Z
Zhengkun Yu
Researcher at Chinese Academy of Sciences
Publications - 236
Citations - 7372
Zhengkun Yu is an academic researcher from Chinese Academy of Sciences. The author has contributed to research in topics: Catalysis & Ketene. The author has an hindex of 45, co-authored 236 publications receiving 6356 citations. Previous affiliations of Zhengkun Yu include Iowa State University & Dalian Institute of Chemical Physics.
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Journal ArticleDOI
Brønsted Acid-Promoted Cascade Alkylation/Cyclization of Pyrroles with N,N-Dimethylaminomethyleneglutaconic Acid Dinitrile: A Concise Route to Cyclopenta[b]pyrroles
TL;DR: In this paper, the 2-alkylated pyrrole was confirmed by isolation and transformation of the reactio ni nter-mediate, i.e., the 2 -alkylation pyrrorole.
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Substitution of Alcohols by N-Nucleophiles via Transition Metal-Catalyzed Dehydrogenation
Qin Yang,Qingfu Wang,Zhengkun Yu +2 more
TL;DR: In this article, transition metal-catalyzed dehydrogenative substitution of alcohols by N-nucleophiles has been studied for the first time in the last decade.
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α,β-Unsaturated N-Acylindoles: An Alternative Class of Michael Acceptors and Their Application in Asymmetric Borylation.
Quanbin Jiang,Tenglong Guo,Runli Gao,Quannan Wang,Quannan Wang,Jiang Lou,Jiang Lou,Zhengkun Yu,Zhengkun Yu +8 more
TL;DR: The present work provides an alternative class of Michael acceptors, that is, α,β-unsaturated N-acylindoles, for potential asymmetric transformations, and affording the enantioenriched products in excellent yields with up to 99% ee.
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Highly Efficient Route to Diselenides from the Reactions of Imines and Selenium in the Presence of Carbon Monoxide and Water
Xiaodan Zhao,Zhengkun Yu,Fanlong Zeng,Jinzhu Chen,Xiaowei Wu,Sizhong Wu,Wen-Jing Xiao,Zhaoyan Zheng +7 more
TL;DR: In this paper, the reaction of selenium with imines (RR 1 C¼NR 2 ) of aldehydes and ketones in the pres- ence of carbon monoxide, water and triethylamine lead to reductive selenation, on aerobic work-up, to afford symmetrical diselenides in good to excellent yields.
Journal ArticleDOI
Reductive desulfurization of organosulfur compounds with sodium in liquid ammonia
Zhengkun Yu,John G. Verkade +1 more
TL;DR: In this article, it was shown that 95% sulfur removal rate was achieved when dialkyl mono or polysulfides were treated with Na in liquid ammonia, while phenylthio derivatives gave thiophenol as the major product and dithiophenols as minor products.