https://orbit.dtu.dk/files/3249858/2007_333.pdf

Critical comparison of radiometric and mass spectrometric methods for the determination of radionuclides in environmental, biological and nuclear waste samples.

Cross sections for residual nuclide production by p-induced reactions were measured from thresholds up to 2.6 GeV using accelerators at CERN/Geneve, IPN/Orsay, KFA/Julich, LANL/Los Alamos, LNS/Saclay, PSI/Villigen, TSL/Uppsala, LUC/Louvain La Neuve. The target elements C, N, O, Mg, Al, Si, Ca, Ti, V, Mn, Fe, Co, Ni, Cu, Sr, Y, Zr, Nb, Ba and Au were investigated. Residual nuclides were measured by X- and γ-spectrometry and by Accelerator Mass Spectrometry (AMS). The measured cross sections were corrected for interfering secondary particles in experiments with primary proton energies above 200 MeV. Our consistent database covers presently ca 550 nuclear reactions and contains nearly 15000 individual cross sections of which about 10000 are reported here for the first time. They provide a basis for model calculations of the production of cosmogenic nuclides in extraterrestrial matter by solar and galactic cosmic ray protons. They are of importance for many other applications in which medium energy nuclear reactions have to be considered ranging from astrophysics over space and environmental sciences to accelerator technology and accelerator-based nuclear waste transmutation and energy amplification. The experimental data are compared with theoretical ones based on calculations using an INC/E model in form of the HETC/KFA2 code and on the hybrid model of preequilibrium reactions in form of the AREL code.

Cross sections for the production of residual nuclides by low- and medium-energy protons from the target elements c, n, o, mg, al, si, ca, ti, v, mn, fe, co, ni, cu, sr, y, zr, nb, ba and au

The kinetics of water absorption in epoxide materials was studied by the aid of a diglycidyl ether of bisphenol-A–triethylenetetramine (DGEBA–TETA) epoxy–resin system containing various amounts of the plasticizer THIOCOL (0–40 phr). The presence of plasticizer permits the formation of products with different crosslinking densities and hydrophilic characters. Dynamic water absorption experiments were carried out at 15, 40, and 70°C. For the fitting of the experimental results, a new model was used, based on a model proposed earlier by Jacobs and Jones. This model considers epoxide product as a two-phase system consisting of a master phase (where the major part of the water is absorbed), which is homogeneous and nonpolar (phase 1), and of a second phase with different density and/or hydrophilic character (phase 2). By making the assumption that water diffusion can take place independently in the different phases of the material in accordance with Fick's second law, we can calculate the diffusion coefficient D and the water content at saturation M∞ for each phase separately. Equilibrium water sorption measurements were performed at 40°C, and the data were analyzed and discussed based on the Guggenheim–Anderson–de Boer (GAB) equation, the results being in support of the two-phase model used in the analysis of absorption kinetics. The linear expansion coefficient and the glass transition temperature of the materials, employed in the discussion of the results, were measured by thermomechanical analysis. © 1999 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 37: 1165–1182, 1999

Water sorption and diffusion studies in an epoxy resin system

Absorbed moisture can degrade the physical properties of an epoxy resin, jeopardizing the performance of an epoxy-based component. Although specific water- epoxy interactions are known to be very important in determining transport behavior, the role of network topology is not clear. In this article, a series of epoxies in which the topology is systematically varied (and the polarity held constant) is used to explore how topology influences the kinetics of moisture transport. The topology is quantified via the positron annihilation lifetime spectroscopy technique in terms of the size and volume fraction of electron density heterogeneities 5- 6 A in diameter, a dimension comparable to the 3-A kinetic diameter of a water molecule. Surprisingly, the volume fraction of such nanopores does not affect the diffusion coefficient (D) of water in any of the resins studied. For temperatures at and below 35 °C, there is a mild exponential dependence of D on the average nanopore size observed. Otherwise, the kinetics of moisture transport do not appear to depend on the nanopores. However, the initial flux of moisture into the epoxy does appear to correlate with the intrinsic hole volume fraction. That this correlation persists only in the initial stages of absorption is partially understood in terms of the ability of the water to alter the nanopore structure; only in the initial stages of uptake are the nanopores, as quantified in the dry state, relevant to transport. The role of specific epoxy-water interactions are also discussed in terms of transport kinetics. The lack of a correlation between the topology and transport sug- gests that polar interactions, and not topology, provide the rate-limiting step of trans- port. © 2000 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 38: 776 -791, 2000

https://deepblue.lib.umich.edu/bitstream/handle/2027.42/35005/15_ftp.pdf;sequence=1

Contributions of the nanovoid structure to the kinetics of moisture transport in epoxy resins

Gas sorption and permeation of glassy polymers with microvoids

Positron irradiation effects on polypropylene and polyethylene studied by positron annihilation

Degradation of Gd 2 SiO 5 :Ce in optical transmittance due to proton irradiation was negligibly small below 10 6 rad, smaller than 2%/cm at 10 7 rad and large at 10 8 rad. The radiation hardness of 10 7 rad against protons is by two orders of magnitude smaller than against low energy γ-rays. Long term spontaneous recovery of the proton-induced damage is not large (10–20% of the initial degradation in 84 days). Recovery upon exposure to UV light occurs to some extent. Degradation due to thermal neutrons was negligibly small for a fluence of 10 14 n/cm 2 . No degradation was observed for exposure to fast neutrons of about 10 13 n/cm 2 during one year in the extracted beam tunnel of proton synchrotron.

Yuichi Oki

Papers

Positron irradiation effects on polypropylene and polyethylene studied by positron annihilation

Radiation hardness of cerium-doped gadolinium silicate Gd2SiO5:Ce against high energy protons, fast and thermal neutrons

Radiation effect on polypropylene studied by the relaxational behaviour at low temperature using positron annihilation

Free-volume characteristics and water absorption of novolac epoxy resins investigated by positron annihilation

Effects of aging and oxidation on positronium formation in polyethylenes