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Yu. I. Baukov

Researcher at Russian National Research Medical University

Publications -  112
Citations -  953

Yu. I. Baukov is an academic researcher from Russian National Research Medical University. The author has contributed to research in topics: Hypervalent molecule & Trimethylsilyl. The author has an hindex of 15, co-authored 108 publications receiving 848 citations. Previous affiliations of Yu. I. Baukov include Russian Academy of Sciences & Russian Academy.

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Modern Trends of Organic Chemistry in Russian Universities

A. I. Konovalov, +84 more
TL;DR: In this paper, a review devoted to the scientific achievements of the departments of organic chemistry in higher schools of Russia within the past decade is presented, focusing on the recent years of the 1990s.
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Model of the SN2 nucleophilic substitution at the Si atom: X-ray structural study of N-(halogenodimethylsilylmethyl) lactams

TL;DR: In this article, the tetrahedral Si atom in N-(halogenodimethylsilylmethyl) lactams has been shown to vary over a wide range [1.749(2)−2.461(8) and 3.734(1)−1.630(7)A, respectively] in the series X = I → Br → Cl → F.
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Stereochemical non-rigidity of complexes of hypercoordinate Group 14 elements

TL;DR: In this article, published data on stereodynamic processes in the coordination units of di-and tetravalent silicon, germanium, tin and lead compounds are summarized and analyzed.
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Dynamic stereochemistry of hypervalent silicon, germanium and tin compounds containing amidomethyl C,O-chelating ligands

TL;DR: The results of NMR-spectroscopy studies of the structure, dynamic stereochemistry, and intermolecular interactions in solutions of organic derivatives of penta-and hexacoordinated silicon, germanium, and tin containing amidomethyl, lactamide, and related bidentate ligands are surveyed in this paper.
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Rearrangement of β-silyl ketones into O-silyl-substituted enols

TL;DR: In this paper, the conditions for the rearrangement of β-silylketones to O -Silyl-substituted enols are reported. And the mechanism of irreversible isomerisation of the organosilicon O - and C -derivatives of keto-enolic systems is discussed.