基礎講座 電気泳動(Electrophoresis)

This review comprises a detailed survey of ongoing methodologies for soft actuators, highlighting approaches suitable for nanometer- to centimeter-scale robotic applications. Soft robots present a special design challenge in that their actuation and sensing mechanisms are often highly integrated with the robot body and overall functionality. When less than a centimeter, they belong to an even more special subcategory of robots or devices, in that they often lack on-board power, sensing, computation, and control. Soft, active materials are particularly well suited for this task, with a wide range of stimulants and a number of impressive examples, demonstrating large deformations, high motion complexities, and varied multifunctionality. Recent research includes both the development of new materials and composites, as well as novel implementations leveraging the unique properties of soft materials.

Soft Actuators for Small-Scale Robotics.

Quantum cryptography is arguably the fastest growing area in quantum
information science. Novel theoretical protocols are designed on a regular
basis, security proofs are constantly improving, and experiments are
gradually moving from proof-of-principle lab demonstrations to in-field
implementations and technological prototypes. In this paper, we provide
both a general introduction and a state-of-the-art description of the
recent advances in the field, both theoretical and experimental. We start
by reviewing protocols of quantum key distribution based on discrete
variable systems. Next we consider aspects of device independence,
satellite challenges, and protocols based on continuous-variable systems.
We will then discuss the ultimate limits of point-to-point private
communications and how quantum repeaters and networks may overcome these
restrictions. Finally, we will discuss some aspects of quantum
cryptography beyond standard quantum key distribution, including quantum
random number generators and quantum digital signatures.

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Advances in quantum cryptography

Post-transition elements, together with zinc-group metals and their alloys belong to an emerging class of materials with fascinating characteristics originating from their simultaneous metallic and liquid natures. These metals and alloys are characterised by having low melting points (i.e. between room temperature and 300 °C), making their liquid state accessible to practical applications in various fields of physical chemistry and synthesis. These materials can offer extraordinary capabilities in the synthesis of new materials, catalysis and can also enable novel applications including microfluidics, flexible electronics and drug delivery. However, surprisingly liquid metals have been somewhat neglected by the wider research community. In this review, we provide a comprehensive overview of the fundamentals underlying liquid metal research, including liquid metal synthesis, surface functionalisation and liquid metal enabled chemistry. Furthermore, we discuss phenomena that warrant further investigations in relevant fields and outline how liquid metals can contribute to exciting future applications.

Liquid metals: fundamentals and applications in chemistry

Gallium and several of its alloys are liquid metals at or near room temperature. Gallium has low toxicity, essentially no vapor pressure, and a low viscosity. Despite these desirable properties, applications calling for liquid metal often use toxic mercury because gallium forms a thin oxide layer on its surface. The oxide interferes with electrochemical measurements, alters the physicochemical properties of the surface, and changes the fluid dynamic behavior of the metal in a way that has, until recently, been considered a nuisance. Here, we show that this solid oxide “skin” enables many new applications for liquid metals including soft electrodes and sensors, functional microcomponents for microfluidic devices, self-healing circuits, shape-reconfigurable conductors, and stretchable antennas, wires, and interconnects.

Emerging Applications of Liquid Metals Featuring Surface Oxides

Controlled actuation of soft objects with functional surfaces in aqueous environments presents opportunities for liquid phase electronics, novel assembled super-structures and unusual mechanical properties. We show the extraordinary electrochemically induced actuation of liquid metal droplets coated with nanoparticles, so-called “liquid metal marbles”. We demonstrate that nanoparticle coatings of these marbles offer an extra dimension for affecting the bipolar electrochemically induced actuation. The nanoparticles can readily migrate along the surface of liquid metals, upon the application of electric fields, altering the capacitive behaviour and surface tension in a highly asymmetric fashion. Surprising actuation behaviours are observed illustrating that nanoparticle coatings can have a strong effect on the movement of these marbles. This significant novel phenomenon, combined with unique properties of liquid metal marbles, represents an exciting platform for enabling diverse applications that cannot be achieved using rigid metal beads.

Electrochemically induced actuation of liquid metal marbles

We demonstrate photochemically induced actuation of liquid metal marbles, which are liquid metal droplets encased in micro/nanoparticles. The WO3 nanoparticles coated marbles are placed in H2O2 solution, and their surfaces are illuminated with UV light. The semiconducting WO3 coating behaves as a photocatalyst to trigger a photochemical reaction, generating oxygen bubbles that propel the marble. The actuation of the marbles is investigated under different H2O2 concentrations, light intensities, and marble dimensions. Equations describing the fundamentals of such actuations are presented.

Photochemically induced motion of liquid metal marbles

In this Letter, the broadband operation in wavelengths from 520 nm to 980 nm is demonstrated on silicon nitride nanophotonic phased arrays. The widest beam steering angle of 65° on a silicon nitride phased array is achieved. The optical radiation efficiency of the main grating lobe in a broad wavelength range is measured and analyzed theoretically. The optical spots radiated from the phased array chip are studied at different wavelengths of lasers. The nanophotonic phased array is excited by a supercontinuum laser source for a wide range of beam steering for the first time to the best of our knowledge. It paves the way to tune the wavelength from visible to near infrared range for silicon nitride nanophotonic phased arrays.

Broadband silicon nitride nanophotonic phased arrays for wide-angle beam steering.

Underwater wireless optical communication (UWOC) will play an important role in the underwater environment exploration and marine resource development due to its advantages of high data rate and good mobility. However, the significant signal power attenuation in the underwater channel limits the transmission distance of UWOC. Attenuation length (AL) is widely used as an indicator for evaluating the UWOC system's long-distance transmission capability. At present, Gbps UWOC is limited within 7AL. Using a SiPM based receiver can dramatically increase the AL that UWOC can support. In this paper, a novel UWOC receiver built from an off-the-shelf SiPM has been demonstrated. The finite pulse width and limited bandwidth of SiPM limit the SiPM based UWOC system's data rate. To boost the system's data rate, an optimum method to process the SiPM's signal has therefore been investigated. Based on these methods, the communication capabilities of the SiPM based UWOC have been investigated experimentally. Results show that the SiPM based receiver can support 11.6AL without turbulence and 9.28AL within weak turbulence (scintillation index = 0.0447) at 1 Gbps.

Over 10 attenuation length gigabits per second underwater wireless optical communication using a silicon photomultiplier (SiPM) based receiver.

In underwater optical wireless communication (UOWC) systems, using single photon avalanche photondiode (SPAD) as the detector can improve the transmission distance. However, the signal detection for SPAD-based systems is greatly challenged by the complex optical channel characteristics and SPAD nonlinear distortion. To address this issue, a novel deep learning aided signal detection scheme is proposed in this paper. By exploiting the physical mechanism and prior expert knowledge of the signal processing, a two-connected multilayer perception (MLP) network is integrated into the receiver. The first subnetwork is regarded as a channel compensation block while the second one works as a demodulator. With sophisticated numerical optical channel model and SPAD non-Poisson model, large amounts of training data are utilized to train the proposed model offline. Afterwards, the online data are recovered with the trained network. Simulation results verify that significant bit error ratio (BER) improvement can be achieved with the proposed scheme.

Xinke Tang

Papers

Electrochemically induced actuation of liquid metal marbles

Photochemically induced motion of liquid metal marbles

Broadband silicon nitride nanophotonic phased arrays for wide-angle beam steering.

Over 10 attenuation length gigabits per second underwater wireless optical communication using a silicon photomultiplier (SiPM) based receiver.

Deep Learning Aided Signal Detection for SPAD-Based Underwater Optical Wireless Communications