Z
Zhong-Liang Li
Researcher at Southern University of Science and Technology
Publications - 26
Citations - 1493
Zhong-Liang Li is an academic researcher from Southern University of Science and Technology. The author has contributed to research in topics: Enantioselective synthesis & Alkyl. The author has an hindex of 14, co-authored 26 publications receiving 680 citations.
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Recent advances in copper-catalysed radical-involved asymmetric 1,2-difunctionalization of alkenes
TL;DR: This tutorial review highlights the recent progress in copper-catalysed radical-involved asymmetric 1,2-difunctionalization of alkenes and the mechanistic scenarios governing the stereocontrol, with an emphasis on utilization of chiral ligands.
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Copper(I)-Catalyzed Asymmetric Reactions Involving Radicals.
TL;DR: The authors' copper-catalyzed asymmetric reactions with alkyl radicals provide expedient access to a diverse range of valuable chiral molecules with broad application potential in areas of organic synthesis, medicine, agrochemical, and material sciences.
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A general asymmetric copper-catalysed Sonogashira C(sp 3)-C(sp) coupling
Xiao-Yang Dong,Yu-Feng Zhang,Can-Liang Ma,Qiang-Shuai Gu,Fu-Li Wang,Zhong-Liang Li,Sheng-Peng Jiang,Xin-Yuan Liu +7 more
TL;DR: A versatile, enantioconvergent Sonogashira coupling via a radical intermediate that is demonstrated in the facile synthesis of stereoenriched bioactive or functional molecule derivatives, medicinal compounds and natural products that feature a range of chiral C( sp3)–C(sp/sp2/sp3) bonds.
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Direct Photocatalytic Synthesis of Medium-Sized Lactams by C-C Bond Cleavage.
TL;DR: Reported is a novel two-step ring-expansion strategy for expeditious synthesis of all ring sizes of synthetically challenging (hetero)aryl-fused medium-sized lactams from readily available 5-8-membered cyclic ketones.
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Copper-catalyzed enantioselective Sonogashira-type oxidative cross-coupling of unactivated C( sp 3 )−H bonds with alkynes
TL;DR: A copper/chiral cinchona alkaloid-based N,N,P-ligand catalyst for asymmetric oxidative cross-coupling of unactivated C(sp3)—H bonds with terminal alkynes in a highly regio-, chemo-, and enantioselective manner is reported.