A simple sol–gel technique for preparing lanthanum oxide nanopowders

Cesium seeded sources for surface generated negative hydrogen ions are major components of neutral beam injection systems in future large-scale fusion experiments such as ITER. The stability and delivered current density depend highly on the work function during vacuum and plasma phases of the ion source. One of the most important quantities that affect the source performance is the work function. A modified photocurrent method was developed to measure the temporal behavior of the work function during and after cesium evaporation. The investigation of cesium exposed Mo and MoLa samples under ITER negative hydrogen ion based neutral beam injection relevant surface and plasma conditions showed the influence of impurities which result in a fast degradation when the plasma exposure or the cesium flux onto the sample is stopped. A minimum work function close to that of bulk cesium was obtained under the influence of the plasma exposition, while a significantly higher work function was observed under ITER-like vacuum conditions.

Work function measurements during plasma exposition at conditions relevant in negative ion sources for the ITER neutral beam injection

Caesium (Cs) is applied in high power negative hydrogen ion sources to reduce a converter surface's work function and thus enabling an efficient negative ion surface formation. Inherent drawbacks with the usage of this reactive alkali metal motivate the search for Cs-free alternative materials for neutral beam injection systems in fusion research. In view of a future DEMOnstration power plant, a suitable material should provide a high negative ion formation efficiency and comply with the RAMI issues of the system: reliability, availability, maintainability, inspectability. Promising candidates, like low work function materials (molybdenum doped with lanthanum (MoLa) and LaB6), as well as different non-doped and boron-doped diamond samples were investigated in this context at identical and ion source relevant parameters at the laboratory experiment HOMER. Negative ion densities were measured above the samples by means of laser photodetachment and compared with two reference cases: pure negative ion volume formation with negative ion densities of about and the effect of H− surface production using an in situ caesiated stainless steel sample which yields 2.5 times higher densities. Compared to pure volume production, none of the diamond samples did exhibit a measurable increase in H− densities, while showing clear indications of plasma-induced erosion. In contrast, both MoLa and LaB6 produced systematically higher densities (MoLa: ×1.60; LaB6: ×1.43). The difference to caesiation can be attributed to the higher work functions of MoLa and LaB6 which are expected to be about 3 eV for both compared to 2.1 eV of a caesiated surface.

https://iopscience.iop.org/article/10.1088/1361-6587/aa7120/pdf

Investigations on Cs-free alternatives for negative ion formation in a low pressure hydrogen discharge at ion source relevant parameters

Synthesis and characterization of lanthanum oxide nanoparticles from thermolysis of nanostructured supramolecular compound

Properties of RE–W cathode and its application in electrostatic precipitation for high temperature gas clean-up

We adopted high-resolution transmission electron microscopy (TEM) and scanning electron microscopy (SAM) to observe and analyze the microstructure of rare earth oxide (La2O3, Sc2O3) doped molybdenum cathodes. The results show that there are many nanometer particles in the molybdenum matrix besides some sub-micrometer particles in the crystal interfaces. All these particles are rare earth oxides as determined through calculating the electron diffraction pattern. Then we determined the electron work function and the zero-field emission current of molybdenum cathodes by the electron emission measurement. To correlate the emission data with surface composition, we use Auger electron spectroscopy (AES) to analyze the elements on the activated cathode surface and their depth profiles. We found that there were about 20 nm thick layers on an activated cathode surface, which have a high content of rare earth elements. We also use AES to analyze the elements diffusion to the cathode surface from cathode body during heating up to its operating temperature to find out which element positively affects the electron emission.

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Papers

Microstructure and emission ability of rare earth oxides doped molybdenum cathodes

Emission ability of La–Sc–Mo cathode

Study on morphology and chemical states of surface active layer of Ce-W cathode