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Journal ArticleDOI

A convenient route to aryl trifluoromethyl sulfones by fluoride-catalyzed cross-coupling of arenesulfonyl fluorides with (trifluoromethyl)trimethylsilane and (trifluoromethyl)trimethylstannane

A. A. Kolomeitsev, +3 more
- 01 Jan 1990 - 
- Vol. 1990, Iss: 12, pp 1151-1152
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TLDR
Trifluoromethylsulfonyl substituted aromatic compounds 3a-d are prepared from the corresponding sulfonyl fluorides 1a-D by reacting with (trifluorsyl)trimethylsilane (or-stannane) in the presence of a base under mild conditions in high yields as mentioned in this paper.
Abstract
Trifluoromethylsulfonyl substituted aromatic compounds 3a-d are prepared from the corresponding sulfonyl fluorides 1a-d by reacting with (trifluoromethyl)trimethylsilane (or-stannane) in the presence of a base under mild conditions in high yields

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Aromatic and heterocyclic perfluoroalkyl sulfides. Methods of preparation

TL;DR: This review covers all of the common methods for the syntheses of aromatic and heterocyclic perfluoroalkyl sulfides, a class of compounds which is finding increasing application as starting materials for the preparation of agrochemicals, pharmaceutical products and, more generally, fine chemicals.
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