T
Tsuyoshi Sawada
Researcher at Kyushu University
Publications - 49
Citations - 343
Tsuyoshi Sawada is an academic researcher from Kyushu University. The author has contributed to research in topics: Cycloaddition & Substituent. The author has an hindex of 10, co-authored 49 publications receiving 329 citations. Previous affiliations of Tsuyoshi Sawada include University of Coimbra & Kyushu Sangyo University.
Papers
More filters
Journal ArticleDOI
Lewis Acid Catalysis in the Oxidative Cycloaddition of Thiophenes
TL;DR: Thiophenes 1 were treated with m-chloroperbenzoic acid under BF(3) under Et(2)O catalysis to afford thiophene S-monoxides and show a high pi-facial selectivity, a fact that can be explained by the Cieplak-effect.
Journal ArticleDOI
[4 + 2] Cycloaddition of thiophene S-monoxides to activated methylenecyclopropanes
Thies Thiemann,Daisuke Ohira,Yuanqiang Li,Tsuyoshi Sawada,Shuntaro Mataka,Karsten Rauch,Mathias Noltemeyer,Armin de Meijere +7 more
TL;DR: The Wittig olefination of cyclopropanone hemiacetal to generate the methylenecyclopropanes and subsequent cycloaddition can be carried out in a one-pot operation as discussed by the authors.
Journal ArticleDOI
Photochemical and electrochemical behavior of thiophene‐S‐oxides
Thies Thiemann,Daisuke Ohira,Kazuya Arima,Tsuyoshi Sawada,Shuntaro Mataka,Frank Marken,Richard G. Compton,Steven D. Bull,Stephen G. Davies +8 more
TL;DR: The photochemical and electrochemical behavior of thiophene-S-oxides as a class was studied for the first time in this paper, where it was shown that in both cases deoxygenation of the S-O functionality takes place.
Journal ArticleDOI
Oxidative Cycloaddition of Thiophenophanes – [n](2.5)Parathiophenophane (n = 8,10-12,14), [8](2,4)Metathiophenophane and [2.2](2,5)Parametathiophenophane
TL;DR: The results of the X-ray analysis of cycloadducts 18, 19 and 30 were discussed in this article, where they were regarded as a new series of paddlanes.
Journal ArticleDOI
Quadruple Decker [3.3][3.3][3.3]Orthocyclophane Acetal-An Orthocyclophane Ladder.
Shuntaro Mataka,Kouichiro Shigaki,Tsuyoshi Sawada,Yoshihara Mitoma,Masahiko Taniguchi,Thies Thiemann,Kazuya Ohga,Naoyoshi Egashira +7 more
TL;DR: Through clever bridging of orthocyclophanes (in this case by acetalization), molecules such as 1 can be formed with four benzene rings in a stacked face-to-face arrangement that governs UV/Vis spectroscopic and electrochemical properties.