Perfluoroalkylation with Organosilicon Reagents

Synthetic Methods for Compounds Having CF3–S Units on Carbon by Trifluoromethylation, Trifluoromethylthiolation, Triflylation, and Related Reactions

Trifluoromethyltrimethylsilane: nucleophilic trifluoromethylation and beyond.

Trifluoromethylations and related reactions in organic chemistry

This review covers all of the common methods for the syntheses of aromatic and heterocyclic perfluoroalkyl sulfides, a class of compounds which is finding increasing application as starting materials for the preparation of agrochemicals, pharmaceutical products and, more generally, fine chemicals. A systematic approach is taken depending on the mode of incorporation of the SRF groups and also on the type of reagents used.

https://www.beilstein-journals.org/bjoc/content/pdf/1860-5397-6-88.pdf

Aromatic and heterocyclic perfluoroalkyl sulfides. Methods of preparation

Trifluoromethylsulfonyl substituted aromatic compounds 3a-d are prepared from the corresponding sulfonyl fluorides 1a-d by reacting with (trifluoromethyl)trimethylsilane (or-stannane) in the presence of a base under mild conditions in high yields

A convenient route to aryl trifluoromethyl sulfones by fluoride-catalyzed cross-coupling of arenesulfonyl fluorides with (trifluoromethyl)trimethylsilane and (trifluoromethyl)trimethylstannane

A Convenient Route to Aryl Trifluoromethyl Sulfones by Fluoride‐ Catalyzed Cross‐Coupling of Arenesulfonyl Fluorides (I) with ( Trifluoromethyl)trimethylsilane (II) and (Trifluoromethyl) trimethylstannane (IV).

V. N. Movchun

Papers

A convenient route to aryl trifluoromethyl sulfones by fluoride-catalyzed cross-coupling of arenesulfonyl fluorides with (trifluoromethyl)trimethylsilane and (trifluoromethyl)trimethylstannane

A Convenient Route to Aryl Trifluoromethyl Sulfones by Fluoride‐ Catalyzed Cross‐Coupling of Arenesulfonyl Fluorides (I) with ( Trifluoromethyl)trimethylsilane (II) and (Trifluoromethyl) trimethylstannane (IV).