Journal ArticleDOI
A convenient route to aryl trifluoromethyl sulfones by fluoride-catalyzed cross-coupling of arenesulfonyl fluorides with (trifluoromethyl)trimethylsilane and (trifluoromethyl)trimethylstannane
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TLDR
Trifluoromethylsulfonyl substituted aromatic compounds 3a-d are prepared from the corresponding sulfonyl fluorides 1a-D by reacting with (trifluorsyl)trimethylsilane (or-stannane) in the presence of a base under mild conditions in high yields as mentioned in this paper.Abstract:
Trifluoromethylsulfonyl substituted aromatic compounds 3a-d are prepared from the corresponding sulfonyl fluorides 1a-d by reacting with (trifluoromethyl)trimethylsilane (or-stannane) in the presence of a base under mild conditions in high yieldsread more
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Perfluoroalkylation with Organosilicon Reagents
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Synthetic Methods for Compounds Having CF3–S Units on Carbon by Trifluoromethylation, Trifluoromethylthiolation, Triflylation, and Related Reactions
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Trifluoromethyltrimethylsilane: nucleophilic trifluoromethylation and beyond.
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Trifluoromethylations and related reactions in organic chemistry
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Aromatic and heterocyclic perfluoroalkyl sulfides. Methods of preparation
TL;DR: This review covers all of the common methods for the syntheses of aromatic and heterocyclic perfluoroalkyl sulfides, a class of compounds which is finding increasing application as starting materials for the preparation of agrochemicals, pharmaceutical products and, more generally, fine chemicals.