (2)
Abstract: The title compound, $C_1_6H_1_5F_3N_2S,$ is a biologically active antiimplantation agent. The dihedral angle between the phenyl and triOuoromethylphenyl rings is $15.9 (2)^o.$ The crystal structure is stabilized by intermolecular $N-H\cdot\cdot\cdot\cdotS$$S$ hydrogen bonds, forming dimers.
TL;DR: In this paper, the central 4H-thiapyran ring of the 9H-thiaxanthene moiety shows a roof-shaped structure with a dihedral angle of $34.3 (2)^o.$.
Abstract: In the title compound, $C_1_9H_1_1ClFNS_,$the central 4H-thiapyran ring of the 9H-thiaxanthene moiety shows a roof-shaped structure, with a dihedral angle of $34.3 (2)^o.$ The molecules pack in the crystal structure via aromatic \pi-\pi interactions.
TL;DR: The dihedral angle between the mean planes of the 9H-xanthene moiety and the 3-fluorophenyl group is 82.5(1)° as discussed by the authors.
Abstract: In the title compound, $C_1_9H_1_2FNO_,$ the dihedral angle between the mean planes of the 9H-xanthene moiety and the 3-fluorophenyl group is 82.5(1)°. An intramolecular. $C-H\cdot\cdot\cdot\p$$\pi$ interaction stabilizes the mol. conformation.
TL;DR: The title compound (also known as captafol), $C_1_0H_9Cl_4NO_2S,$ exhibits fungicidal activity Crystallog data are given The six-membered ring exists in a boat conformation The crystal packing is stabilized by weak intermol.
Abstract: The title compound (also known as captafol), $C_1_0H_9Cl_4NO_2S_,$ exhibits fungicidal activity Crystallog data are given The six-membered ring exists in a boat conformation The crystal packing is stabilized by weak intermol $C-H\cdo\cdot\cdot\cdot$$O$ and $C-H\cdot\cdot\cdot$$Cl$ interactions