The solar chemical composition is an important ingredient in our understanding of the formation, structure, and evolution of both the Sun and our Solar System. Furthermore, it is an essential refer ...

The Chemical Composition of the Sun

RECENT results1,2 from two ice cores drilled in central Greenland have revealed large, abrupt climate changes of at least regional extent during the late stages of the last glaciation, suggesting that climate in the North Atlantic region is able to reorganize itself rapidly, perhaps even within a few decades. Here we present a detailed stable-isotope record for the full length of the Greenland Ice-core Project Summit ice core, extending over the past 250 kyr according to a calculated timescale. We find that climate instability was not confined to the last glaciation, but appears also to have been marked during the last interglacial (as explored more fully in a companion paper3) and during the previous Saale–Holstein glacial cycle. This is in contrast with the extreme stability of the Holocene, suggesting that recent climate stability may be the exception rather than the rule. The last interglacial seems to have lasted longer than is implied by the deep-sea SPECMAP record4, in agreement with other land-based observations5,6. We suggest that climate instability in the early part of the last interglacial may have delayed the melting of the Saalean ice sheets in America and Eurasia, perhaps accounting for this discrepancy.

Evidence for general instability of past climate from a 250-kyr ice-core record

This paper gives the 2010 self-consistent set of values of the basic constants and conversion factors of physics and chemistry recommended by the Committee on Data for Science and Technology (CODATA) for international use. The 2010 adjustment takes into account the data considered in the 2006 adjustment as well as the data that became available from 1 January 2007, after the closing date of that adjustment, until 31 December 2010, the closing date of the new adjustment. Further, it describes in detail the adjustment of the values of the constants, including the selection of the final set of input data based on the results of least-squares analyses. The 2010 set replaces the previously recommended 2006 CODATA set and may also be found on the World Wide Web at physics.nist.gov/constants.

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CODATA Recommended Values of the Fundamental Physical Constants: 2006

The International Atomic Energy Agency (IAEA), in cooperation with the World Meteorological Organization (WMO), has been conducting a world-wide survey of hydrogen (H/'H) and oxygen (O/O) isotope composition of monthly precipitation since 1961 At present, 72 IAEA/WMO network stations are in operation Another 82 stations belonging to national organizations continue to send their results to the IAEA for publication The paper focuses on basic features of spatial and temporal distribution of deuterium and O in global precipitation, as derived from the IAEA/WMO isotope database The internal structure and basic characteristics of this database are discussed in some detail The existing phenomenological relationships between observed stable isotope composition of precipitation and various climate-related parameters such as local surface air temperature and amount of precipitation are reviewed and critically assessed Attempts are presented towards revealing interannual fluctuations in the accumulated isotope records and relating them to changes of precipitation amount and the surface air temperature over the past 30 years

Isotopic Patterns in Modern Global Precipitation

The second edition of The Biomarker Guide is a fully updated and expanded version of this essential reference. Now in two volumes, it provides a comprehensive account of the role that biomarker technology plays both in petroleum exploration and in understanding Earth history and processes. Biomarkers and Isotopes in the Environment and Human History details the origins of biomarkers and introduces basic chemical principles relevant to their study. It discusses analytical techniques, and applications of biomarkers to environmental and archaeological problems. The Biomarker Guide is an invaluable resource for geologists, petroleum geochemists, biogeochemists, environmental scientists and archaeologists.

The Biomarker Guide

To minimize confusion in the expression of measurement results of stable isotope and gas-ratio measurements, recommendations based on publications of the Commission on Isotopic Abundances and Atomic Weights of the International Union of Pure and Applied Chemistry (IUPAC) are presented. Whenever feasible, entries are consistent with the Systeme International d'Unites, the SI (known in English as the International System of Units), and the third edition of the International Vocabulary of Basic and General Terms in Metrology (VIM, 3rd edition). The recommendations presented herein are approved by the Commission on Isotopic Abundances and Atomic Weights and are designed to clarify expression of quantities related to measurement of isotope and gas ratios to ensure that quantity equations instead of numerical value equations are used for quantity definitions. Examples of column headings consistent with quantity calculus (also called the algebra of quantities) and examples of various deprecated usages connected with the terms recommended are presented.

https://onlinelibrary.wiley.com/doi/pdf/10.1002/rcm.5129

Guidelines and recommended terms for expression of stable‐isotope‐ratio and gas‐ratio measurement results

Use of light stable isotope ratio measurements has proliferated in the past decade The need for procuring additional stable isotope reference materials was recognized at an International Atomic Energy Agency (IAEA) consultants' meeting convened in 19761 This group recommended acquisition of two carbonates, two carbon dioxide samples, a biotite, a sulphate, and other reference materials We report here on the mass-spectrometric analysis of these and other reference samples in a single laboratory to minimize interlaboratory calibration errors A result of this work is an improved equation for relating the PDB isotope scale (belemnite from the Peedee Formation of South Carolina adopted in the 1950s as a reference in palaeotemperature studies2) to the V-SMOW (Vienna-Standard Mean Ocean Water) scale1

Comparison of stable isotope reference samples

New guidelines for reporting stable hydrogen, carbon, and oxygen isotope-ratio data

Reconstruction of continental palaeoclimate and palaeohydrology is currently hampered by limited information about isotopic patterns in the modern hydrologic cycle. To remedy this situation and to provide baseline data for other isotope hydrology studies, more than 4800, depth- and width-integrated, stream samples from 391 selected sites within the USGS National Stream Quality Accounting Network (NASQAN) and Hydrologic Benchmark Network (HBN) were analysed for δ18O and δ2H (http://water.usgs.gov/pubs/ofr/ofr00-160/pdf/ofr00-160.pdf). Each site was sampled bimonthly or quarterly for 2·5 to 3 years between 1984 and 1987. The ability of this dataset to serve as a proxy for the isotopic composition of modern precipitation in the USA is supported by the excellent agreement between the river dataset and the isotopic compositions of adjacent precipitation monitoring sites, the strong spatial coherence of the distributions of δ18O and δ2H, the good correlations of the isotopic compositions with climatic parameters, and the good agreement between the ‘national’ meteoric water line (MWL) generated from unweighted analyses of samples from the 48 contiguous states of δ2H=8·11δ18O+8·99 (r2=0·98) and the unweighted global MWL of sites from the Global Network for Isotopes in Precipitation (GNIP) of the International Atomic Energy Agency and the World Meteorological Organization (WMO) of δ2H=8·17δ18O+10·35.



The national MWL is composed of water samples that arise in diverse local conditions where the local meteoric water lines (LMWLs) usually have much lower slopes. Adjacent sites often have similar LMWLs, allowing the datasets to be combined into regional MWLs. The slopes of regional MWLs probably reflect the humidity of the local air mass, which imparts a distinctive evaporative isotopic signature to rainfall and hence to stream samples. Deuterium excess values range from 6 to 15‰ in the eastern half of the USA, along the northwest coast and on the Colorado Plateau. In the rest of the USA, these values range from −2 to 6‰, with strong spatial correlations with regional aridity. The river samples have successfully integrated the spatial variability in the meteorological cycle and provide the best available dataset on the spatial distributions of δ18O and δ2H values of meteoric waters in the USA. Published in 2001 by John Wiley & Sons, Ltd.

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Distribution of oxygen-18 and deuterium in river waters across the United States†

Consistency of δ13C measurements can be improved 39−47% by anchoring the δ13C scale with two isotopic reference materials differing substantially in 13C/12C. It is recommended that δ13C values of both organic and inorganic materials be measured and expressed relative to VPDB (Vienna Peedee belemnite) on a scale normalized by assigning consensus values of −46.6‰ to L-SVEC lithium carbonate and +1.95‰ to NBS 19 calcium carbonate. Uncertainties of other reference material values on this scale are improved by factors up to two or more, and the values of some have been notably shifted:  the δ13C of NBS 22 oil is −30.03‰.

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Tyler B. Coplen

Papers

Guidelines and recommended terms for expression of stable‐isotope‐ratio and gas‐ratio measurement results

Comparison of stable isotope reference samples

New guidelines for reporting stable hydrogen, carbon, and oxygen isotope-ratio data

Distribution of oxygen-18 and deuterium in river waters across the United States†

New Guidelines for δ13C Measurements