Mechanical properties of nanocrystalline materials

http://nanomechanics.mit.edu/sites/default/files/documents/Kumar_03.pdf

Mechanical behavior of nanocrystalline metals and alloys

Plasticity in small-sized metallic systems: Intrinsic versus extrinsic size effect

We used molecular dynamics simulations with system sizes up to 100 million atoms to simulate plastic deformation of nanocrystalline copper. By varying the grain size between 5 and 50 nanometers, we show that the flow stress and thus the strength exhibit a maximum at a grain size of 10 to 15 nanometers. This maximum is because of a shift in the microscopic deformation mechanism from dislocation-mediated plasticity in the coarse-grained material to grain boundary sliding in the nanocrystalline region. The simulations allow us to observe the mechanisms behind the grain-size dependence of the strength of polycrystalline metals.

https://science.sciencemag.org/content/sci/301/5638/1357.full.pdf

A Maximum in the Strength of Nanocrystalline Copper

Digital Image Correlation (DIC) is an important and widely used non-contact technique for measuring material deformation. Considerable progress has been made in recent decades in both developing new experimental DIC techniques and in enhancing the performance of the relevant computational algorithms. Despite this progress, there is a distinct lack of a freely available, high-quality, flexible DIC software. This paper documents a new DIC software package Ncorr that is meant to fill that crucial gap. Ncorr is an open-source subset-based 2D DIC package that amalgamates modern DIC algorithms proposed in the literature with additional enhancements. Several applications of Ncorr that both validate it and showcase its capabilities are discussed.

http://ncorr.com/download/publications/blaberncorr.pdf

Ncorr: Open-Source 2D Digital Image Correlation Matlab Software

Polycrystalline γ-γ′ superalloys with varying grain sizes and unimodal, bimodal, or trimodal distributions of precipitates have been studied. To assess the contributions of specific features of the microstructure to the overall strength of the material, a model that considers solid-solution strengthening, Hall–Petch effects, precipitate shearing in the strong and weak pair-coupled modes, and dislocation bowing between precipitates has been developed and assessed. Cross-slip-induced hardening of the Ni3Al phase and precipitate size distributions in multimodal microstructures are also considered. New experimental observations on the contribution of precipitate shearing to the peak in flow stress at elevated temperatures are presented. Various alloys having comparable yield strengths were investigated and were found to derive their strength from different combinations of microconstituents (mechanisms). In all variants of the microstructure, there is a strong effect of antiphase boundary (APB) energy on strength. Materials subjected to heat treatments below the γ′ solvus temperature benefit from a strong Hall–Petch contribution, while supersolvus heat-treated materials gain the majority of their strength from their resistance to precipitate shearing.

Strengthening Mechanisms in Polycrystalline Multimodal Nickel-Base Superalloys

Strength and tension/compression asymmetry in nanostructured and ultrafine-grain metals

Investigation of creep deformation mechanisms at intermediate temperatures in René 88 DT

Observation and measurement of grain rotation and plastic strain in nanostructured metal thin films

Bulk, fully dense materials were prepared from Fe-10Cu with grain diameters between 45 nm and 1.7 µm. The materials were prepared by ball milling of powders in a glove box, followed by hot isostatic pressing (hipping) or powder forging. Larger grain sizes were obtained by thermal treatment of the consolidated powders. The bulk materials were relatively clean, with oxygen levels below 1500 wpm and other contaminants less than 0.1 at. pct. The mechanical behavior of these materials was unique. At temperatures from 77 to 470 K, the first and only mechanism of plastic deformation was intense shear banding, which was accompanied by a perfectly plastic stress-strain response (absence of strain hardening). There was a large tension-compression asymmetry in the strength, and the shear bands did not occur on the plane of maximum shear stress or the plane of zero extension. This behavior, while unusual for metals, has been observed in amorphous polymers and metallic glasses. On the other hand, the fine-grained Fe-10Cu materials behaved like coarse-grained iron in some respects, particularly by obeying the Hall-Petch equation with constants reasonably close to those of pure iron and by exhibiting low-temperature mechanical behavior which was very similar to that of steels. Transmission electron microscopy (TEM) studies found highly elongated grains within shear bands, indicating that shear banding occurred by a dislocation-based mechanism, at least at grain sizes above 100 nm. Similarities and differences between the fine-grained Fe-10Cu and metals, polymers, metallic glasses, radiation-damaged metals, and quench-damaged metals are discussed.

W.W. Milligan

Papers

Strengthening Mechanisms in Polycrystalline Multimodal Nickel-Base Superalloys

Strength and tension/compression asymmetry in nanostructured and ultrafine-grain metals

Investigation of creep deformation mechanisms at intermediate temperatures in René 88 DT

Observation and measurement of grain rotation and plastic strain in nanostructured metal thin films

Mechanical behavior of a bulk nanostructured iron alloy