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Xiaobing Wan
Researcher at Soochow University (Suzhou)
Publications - 86
Citations - 2862
Xiaobing Wan is an academic researcher from Soochow University (Suzhou). The author has contributed to research in topics: Catalysis & Radical. The author has an hindex of 26, co-authored 84 publications receiving 2456 citations. Previous affiliations of Xiaobing Wan include Lanzhou University.
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Cross Coupling of Acyl and Aminyl Radicals: Direct Synthesis of Amides Catalyzed by Bu4NI with TBHP as an Oxidant
TL;DR: A metal-free, simple, and scalable method for the synthesis of amides (III, V, VI, VII, and X) from commercially available or easily synthesized starting materials is described in this article.
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Bu4NI‐Catalyzed C ? O Bond Formation by Using a Cross‐Dehydrogenative Coupling (CDC) Reaction
TL;DR: The title reaction proceeds in the absence of transition metal catalysts, is operationally simple and tolerates a wide variety of functional groups like cyano, amide, aromatic halide, ether, ketone groups and C-C double bonds.
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Tetrabutylammonium Iodide Catalyzed Synthesis of Allylic Ester with tert-Butyl Hydroperoxide as an Oxidant
TL;DR: A metal-free C-H oxidation for the construction of allylic esters has been developed using a commercially available and inexpensive catalyst and oxidant and readily available starting materials, rendering the methodology a useful alternative to other approaches typically employed in the synthesis of allies.
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Synthesis of tert-butyl peresters from aldehydes by Bu4NI-catalyzed metal-free oxidation and its combination with the Kharasch-Sosnovsky reaction
TL;DR: A new tert-butyl peresters synthesis directly from aldehydes and TBHP was developed via Bu(4)NI-catalyzed aldehyde C-H oxidation, which offers a practical approach for the synthesis of allylic esters from simple aldeHydes and alkenes via a two-step one-pot procedure.
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Wacker-type oxidation of alkynes into 1,2-diketones using molecular oxygen.
TL;DR: An intriguing new Wacker-type oxidation of alkynes catalyzed by PdBr(2) and CuBr( 2) is described, which opens an efficient access to 1,2-diketones using molecular oxygen.