Z
Zhen Long
Researcher at East China Normal University
Publications - 10
Citations - 89
Zhen Long is an academic researcher from East China Normal University. The author has contributed to research in topics: Derivative (chemistry) & Amine gas treating. The author has an hindex of 3, co-authored 10 publications receiving 58 citations.
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Journal ArticleDOI
Cascade Reaction of Propargyl Amines with AgSCF3, as Well as One-Pot Reaction of Propargyl Amines, AgSCF3, and Di- tert-butyl Peroxide: Access to Allenyl Thiocyanates and Allenyl Trifluoromethylthioethers.
TL;DR: An efficient cascade reaction of propargyl amines with AgSCF3 and KBr is developed, affording allenyl thiocyanates at room temperature in high yields via a "one-pot" three-step process.
Journal ArticleDOI
Synthesis of Thiocarbamoyl Fluorides and Isothiocyanates Using CF3SiMe3 and Elemental Sulfur or AgSCF3 and KBr with Amines
TL;DR: AgSCF3 reacts with secondary/primary amines under KBr at room temperature, affording quantitative thiocarbamoyl fluorides/isothiocyanates, which feature late-stage application.
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Iron(III)-Catalyzed Domino Claisen Rearrangement/Regio- and Chemoselective Aerobic Dehydrogenative Cyclization of β-Naphthyl-Substituted-Allenylmethyl Ether.
TL;DR: An FeCl3-catalyzed allenic Claisen rearrangement/regio- and chemoselective aerobic dehydrogenative cyclization domino reaction is developed, providing a wide range of 2-aryl/alkyl, 3-(substituted-vinyl)naphtho[2,1- b]furans in high yields at 95-130 °C in an atom- and step-economic fashion.
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Cobalt-Catalyzed Switchable Intramolecular Thioenolization/C-H Thiolation and C(sp2)-H/C(sp3)-H Dehydrogenative Coupling.
TL;DR: The selectivity for either product is achieved by accessing unique catalytic cycles involving different valence states for cobalt, as well as through an electrophilic cobaltation(III) pathway.