The present invention relates to an electronic device comprising anode, cathode and at least one organic layer which comprises a compound of the formula (I) to (IV). The invention furthermore encompasses the use of compounds of the formula (I) to (IV) in an electronic device and to a compound of the formula (Ic) to (IVc).

Materials for electronic devices

Carbon dioxide chemistry (in particular, capture and conversion) has attracted much attention from the scientific community due to global warming associated with positive carbon accumulation. The most widely used chemical absorption technique for carbon capture and storage/sequestration (CCS) would be essentially adopting amino-containing absorbents through formation of C–N bond in terms of mechanistic consideration. However, extensive energy input in desorption and compression process would be a crucial barrier to realize practical CCS. On the other hand, CO2 is very attractive as an environmentally friendly feedstock to replace the hazardous phosgene route for making commodity chemicals, fuels, and materials from a standpoint of green chemistry, whereas the reactions involving CO2 are commonly carried out at high pressure, which may not be economically suitable and also pose safety concerns. The challenge is to develop catalysts that are capable of activating CO2 under low pressure (preferably at 1 atm), and thus incorporating CO2 into organic molecules catalytically. We have proposed a carbon capture and utilization (CCU) strategy as an alternative approach to addressing the energy penalty problem in CCS. The essence of our strategy is to use captured CO2, also considered as the activated form of CO2, which could render this system suitable for accomplishing chemical transformation of CO2 under low pressure to avoid an additional desorption step. Indeed, CO2 could be activated through the formation of carbamate/alkyl carbonate with Lewis basic nitrogen species. In this review, we would like to discuss and update advances on CCU, particularly C–N bond formation with the production of oxazolidinones, quinazolines, carbamates, isocyanates and polyurethanes by using CO2 as C1 feedstock, and CO2 capture by amino-containing absorbents, including conventional aqueous solution of amine, chilled ammonia, amino-functionalized ionic liquids and solid absorbents such as amino-functionalized silica, carbon, polymers and resin, presumably leading to CO2's activation and thus subsequent conversion through C–N bond formation pathway.

Carbon dioxide utilization with C–N bond formation: carbon dioxide capture and subsequent conversion

Ball milling has been applied in numerous solvent-free carbon-carbon bond formations. In many cases, these transformations proved superior to the analogous reactions performed in solution. The reaction scope involves purely organic addition and coupling reactions, transformations involving metals (in stoichiometric and catalytic amounts) as well as asymmetric organocatalyses.

Solvent-Free Carbon-Carbon Bond Formations in Ball Mills

https://recipp.ipp.pt/bitstream/10400.22/7411/1/ART_AnaPessoa_2015_2.pdf

Quinoxaline, its derivatives and applications: A state of the art review.

Potassium phthalimide-N-oxyl: a novel, efficient, and simple organocatalyst for the one-pot three-component synthesis of various 2-amino-4H-chromene derivatives in water

An efficient synthesis of quinazoline-2,4-dione derivatives with the aid of a low-valent titanium reagent

Efficient Green Procedure for the Knoevenagel Condensation under Solvent‐Free Conditions

Efficient Synthesis of Tetrahydrobenzo[b]pyrans under Solvent‐Free Conditions at Room Temperature

A mild, efficient, and novel synthesis of 2-aryl-2H-indazoles via cyclization of 2-nitrobenzylamines promoted by SnCl 2 ·2H 2 O has been described. This method applies to a wide scope of substrates containing electron-donating and electron-withdrawing substituents.

Xiaoyue Li

Papers

An efficient synthesis of quinazoline-2,4-dione derivatives with the aid of a low-valent titanium reagent

Efficient Green Procedure for the Knoevenagel Condensation under Solvent‐Free Conditions

Efficient Synthesis of Tetrahydrobenzo[b]pyrans under Solvent‐Free Conditions at Room Temperature

A Novel and Efficient Synthesis of 2-Aryl-2H-indazoles via SnCl2-Mediated Cyclization of 2-Nitrobenzylamines

An efficient synthesis of quinoxaline derivatives mediated by stannous chloride