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Showing papers by "Wenrong Yang published in 2008"


Journal ArticleDOI
TL;DR: In this article, the authors used sphene ceramics as coatings for Ti-6Al-4V for orthopedic implant applications, and the results indicated that sphene coatings had a significantly improved chemical stability compared to the HAp coatings.

91 citations


Journal ArticleDOI
TL;DR: The polyaniline/gold nanocomposite displays superior function in the biocatalytic activation of microperoxidase-11 because of the high surface area of the assembly and the enhanced charge transport properties of the composite material.
Abstract: In this report, a novel chemical synthesis of polyaniline/gold nanocomposite is explored using ionic liquid (IL) 1-Butyl-3-methylimidazolium hexafluorophosphate The direct chemical synthesis of polyaniline/gold nanocomposite was initiated via the spontaneous oxidation of aniline by AuCl4−in IL A nearly uniform dispersion of polyaniline/Au particles with a diameter of 450 ± 80 nm was produced by this method, which indicates that this method is more suitable for controlling particle dimensions It was also found that the electrical conductivity of the polyaniline/gold nanocomposite was more than 100 times higher than that of the pure polyaniline nanoparticles The polyaniline/gold nanocomposite displays superior function in the biocatalytic activation of microperoxidase-11 because of the high surface area of the assembly and the enhanced charge transport properties of the composite material We also report the possible application of polyaniline/gold nanocomposite as a H2O2biosensor

37 citations


Journal ArticleDOI
TL;DR: A novel procedure combining monolayer self-assembly with electron beam lithography has been developed for attaching ferritin nanoparticles to a submicron thin-film SQUID (superconducting quantum interference device).
Abstract: A novel procedure combining monolayer self-assembly with electron beam lithography has been developed for attaching ferritin nanoparticles to a submicron thin-film SQUID (superconducting quantum interference device). After opening a window in the PMMA (polymethylmethacrylate) resist, organic linker molecules are used to attach ferritin to the exposed parts of the gold overlayer of a Nb nanoSQUID. This allows the magnetic nanoparticles to be located optimally as far as magnetic coupling to the nanoSQUID is concerned.

36 citations


Journal ArticleDOI
TL;DR: In this paper, a homologous series of norbornylogous (NB) bridges has been synthesized in which the average curvature of the bridges is very small and two thiol moieties at each end allow them to form self-assembled monolayers (SAMs) and connect to two gold electrodes to form a molecular junction.
Abstract: A new homologous series of norbornylogous (NB) bridges has been synthesized in which the average curvature of the bridges is very small. The molecules are rigid and have two thiol moieties at each end to allow them to form self-assembled monolayers (SAMs) and to connect to two gold electrodes to form a molecular junction. The SAMs formed were characterized using electrochemistry to determine the surface coverage of molecules on gold surface and to provide an indication of the packing of the NB bridges while ellipsometry and X-ray photoelectron spectroscopy (XPS) were used to provide an indication of the SAM thickness and orientation. Single molecule conductance of NB bridges was measured as a function of the molecular length. The conductance was found to decrease exponentially with the length with a decay constant that is exactly correlated with photoelectron transfer and other studies at the multiple molecule level. The molecule−electrode contact resistance was determined and compared with that of relate...

16 citations


01 Jan 2008
TL;DR: The use of self-assembled monolayers (SAM) is a typical example of the techniques used in nanotechnology, from the process "bottom up", which is to create a nanostructure by successive additions of molecular or atomic entities on a surface as discussed by the authors.
Abstract: The modification of an electrode surface at the molecular level using the technique of depositing self-assembled monolayers (SAM) is a typical example of the techniques used in nanotechnology, from the process "bottom up", which is to create a nanostructure by successive additions of molecular or atomic entities on a surface. This article presents some recent advances in the field, with examples: the development of systems Sat hybridized with biomolecules, nanoparticles or nanotubes in bioelectronics, the use of switchable electrodes to study the adhesion and migration of biological cells , and the integration of molecular son in the SAM to recognize and allow the transduction of a biological response allowing the practice of electrochemistry in a complex biological environment.

2 citations


Journal ArticleDOI
TL;DR: Yang as discussed by the authors obtained his Ph.D. from the University of New South Wales (UNSW) with Professor Justin Gooding and Professor Bryn Hibbert in 2002 and worked then at CSIRO as a CSIRO post-doctoral fellow before returning to UNSW in 2005.
Abstract: Wenrong Yang obtained his Ph.D. from the University of New South Wales (UNSW) with Professor Justin Gooding and Professor Bryn Hibbert in 2002 and worked then at CSIRO as a CSIRO post-doctoral fellow before returning to UNSW in 2005. Wenrong currently is a University of Sydney Postdoctoral Research Fellow and working on electron transport in single molecules by means of scanning probe microscopy techniques. Manuscript received: 19 September 2008. Final version: 9 October 2008.

Posted Content
TL;DR: Cell culture studies in conjunction with microscopy and viability assays and cytotoxicity studies showed that cells were unaffected during the time-course of the experiments, providing support for the biocompatibility aspects of PrO(x)FeAs-based superconductor material.
Abstract: The recent discovery of arsenic-based high temperature superconductors has reignited interest in the study of superconductor : biological interfaces. However, the new superconductor materials involve the chemistry of arsenic, their toxicity remain unclear [ Nature, 2008, 452(24):922]. In this study the possible adverse effects of this new family of superconductors on cells have been examined. Cell culture studies in conjunction with microscopy and viability assays were employed to examine the influence of arsenic-based superconductor PrOxFeAs (x=0.75) material in vitro. Imaging data revealed that cells were well adhered and spread on the surface of the superconductor. Furthermore, cytotoxicity studies showed that cells were unaffected during the time-course of the experiments, providing support for the biocompatibility aspects of PrOxFeAs-based superconductor material.