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Showing papers by "Thomas F. Koetzle published in 2002"

Journal Article•DOI•
Direct observation of η2-imine formation through β-H abstraction between amide ligands. Neutron and X-ray diffraction structure of a dihydride imine ditantalum complex

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Hu Cai1, Tianniu Chen1, Xiaoping Wang2, Arthur J. Schultz2, Thomas F. Koetzle3, Zi-Ling Xue1 •
University of Tennessee1, Argonne National Laboratory2, Brookhaven National Laboratory3
30 Jan 2002-Chemical Communications
TL;DR: In this paper, the reaction of Ta(NMe2N)5 with D2SiR′Ph (R′ = Me, Ph) was found to give a dideuteride η2-imine complex, which was confirmed by single crystal neutron and X-ray diffraction.

30 citations

Book Chapter•DOI•
Neutron diffraction studies on transition metal hydride complexes

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Robert Bau1, Thomas F. Koetzle2•
University of Southern California1, Brookhaven National Laboratory2
06 Aug 2002-Acta Crystallographica Section A
TL;DR: In this paper, a review of recent neutron diffraction investigations on terminal, bridging and triply-bridging metal-hydrogen bonds is presented. But the authors focus on terminal and bridging bridges.
Abstract: Recent neutron diffraction investigations on terminal, bridging and triply-bridging metal-hydrogen bonds are reviewed

1 citations