Owing to the promise of high safety and energy density, all-solid-state batteries are attracting incremental interest as one of the most promising next-generation energy storage systems. However, their widespread applications are inhibited by many technical challenges, including low-conductivity electrolytes, dendrite growth, and poor cycle/rate properties. Particularly, the interfacial dynamics between the solid electrolyte and the electrode is considered as a crucial factor in determining solid-state battery performance. In recent years, intensive research efforts have been devoted to understanding the interfacial behavior and strategies to overcome these challenges for all-solid-state batteries. Here, the interfacial principle and engineering in a variety of solid-state batteries, including solid-state lithium/sodium batteries and emerging batteries (lithium-sulfur, lithium-air, etc.), are discussed. Specific attention is paid to interface physics (contact and wettability) and interface chemistry (passivation layer, ionic transport, dendrite growth), as well as the strategies to address the above concerns. The purpose here is to outline the current interface issues and challenges, allowing for target-oriented research for solid-state electrochemical energy storage. Current trends and future perspectives in interfacial engineering are also presented.

Interface Issues and Challenges in All-Solid-State Batteries: Lithium, Sodium, and Beyond.

Lithium-sulfur (Li-S) batteries are considered as promising next-generation energy storage devices due to their ultrahigh theoretical energy density, where soluble lithium polysulfides are crucial in the Li-S electrochemistry as intrinsic redox mediators. However, the poor mediation capability of the intrinsic polysulfide mediators leads to sluggish redox kinetics, further rendering limited rate performances, low discharge capacity, and rapid capacity decay. Here, an organodiselenide, diphenyl diselenide (DPDSe), is proposed to accelerate the sulfur redox kinetics as a redox comediator. DPDSe spontaneously reacts with lithium polysulfides to generate lithium phenylseleno polysulfides (LiPhSePSs) with improved redox mediation capability. The as-generated LiPhSePSs afford faster sulfur redox kinetics and increase the deposition dimension of lithium sulfide. Consequently, the DPDSe comediator endows Li-S batteries with superb rate performance of 817 mAh g-1 at 2 C and remarkable cycling stability with limited anode excess. Moreover, Li-S pouch cells with the DPDSe comediator achieve an actual initial energy density of 301 Wh kg-1 and 30 stable cycles. This work demonstrates a novel redox comediation strategy with an effective organodiselenide comediator to facilitate the sulfur redox kinetics under pouch cell conditions and inspires further exploration in mediating Li-S kinetics for practical high-energy-density batteries.

An Organodiselenide Comediator to Facilitate Sulfur Redox Kinetics in Lithium-Sulfur Batteries.

Electrochemical energy storage devices (EESs) play a crucial role for the construction of sustainable energy storage system from the point of generation to the end user due to the intermittent nature of renewable sources. Additionally, to meet the demand for next-generation electronic applications, optimizing the energy and power densities of EESs with long cycle life is the crucial factor. Great efforts have been devoted towards the search for new materials, to augment the overall performance of the EESs. Although there are a lot of ongoing researches in this field, the performance does not meet up to the level of commercialization. A further understanding of the charge storage mechanism and development of new electrode materials are highly required. The present review explains the overview of recent progress in supercapattery devices with reference to their various aspects. The different charge storage mechanisms and the multiple factors involved in the performance of the supercapattery are described in detail. Moreover, recent advancements in this supercapattery research and its electrochemical performances are reviewed. Finally, the challenges and possible future developments in this field are summarized.

/pdf/comprehensive-insight-into-the-mechanism-material-selection-1x6r17ycdm.pdf

Comprehensive Insight into the Mechanism, Material Selection and Performance Evaluation of Supercapatteries

Ever-increasing global energy consumption has driven the development of renewable energy technologies to reduce greenhouse gas emissions and air pollution. Battery energy storage systems (BESS) with high electrochemical performance are critical for enabling renewable yet intermittent sources of energy such as solar and wind. In recent years, numerous new battery technologies have been achieved and showed great potential for grid scale energy storage (GSES) applications. However, their practical applications have been greatly impeded due to the gap between the breakthroughs achieved in research laboratories and the industrial applications. In addition, various complex applications call for different battery performances. Matching of diverse batteries to various applications is required to promote practical energy storage research achievement. This review provides in-depth discussion and comprehensive consideration in the battery research field for GSES. The overall requirements of battery technologies for practical applications with key parameters are systematically analyzed by generating standards and measures for GSES. We also discuss recent progress and existing challenges for some representative battery technologies with great promise for GSES, including metal-ion batteries, lead-acid batteries, molten-salt batteries, alkaline batteries, redox-flow batteries, metal-air batteries, and hydrogen-gas batteries. Moreover, we emphasize the importance of bringing emerging battery technologies from academia to industry. Our perspectives on the future development of batteries for GSES applications are provided.

Rechargeable Batteries for Grid Scale Energy Storage.

With increasing demand for grid-scale energy storage, potassium-ion batteries (PIBs) have emerged as promising complements or alternatives to commercial lithium-ion batteries owing to the low cost, natural abundance of potassium resources, the low standard reduction potential of potassium, and fascinating K+ transport kinetics in the electrolyte. However, the low energy density and unstable cycle life of cathode materials hamper their practical application. Therefore, cathode materials with high capacities, high redox potentials, and good structural stability are required with the advancement toward next-generation PIBs. To this end, understanding the structure-dependent intercalation electrochemistry and recognizing the existing issues relating to cathode materials are indispensable prerequisites. This review summarizes the recent advances of PIB cathode materials, including metal hexacyanometalates, layered metal oxides, polyanionic frameworks, and organic compounds, with an emphasis on the structural advantages of the K+ intercalation reaction. Moreover, major current challenges with corresponding strategies for each category of cathode materials are highlighted. Finally, future research directions and perspectives are presented to accelerate the development of PIBs and facilitate commercial applications. It is believed that this review will provide practical guidance for researchers engaged in developing next-generation advanced PIB cathode materials.

Challenges and Strategies toward Cathode Materials for Rechargeable Potassium-Ion Batteries

High-Energy-Density Solid-Electrolyte-Based Liquid Li-S and Li-Se Batteries

Detection of Micro-Scale Li Dendrite via H2 Gas Capture for Early Safety Warning

Metallic zinc anodes in zinc-ion batteries suffer from problematic Zn dendrite chemistry. Previous works have shown that preferred-orientation crystal planes can help dendrite-free metal anodes. This work reports a nanothickness (≈570 nm) AgZn3  coating to regulate the Zn growth. First, AgZn3 @Zn anode avoids the problem, in Ag@Zn anode, that the rate of electrochemical Ag-Zn alloying is slower than that of Zn dendrites growth. Batteries life increased from 112 h (pure Zn) and 932 h (Ag@Zn) to 1360 h (AgZn3 @Zn) at 2 mA cm-2  and 1 mAh cm-2 . Then, plasma sputtering can remove nonconductive ZnO and improve Zn-ion affinity, which brings a longer life for AuZn3 @Zn (423 h), CuZn3 @Zn (385 h), and AgZn3 @Zn (1150 h) than pure Zn (93 h) at 1 mAh cm-2 . More importantly, AgZn3 (002) has a high matching with the Zn (002), which can guide ordered Zn epitaxial deposition, thereby achieving dense and dendrite-free Zn growth. This work clearly captures the fascinating structure of the densely stacked Zn layers on the AgZn3  layer. This strategy not only improves the performance of zinc-ion batteries greatly but will also help one understand the matching mechanism of the (002) vertical crystal plane.

Vertical Crystal Plane Matching between AgZn3 (002) and Zn (002) Achieving a Dendrite-Free Zinc Anode.

An optimal sizing model of the battery energy storage system (BESS) for large-scale wind farm adapting to the scheduling plan is proposed in this paper. Based on the analysis of the variability and uncertainty of wind output, the cost of auxiliary services of systems that are eased by BESS is quantized and the constraints of BESS accounting for the effect of wind power on system dispatching are proposed. Aiming to maximum the benefits of wind-storage union system, an optimal capacity model considering BESS investment costs, wind curtailment saving, and auxiliary services compensation is established. What’s more, the effect of irregular charge/discharge process on the life cycle of BESS is considered into the optimal model by introducing an equivalent loss of the cycle life. Finally, based on the typical data of a systems, results show that auxiliary services compensation can encourage wind farm configuration BESS effectively. Various sensitivity analyses are performed to assess the effect of the auxiliary services compensation, on-grid price of wind power, investment cost of BESS, cycle life of BESS, and wind uncertainty reserve level of BESS on this optimal capacity.

https://www.mdpi.com/2076-3417/8/10/1957/pdf

Optimization of Battery Energy Storage System Capacity for Wind Farm with Considering Auxiliary Services Compensation

Optimal configuration of hybrid energy systems considering power to hydrogen and electricity-price prediction: A two-stage multi-objective bi-level framework

Xin Jiang

Papers

High-Energy-Density Solid-Electrolyte-Based Liquid Li-S and Li-Se Batteries

Detection of Micro-Scale Li Dendrite via H2 Gas Capture for Early Safety Warning

Vertical Crystal Plane Matching between AgZn3 (002) and Zn (002) Achieving a Dendrite-Free Zinc Anode.

Optimization of Battery Energy Storage System Capacity for Wind Farm with Considering Auxiliary Services Compensation

Optimal configuration of hybrid energy systems considering power to hydrogen and electricity-price prediction: A two-stage multi-objective bi-level framework