T
Takashi Nakazono
Researcher at Kyushu University
Publications - 18
Citations - 619
Takashi Nakazono is an academic researcher from Kyushu University. The author has contributed to research in topics: Catalysis & Cobalt. The author has an hindex of 7, co-authored 13 publications receiving 470 citations. Previous affiliations of Takashi Nakazono include Rikkyo University & International Institute of Minnesota.
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Cobalt porphyrins as homogeneous catalysts for water oxidation
TL;DR: Three water-soluble cobalt porphyrins investigated as water oxidation catalysts via photo-initiation using Ru(II)(bpy)3(2+)/Na2S2O8 are investigated and a bimolecular radical coupling process is suggested as the rate determining step.
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Highly Efficient and Selective Photocatalytic CO2 Reduction to CO in Water by a Cobalt Porphyrin Molecular Catalyst
TL;DR: The performance of a water-soluble cobalt porphyrin ([{meso-tetra(4-sulfonatophenyl)porphyrinato}cobalt(III)], CoTPPS] as a catalyst for the photoreduction of CO2 in fully aqueous media has been in this article.
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Improving Singlet Oxygen Resistance during Photochemical Water Oxidation by Cobalt Porphyrin Catalysts
TL;DR: Photochemical water oxidation by CoFPS, a fluorinated Co-porphyrin designed to resist attack by singlet oxygen is reported, which exhibits significantly improved stability relative to its non-fluorinated analogue, as shown by a large increase in turnover numbers.
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Mechanism of water oxidation by non-heme iron catalysts when driven with sodium periodate
TL;DR: Under acidic conditions formation of the monomer is favored, which leads to an increase in the WO rate, and Fe(TPA) shows complex kinetic behavior due to the formation of multiple oxidation states of the complex in solution, each of which exhibits catalytic activity for WO.
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Photochemical Water Oxidation Catalyzed by a Water‐Soluble Copper Phthalocyanine Complex
Ryota Terao,Takashi Nakazono,Takashi Nakazono,Alexander Rene Parent,Alexander Rene Parent,Ken Sakai,Ken Sakai +6 more
TL;DR: Chloride greatly inhibits the water oxidation rate as a result of axial chloride binding to CuPcTS, preventing formation of the Cu oxyl or hydroxyl intermediate required for O-O bond formation.