Journal•ISSN: 0196-4313
Industrial & Engineering Chemistry Fundamentals
American Chemical Society
About: Industrial & Engineering Chemistry Fundamentals is an academic journal. The journal publishes majorly in the area(s): Diffusion (business) & Adsorption. It has an ISSN identifier of 0196-4313. Over the lifetime, 2258 publications have been published receiving 78691 citations.
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TL;DR: In this paper, the attractive pressure term of the semi-empirical van der Waals equation has been modified for predicting the vapor pressure and volumetric behavior of singie-component systems.
Abstract: The development of a new two-constant equation of state in which the attractive pressure term of the semiempirical van der Waals equation has been modified is outlined. Examples of the use of the equation for predicting the vapor pressure and volumetric behavior of singie-component systems, and the phase behavior and volumetric behavior of binary, ternary, and multicomponent systems are given. The proposed equation combines simplicity and accuracy. It performs as well as or better than the Soave-Redlich-Kwong equation in all cases tested and shows its greatest advantages in the prediction of liquid phase densities.
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