The term photonic crystals appears because of the analogy between electron waves in crystals and the light waves in artificial periodic dielectric structures. During the recent years the investigation of one-, two-and three-dimensional periodic structures has attracted a widespread attention of the world optics community because of great potentiality of such structures in advanced applied optical fields. The interest in periodic structures has been stimulated by the fast development of semiconductor technology that now allows the fabrication of artificial structures, whose period is comparable with the wavelength of light in the visible and infrared ranges.

http://ieeexplore.ieee.org/iel5/6354/16969/00781867.pdf

Photonic crystals

“Life is branched” was the motto of a special issue of Macromolecular Chemistry and Physics1 on “Branched Polymers”, indicating that branching is of similar importance in the world of synthetic macromolecules as it is in nature. The significance of branched macromolecules has evolved over the last 30 years from just being considered as a side reaction in polymerization or as a precursor step in the formation of networks. Important to this change in perception of branching was the concept of “polymer architectures”, which formed on new starand graft-branched structures in the 1980s and then in the early 1990s on dendrimers and dendritic polymers. Today, clearly, controlled branching is considered to be a major aspect in the design of macromolecules and functional material. Hyperbranched (hb) polymers are a special type of dendritic polymers and have as a common feature a very high branching density with the potential of branching in each repeating unit. They are usually prepared in a one-pot synthesis, which limits the control on molar mass and branching accuracy and leads to “heterogeneous” products with a distribution in molar mass and branching. This distinguishes hyperbranched polymers from perfectly branched and monodisperse dendrimers. In the last 20 years, both classes of dendritic polymers, dendrimers as well as hb polymers, have attracted major attention because of their interesting properties resulting from the branched architecture as well as the high number of functional groups.2 The challenging synthesis of the dendrimers attracted especially scientists with a strong organic chemistry background and led to beautifully designed macromolecules, which allowed a deeper insight into the effect of branching and functionality. Dendrimers have been considered as perfect “nano-objects” where one can control perfectly size and functionality, which is of high interest in nanotechnology and biomedicine. hb polymers, however, were considered from the beginning as products suitable for larger-scale application in typical polymer fields like coatings and resins, where a perfect structure is sacrificed for an easy and affordable synthetic route. Thus, the first structures that were reported paralleled the chemistry used for linear polymers like typical polycondensation for polyester synthesis. More recently, unconventional synthetic methods have been adopted also for hb polymers and related structures. Presently, a vast variety of highly branched structures have been realized and studied regarding their properties and potential application fields. Excellent reviews appeared covering synthesis strategies, properties, and applications, like the very recent tutorial by Carlmark et al.,3 the comprehensive book on hyperbranched polymers covering extensively synthesis and application * E-mail: voit@ipfdd.de; lederer@ipfdd.de. Chem. Rev. 2009, 109, 5924–5973 5924

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Hyperbranched and highly branched polymer architectures--synthetic strategies and major characterization aspects.

We analyze theoretically the optical properties of ideal semiconductor crystallites so small that they show quantum confinement in all three dimensions [quantum dots (QD's)]. In the limit of a QD much smaller than the bulk exciton size, the linear spectrum will be a series of lines, and we consider the phonon broadening of these lines. The lowest interband transition will saturate like a two-level system, without exchange and Coulomb screening. Depending on the broadening, the absorption and the changes in absorption and refractive index resulting from saturation can become very large, and the local-field effects can become so strong as to give optical bistability without external feedback. The small QD limit is more readily achieved with narrow-band-gap semiconductors.

Theory of the linear and nonlinear optical properties of semiconductor microcrystallites

We present a detailed overview of stimulated Brillouin scattering (SBS) in
 single-mode optical fibers. The review is divided into two parts. In the first part,
 we discuss the fundamentals of SBS. A particular emphasis is given to analytical
 calculation of the backreflected power and SBS threshold (SBST) in optical fibers
 with various index profiles. For this, we consider acousto-optic interaction in the
 guiding geometry and derive the modal overlap integral, which describes the
 dependence of the Brillouin gain on the refractive index profile of the optical
 fiber. We analyze Stokes backreflected power initiated by thermal phonons, compare
 values of the SBST calculated from different approximations, and discuss the SBST
 dependence on the fiber length. We also review an analytical approach to calculate
 the gain of Brillouin fiber amplifiers (BFAs) in the regime of pump depletion. In the
 high-gain regime, fiber loss is a nonnegligible effect and needs to be accounted for
 along with the pump depletion. We provide an accurate analytic expression for the BFA
 gain and show results of experimental validation. Finally, we review methods to
 suppress SBS including index-controlled acoustic guiding or segmented fiber links.
 The second part of the review deals with recent advances in fiber-optic applications
 where SBS is a relevant effect. In particular, we discuss the impact of SBS on the
 radio-over-fiber technology, enhancement of the SBS efficiency in Raman-pumped
 fibers, slow light due to SBS and SBS-based optical delay lines, Brillouin
 fiber-optic sensors, and SBS mitigation in high-power fiber lasers, as well as SBS in
 multimode and microstructured fibers. A detailed derivation of evolutional equations
 in the guided wave geometry as well as key physical relations are given in
 appendices.

Stimulated Brillouin scattering in optical fibers

Rapid developments in advanced photonic devices have led to the increasing exploration of high refractive index (high-n) materials, particularly high-refractive-index polymers (HRIP). High refractive indices have been achieved either by introducing substituents with high molar refractions to make intrinsic HRIPs or by combining high-nnanoparticles with polymer matrixes to make HRIP nanocomposites. For intrinsic HRIPs, aromatic rings, sulfur-containing groups, halogens except fluorine and organometallic moieties are often utilized to increase their refractive indices. However, their upper n limitation is usually below 1.80. Incorporation of high-nnanoparticles into polymers seems to be a more promising strategy to achieve a refractive index higher than 1.80; however, the obtained organic–inorganic hybrid materials sometimes suffer from poor storage stability, higher optical loss and poor processability. Besides the refractive index, optical dispersion (Abbe number), birefringence and optical transparency are often involved in designing HRIPs for practical optical fabrications. Therefore, research of HRIPs is becoming an interdisciplinary subject. This feature article reviews recent developments in optical HRIPs and their typical applications in high-tech fields.

High refractive index polymers: fundamental research and practical applications

We demonstrate permanent holographic storage in the green with high diffraction efficiency and recording sensitivity in TiO2 nanoparticle-dispersed methacrylate photopolymer films. It is shown that the diffraction efficiency as well as the recording sensitivity significantly increase with an increase of nanoparticle concentration. It is also found that volumetric shrinkage during holographic exposure is noticeably suppressed by inclusion of the nanoparticles.

Holographic recording in TiO2 nanoparticle-dispersed methacrylate photopolymer films

We demonstrate and characterize volume holographic recording in ZrO2 nanoparticle-dispersed acrylate photopolymer films that have very low scattering loss. More than thirty-fold reduction in the scattering coefficient, as compared with those of previously reported TiO2 nanoparticle-dispersed photopolymers, is achieved. It is shown that the refractive index modulation as high as 5.3×10-3, together with substantive photopolymerization-shrinkage suppression, is obtained at the nanoparticle concentration of 15 vol.%. Dependences of nanoparticle concentration and grating spacing on the refractive index modulation are also investigated.

Highly transparent ZrO(2) nanoparticle-dispersed acrylate photopolymers for volume holographic recording.

We demonstrate volume holographic recording in silica-nanoparticle-dispersed methacrylate photopolymers with reduced scattering loss as low as 2%. This is made possible by use of 13-nm silica nanoparticles. As a result a net diffraction efficiency near 100% is achieved for a transmission volume hologram of 45-μm thickness. Grating buildup dynamics are measured for various nanoparticle concentrations, and the effects of nanoparticle size on refractive-index modulation and polymerization shrinkage are also evaluated.

Silica-nanoparticle-dispersed methacrylate photopolymers with net diffraction efficiency near 100%.

We report on experimental verification of mass transfer of nanoparticles during holographic recording in nanoparticle-dispersed photopolymers. Through direct observations of the microscopic structure of recorded holograms as well as optical measurements of the phase shift between the light interference pattern and a recorded hologram we find that holographic exposure causes nanoparticles to be redistributed from bright to dark regions, leading to periodic assembly of nanoparticles and thereby to formation of high-contrast holograms.

Holographic manipulation of nanoparticle distribution morphology in nanoparticle-dispersed photopolymers

We report on the photopolymerization kinetics and volume holographic recording characteristics of silica nanoparticle-polymer composites using thiol-ene monomers capable of step-growth polymerization. Real-time Fourier transform spectroscopy and photocalorimetry are used to characterize the visible light curing kinetics of a thiol-ene monomer system consisting of secondary dithiol with high self-life stability and low odor and triene with rigid structure and high electron density. It is shown that while the nanoparticle-(thiol-ene)polymer composites exhibit high transparency, their saturated refractive index modulation (Δnsat ) and material sensitivity (S) are as large as 1×10−2 and 1615 cm/J, respectively. The polymerization shrinkage is reduced as low as 0.4% as a result of the late gelation in conversion. These values meet the acceptable values for holographic data storage media (i.e., 5×10−3, 500 cm/J and 0.5% for Δnsat, S and shrinkage, respectively). It is also shown that because of the dispersion of inorganic silica nanoparticles and the use of the triene monomer having the rigid structure of the triazine functional group, the thermal stability of recorded holograms is much improved over our previously reported nanoparticle-polymer composites using organic nanoparticles and primary mercaptopropionate trithiol/allyl ether triene monomers [Opt. Lett. 35, 396 (2010)].

Yasuo Tomita

Papers

Holographic recording in TiO2 nanoparticle-dispersed methacrylate photopolymer films

Highly transparent ZrO(2) nanoparticle-dispersed acrylate photopolymers for volume holographic recording.

Silica-nanoparticle-dispersed methacrylate photopolymers with net diffraction efficiency near 100%.

Holographic manipulation of nanoparticle distribution morphology in nanoparticle-dispersed photopolymers

Holographic nanoparticle-polymer composites based on step-growth thiol-ene photopolymerization