Secondary organic aerosol (SOA) accounts for a significant fraction of ambient tropospheric aerosol and a detailed knowledge of the formation, properties and transformation of SOA is therefore required to evaluate its impact on atmospheric processes, climate and human health. The chemical and physical processes associated with SOA formation are complex and varied, and, despite considerable progress in recent years, a quantitative and predictive understanding of SOA formation does not exist and therefore represents a major research challenge in atmospheric science. This review begins with an update on the current state of knowledge on the global SOA budget and is followed by an overview of the atmospheric degradation mechanisms for SOA precursors, gas-particle partitioning theory and the analytical techniques used to determine the chemical composition of SOA. A survey of recent laboratory, field and modeling studies is also presented. The following topical and emerging issues are highlighted and discussed in detail: molecular characterization of biogenic SOA constituents, condensed phase reactions and oligomerization, the interaction of atmospheric organic components with sulfuric acid, the chemical and photochemical processing of organics in the atmospheric aqueous phase, aerosol formation from real plant emissions, interaction of atmospheric organic components with water, thermodynamics and mixtures in atmospheric models. Finally, the major challenges ahead in laboratory, field and modeling studies of SOA are discussed and recommendations for future research directions are proposed.

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The formation, properties and impact of secondary organic aerosol: current and emerging issues

http://joenschem.com/yahoo_site_admin/assets/docs/atkinson2000r.93190106.pdf

Atmospheric chemistry of VOCs and NOx

https://ams.confex.com/ams/pdfpapers/71176.pdf

Fully coupled “online” chemistry within the WRF model

Atmospheric degradation of volatile organic compounds

We present a first description and evaluation of GEOS-CHEM, a global three-dimensional (3-D) model of tropospheric chemistry driven by assimilated meteorological observations from the Goddard Earth Observing System (GEOS) of the NASA Data Assimilation Office (DAO). The model is applied to a 1-year simulation of tropospheric ozone-NOx-hydrocarbon chemistry for 1994, and is evaluated with observations both for 1994 and for other years. It reproduces usually to within 10 ppb the concentrations of ozone observed from the worldwide ozonesonde data network. It simulates correctly the seasonal phases and amplitudes of ozone concentrations for different regions and altitudes, but tends to underestimate the seasonal amplitude at northern midlatitudes. Observed concentrations of NO and peroxyacetylnitrate (PAN) observed in aircraft campaigns are generally reproduced to within a factor of 2 and often much better. Concentrations of HNO3 in the remote troposphere are overestimated typically by a factor of 2-3, a common problem in global models that may reflect a combination of insufficient precipitation scavenging and gas-aerosol partitioning not resolved by the model. The model yields an atmospheric lifetime of methylchloroform (proxy for global OH) of 5.1 years, as compared to a best estimate from observations of 5.5 plus or minus 0.8 years, and simulates H2O2 concentrations observed from aircraft with significant regional disagreements but no global bias. The OH concentrations are approximately 20% higher than in our previous global 3-D model which included an UV-absorbing aerosol. Concentrations of CO tend to be underestimated by the model, often by 10-30 ppb, which could reflect a combination of excessive OH (a 20% decrease in model OH could be accommodated by the methylchloroform constraint) and an underestimate of CO sources (particularly biogenic). The model underestimates observed acetone concentrations over the South Pacific in fall by a factor of 3; a missing source from the ocean may be implicated.

/pdf/global-modeling-of-tropospheric-chemistry-with-assimilated-4jwui0m63q.pdf

Global modeling of tropospheric chemistry with assimilated meteorology : Model description and evaluation

This paper discusses methods for ranking photochemical ozone formation reactivities of volatile organic compounds (VOCs). Photochemical mechanisms for the atmospheric reactions of 118 VOCs were used to calculate their effects on ozone formation under various NOx conditions in model scenarios representing 39 different urban areas. Their effects on ozone were used to derive 18 different ozone reactivity scales, one of which is the Maximum Incremental Reactivity (MIR) scale used in the new California Low Emission Vehicle and Clean Fuel Regulations. These scales are based on three different methods for quantifying ozone impacts and on six different approaches for dealing with the dependencies of reactivity on NOx. The predictions of the scales are compared, the reasons for their similarities and differences are discussed, and the sensitivities of the scales to NOx and other scenario conditions are examined. Scales based on peak ozone levels were highly dependent on NOx, but those based on integrated ...

Development of Ozone Reactivity Scales for Volatile Organic Compounds

Kinetics and mechanisms of the gas-phase reactions of ozone with organic compounds under atmospheric conditions

A detailed mechanism for the gas-phase atmospheric reactions of organic compounds

Development of the SAPRC-07 chemical mechanism

The yields of alkyl nitrates formed in the NO/sub x/-air photooxidations of the homologous series of n-alkanes from ethane through n-octane have been determined at 299 +/- 2K and 735 torr total pressure for two different chemical systems. Alkyl peroxy radicals were generated by reaction of the n-alkanes with OH radicals (generated from the photolysis of methyl nitrite in air) or Cl atoms (from photolysis of Cl/sub 2/ in air). The alkyl nitrate yields obtained from the two systems, corrected for secondary reactions, were in agreement within the experimental errors and increased monotonically with the carbon number of the n-alkane, from less than or equal to1% for ethane to approx. 33% for n-octane, with the yields apparently approaching a limit of approx. 35% for large n-alkanes. The relative yields of the various secondary alkyl nitrate isomers in the n-pentane through n-octane systems were in good agreement with those expected from OH radical or Cl atom reaction with the corresponding secondary C-H bonds. However, the relative yields of the primary alkyl nitrates in the propane and butane systems were a factor of approx. 2 lower than expected. The data are consistent with the alkyl nitrates being formed almost entirely from themore » reaction of peroxy radicals with NO, and the ratios of the corrected alkyl nitrate yields thus reflect the fraction of RO/sub 2/ radicals which react with NO to form alkyl nitrates. These nitrate yields from the reaction of RO/sub 2/ radicals with NO are important inputs into chemical computer models of the atmospheric NO/sub x/-air photooxidations of the large n-alkanes.« less

William P. L. Carter

Papers

Development of Ozone Reactivity Scales for Volatile Organic Compounds

Kinetics and mechanisms of the gas-phase reactions of ozone with organic compounds under atmospheric conditions

A detailed mechanism for the gas-phase atmospheric reactions of organic compounds

Development of the SAPRC-07 chemical mechanism

Alkyl nitrate formation from the nitrogen oxide (NOx)-air photooxidations of C2-C8 n-alkanes