Wetting phenomena are ubiquitous in nature and technology. A solid substrate exposed to the environment is almost invariably covered by a layer of fluid material. In this review, the surface forces that lead to wetting are considered, and the equilibrium surface coverage of a substrate in contact with a drop of liquid. Depending on the nature of the surface forces involved, different scenarios for wetting phase transitions are possible; recent progress allows us to relate the critical exponents directly to the nature of the surface forces which lead to the different wetting scenarios. Thermal fluctuation effects, which can be greatly enhanced for wetting of geometrically or chemically structured substrates, and are much stronger in colloidal suspensions, modify the adsorption singularities. Macroscopic descriptions and microscopic theories have been developed to understand and predict wetting behavior relevant to microfluidics and nanofluidics applications. Then the dynamics of wetting is examined. A drop, placed on a substrate which it wets, spreads out to form a film. Conversely, a nonwetted substrate previously covered by a film dewets upon an appropriate change of system parameters. The hydrodynamics of both wetting and dewetting is influenced by the presence of the three-phase contact line separating "wet" regions from those that are either dry or covered by a microscopic film only. Recent theoretical, experimental, and numerical progress in the description of moving contact line dynamics are reviewed, and its relation to the thermodynamics of wetting is explored. In addition, recent progress on rough surfaces is surveyed. The anchoring of contact lines and contact angle hysteresis are explored resulting from surface inhomogeneities. Further, new ways to mold wetting characteristics according to technological constraints are discussed, for example, the use of patterned surfaces, surfactants, or complex fluids.

/pdf/wetting-and-spreading-56ditqbfmj.pdf

Wetting and Spreading

The review deals with drop impacts on thin liquid layers and dry surfaces. The impacts resulting in crown formation are referred to as splashing. Crowns and their propagation are discussed in detail, as well as some additional kindred, albeit nonsplashing, phenomena like drop spreading and deposition, receding (recoil), jetting, fingering, and rebound. The review begins with an explanation of various practical motivations feeding the interest in the fascinating phenomena of drop impact, and the above-mentioned topics are then considered in their experimental, theoretical, and computational aspects.

Drop Impact Dynamics: Splashing, Spreading, Receding, Bouncing ...

The numerical simulation of flows with interfaces and free-surface flows is a vast topic, with applications to domains as varied as environment, geophysics, engineering, and fundamental physics. In engineering, as well as in other disciplines, the study of liquid-gas interfaces is important in combustion problems with liquid and gas reagents. The formation of droplet clouds or sprays that subsequently burn in combustion chambers originates in interfacial instabilities, such as the Kelvin-Helmholtz instability. What can numerical simulations do to improve our understanding of these phenomena? The limitations of numerical techniques make it impossible to consider more than a few droplets or bubbles. They also force us to stay at low Reynolds or Weber numbers, which prevent us from finding a direct solution to the breakup problem. However, these methods are potentially important. First, the continuous improvement of computational power (or, what amounts to the same, the drop in megaflop price) continuously extends the range of affordable problems. Second, and more importantly, the phenomena we consider often happen on scales of space and time where experimental visualization is difficult or impossible. In such cases, numerical simulation may be a useful prod to the intuition of the physicist, the engineer, or the mathematician. A typical example of interfacial flow is the collision between two liquid droplets. Finding the flow involves the study not only of hydrodynamic fields in the air and water phases but also of the air-water interface. This latter part

Direct numerical simulation of free-surface and interfacial flow

Surface-tension-driven flows and, in particular, their tendency to decay spontaneously into drops have long fascinated naturalists, the earliest systematic experiments dating back to the beginning of the 19th century. Linear stability theory governs the onset of breakup and was developed by Rayleigh, Plateau, and Maxwell. However, only recently has attention turned to the nonlinear behavior in the vicinity of the singular point where a drop separates. The increased attention is due to a number of recent and increasingly refined experiments, as well as to a host of technological applications, ranging from printing to mixing and fiber spinning. The description of drop separation becomes possible because jet motion turns out to be effectively governed by one-dimensional equations, which still contain most of the richness of the original dynamics. In addition, an attraction for physicists lies in the fact that the separation singularity is governed by universal scaling laws, which constitute an asymptotic solution of the Navier-Stokes equation before and after breakup. The Navier-Stokes equation is thus continued uniquely through the singularity. At high viscosities, a series of noise-driven instabilities has been observed, which are a nested superposition of singularities of the same universal form. At low viscosities, there is rich scaling behavior in addition to aesthetically pleasing breakup patterns driven by capillary waves. The author reviews the theoretical development of this field alongside recent experimental work, and outlines unsolved problems.

/pdf/nonlinear-dynamics-and-breakup-of-free-surface-flows-2oabav2z0g.pdf

Nonlinear dynamics and breakup of free-surface flows

Jets, ie collimated streams of matter, occur from the microscale up to the large-scale structure of the universe Our focus will be mostly on surface tension effects, which result from the cohesive properties of liquids Paradoxically, cohesive forces promote the breakup of jets, widely encountered in nature, technology and basic science, for example in nuclear fission, DNA sampling, medical diagnostics, sprays, agricultural irrigation and jet engine technology Liquid jets thus serve as a paradigm for free-surface motion, hydrodynamic instability and singularity formation leading to drop breakup In addition to their practical usefulness, jets are an ideal probe for liquid properties, such as surface tension, viscosity or non-Newtonian rheology They also arise from the last but one topology change of liquid masses bursting into sprays Jet dynamics are sensitive to the turbulent or thermal excitation of the fluid, as well as to the surrounding gas or fluid medium The aim of this review is to provide a unified description of the fundamental and the technological aspects of these subjects

Physics of liquid jets

Direct numerical simulations are conducted for a Newtonian drop in a Newtonian matrix subjected to large amplitude oscillatory shear flows. In the experimental study of Guido et al. (in Rheol Acta 43:575–583, 2004), the drop shape is found to oscillate at higher harmonics of the forcing frequency when the capillary number is increased. Their phenomenological model requires a much smaller capillary number for predicting the harmonic nature of the experimental data. In this paper, computational results on the evolution of drop length and inclination angle are obtained at the same fluid and flow properties as the experiments, and are shown to reasonably reproduce the experimental data. In particular, the computed velocity fields around the drop are shown to elucidate the over-rotation, which is a mechanism for the experimentally observed harmonics.

Numerical simulation of a drop undergoing large amplitude oscillatory shear

We study the stability of viscometric flow using the type of short memory introduced by Akbay, Becker, Krozer and Sponagel. The instability found by these researchers is recognized as a “change of type” leading to non-evolutionary character of the governing equations. We also address the question of justification for the short memory assumption and find that it cannot be justified for some of the more popular rheological models.

/pdf/remarks-on-the-stability-of-viscometric-flow-598lvulfwf.pdf

Remarks on the Stability of Viscometric Flow.

The two-layer Couette flow of superposed Giesekus liquids is examined. In order to emphasize the effect of a jump in the second normal stress difference, the analysis is focused on flows where the shear rate and first normal stress difference are continuous across the interface. In this case, the flow is neutrally stable to streamwise disturbances, but can be unstable for spanwise disturbances driven by a jump in the second normal stress difference. Whether the long and order one waves are stable or not depends on the sign of this difference. Short waves are unstable. In the case of order one wave instability, the mode of maximum growth rate gives rise to stationary ripples perpendicular to the flow. The eigenvalue problem for purely spanwise wave vectors can in principle be solved analytically, although, in general, the analytical solution is too complicated to obtain. In most cases, however, a simplifying assumption can be made which makes analytical solutions feasible. We present such solutions and compare them with purely numerical solutions.

Instability due to second normal stress jump in two-layer shear flow of the Giesekus fluid

A layer of fluid lies between two parallel horizontal walls and the solute concentration and temperature are higher at the bottom wall. The onset of time‐periodic instability in this double diffusion problem in three dimensions is analyzed. Periodicity with respect to the hexagonal lattice is assumed. The no‐slip condition is imposed at the top and bottom boundaries. There are 11 bifurcating solutions, and their stability is presented. For relatively low solutal and thermal Rayleigh numbers, the solutions are found to be unstable. For the heating of salty water, situations are presented where the standing rolls, the standing patchwork quilt, and either the standing hexagons or the standing regular triangles, may be stable.

Pattern selection for the oscillatory onset in thermosolutal convection

We consider the linear stability of inviscid parallel shear flow with a free surface. Gravity is included in the analysis, but surface tension is not. We focus on several specific profiles including Poiseuille flow and various profiles with inflection points. Instabilities are found in all the profiles we studied. At neutral limiting modes, the wave speed of the disturbance is equal to one of three choices: the fluid speed at the bottom, an extremum of the fluid speed, or an inflectional value. The results help to clarify conflicting claims in prior literature.

Yuriko Renardy

Papers

Numerical simulation of a drop undergoing large amplitude oscillatory shear

Remarks on the Stability of Viscometric Flow.

Instability due to second normal stress jump in two-layer shear flow of the Giesekus fluid

Pattern selection for the oscillatory onset in thermosolutal convection

On the Stability of Inviscid Parallel Shear Flows with a Free Surface