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Zhuo Zeng

Researcher at South China Normal University

Publications -  13
Citations -  162

Zhuo Zeng is an academic researcher from South China Normal University. The author has contributed to research in topics: Bond cleavage & Aryl. The author has an hindex of 6, co-authored 13 publications receiving 106 citations. Previous affiliations of Zhuo Zeng include Chinese Academy of Sciences & Hunan University.

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One-Pot Synthesis of Arylketones from Aromatic Acids via Palladium-Catalyzed Suzuki Coupling

TL;DR: A palladium-catalyzed one-pot procedure for the synthesis of aryl ketones in moderate to excellent yields in the presence of 1 mol % Pd(PPh3)2Cl2 for 30 min.
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Palladium-Catalyzed Decarbonylative Suzuki-Miyaura Coupling of Amides To Achieve Biaryls via C-N Bond Cleavage.

TL;DR: The palladium-catalyzed decarbonylative Suzuki-Miyaura coupling of amides via selective amides C-N bond cleavage was reported, which afforded a mild access to substitute biaryl products in the presence of low catalyst loading with NaHCO3 as base in good yields within 4 hours.
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Unexpected Intramolecular Cyclization of 2‐(Perfluoroalkyl)tetraarylporphyrin Radicals: Approaches for the Intramolecular Cyclization of 2‐(Perfluoroalkyl)tetraarylporphyrin Radicals

TL;DR: The reaction of I(CF2nX (n = 2−5; X = I, Cl) with porphyrins in the presence of Na2S2O4/NaHCO3 in DMSO/CH2Cl2/DMSO, undergo cyclizations at the ortho position of a neighbouring phenyl ring and/or adjacent pyrrolic unit to give five-, six-, seven-, and eight-membered fused porphrin this article.
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C−F Bond Activation by Modified Sulfinatodehalogenation: Facile Synthesis and Properties of Novel Tetrafluorobenzoporphyrins by Direct Intramolecular Cyclization and Reductive Defluorinative Aromatization of Readily Available β-Perfluoroalkylated Porphyrins

TL;DR: It was found that the amount of sodium dithionite, base, and central metal ion of substrate porphyrins play important roles in the reaction and that further reduction of C-F bonds of the products was not observed under the optimal conditions indicates the high selectivity of the reaction.