Showing papers in "Open Geosciences in 2010"

Pedo-geochemical baseline content levels and soil quality reference values of trace elements in soils from the Mediterranean (Castilla La Mancha, Spain)

Abstract: To evaluate trace element soil contamination, geochemical baseline contents and reference values need to be established. Pedo-geochemical baseline levels of trace elements in 72 soil samples of 24 soil profiles from the Mediterranean, Castilla La Mancha, are assessed and soil quality reference values are calculated. Reference value contents (in mg kg−1) were: Sc 50.8; V 123.2; Cr 113.4; Co 20.8; Ni 42.6; Cu 27.0; Zn 86.5; Ga 26.7; Ge 1.3; As 16.7; Se 1.4; Br 20.1; Rb 234.7; Sr 1868.4; Y 38.3; Zr 413.1; Nb 18.7; Mo 2.0; Ag 7.8; Cd 4.4; Sn 8.7; Sb 5.7; I 25.4; Cs 14.2; Ba 1049.3; La 348.4; Ce 97.9; Nd 40.1; Sm 10.7; Yb 4.2; Hf 10.0; Ta 4.0; W 5.5; Tl 2.3; Pb 44.2; Bi 2.2; Th 21.6; U 10.3. The contents obtained for some elements are below or close to the detection limit: Co, Ge, Se, Mo, Ag, Cd, Sb, Yb, Hf, Ta, W, Tl and Bi. The element content ranges (the maximum value minus the minimum value) are: Sc 55.0, V 196.0, Cr 346.0, Co 64.4, Ni 188.7, Cu 49.5, Zn 102.3, Ga 28.7, Ge 1.5, As 26.4, Se 0.9, Br 33.0 Rb 432.7, Sr 3372.6, Y 39.8, Zr 523.2, Nb 59.7, Mo 3.9, Ag 10.1, Cd 1.8, Sn 75.2, Sb 9.9, I 68.0, Cs 17.6, Ba 1394.9, La 51.3, Ce 93.5, Nd 52.5, Sm 11.2, Yb 4.2, Hf 11.3, Ta 6.3, W 5.2, Tl 2.1, Pb 96.4, Bi 3.0, Th 24.4, U 16.4 (in mg kg−1). The spatial distribution of the elements was affected mainly by the nature of the bedrock and by pedological processes. The upper limit of expected background variation for each trace element in the soil is documented, as is its range as a criterion for evaluating which sites may require decontamination.

Volcanic glass textures, shape characteristics and compositions of phreatomagmatic rock units from the Western Hungarian monogenetic volcanic fields and their implications for magma fragmentation

Abstract: The majority of the Mio-Pleistocene monogenetic volcanoes in Western Hungary had, at least in their initial eruptive phase, phreatomagmatic eruptions that produced pyroclastic deposits rich in volcanic glass shards. Electron microprobe studies on fresh samples of volcanic glass from the pyroclastic deposits revealed a primarily tephritic composition. A shape analysis of the volcanic glass shards indicated that the fine-ash fractions of the phreatomagmatic material fragmented in a brittle fashion. In general, the glass shards are blocky in shape, low in vesicularity, and have a low-to-moderate microlite content. The glass-shape analysis was supplemented by fractal dimension calculations of the glassy pyroclasts. The fractal dimensions of the glass shards range from 1.06802 to 1.50088, with an average value of 1.237072876, based on fractal dimension tests of 157 individual glass shards. The average and mean fractal-dimension values are similar to the theoretical Koch-flake (snowflake) value of 1.262, suggesting that the majority of the glass shards are bulky with complex boundaries. Light-microscopy and backscattered-electron-microscopy images confirm that the glass shards are typically bulky with fractured and complex particle outlines and low vesicularity; features that are observed in glass shards generated in either a laboratory setting or naturally through the interaction of hot melt and external water. Textural features identified in fine- and coarse-ash particles suggest that they were formed by brittle fragmentation both at the hot melt-water interface (forming active particles) as well as in the vicinity of the interaction interface. Brittle fragmentation may have occurred when hot melt rapidly penetrated abundant water-rich zones causing the melt to cool rapidly and rupture explosively.

Fluvial stacking due to plate collision and uplift during the Early Pleistocene in Cyprus

Abstract: Southern Cyprus is situated within a mosaic terrane that has been fragmented between the northward drifting African and Arabian plates and the Eurasian plate. Enormous uplift of the earth mantle in the Troodos Mountains is explained by two models. The subduction model explains subduction along the Cyprean arc to be the driving force for uplift whereas after the restraining bend model westward squeezing of Cyprus along strike-slip faulting is responsible for the enormous uplift at restraining bends. Since its emergence as an island in early Miocene times, landscape formation on Cyprus has been strongly controlled by this uplift. Until the Plio-Pleistocene, a strait belt separated the southern unroofed ophiolitic core region-the Troodos Mountains-from the folded Kyrenia range to the north. This former sea basin, nowadays the Mesaoria Basin, is linked with the Troodos Mountains by a dissected glacis with a thick cover of river deposits. The highest and oldest river deposits (Apalos Formation) were studied in the Vlokkaria hill southwest of Lefkosia. The 45.5 m thick Apalos Formation of Early Pleistocene age exhibits 24 sedimentary units (Fluviatile Series). Their magnetostratigraphical characters align with the Matuyama chron including the Olduvai and Jaramillo subchrons thus comprising about 1.15 Ma within the Early Pleistocene. This fluvial stack indicates a very flat and deeply lying river environment flowing from a slowly uplifting Troodos hinterland. It happened during the end of Early Pleistocene when the enhanced Troodos uplift started the dissection of the stacked river plain.

The INQUA Loess Commission as a Central European Enterprise

Abstract: The International Union of Quaternary Research (INQUA) organized the study and consideration of the Quaternary Period (the last 2.6 million years in Earth’s history) via a set of commissions, sub-commissions, working groups, projects and programmes. One of the most successful and best records was the Loess Commission (LC) which functioned assub-commission and then commission from 1961 to 2003, resulting in 40 years of useful activity. The history of the LC can be divided into three phases: 1, from 1961–1977 when the President was Julius Fink; 2, from 1977–1991, with President Marton Pecsi; 3, from 1991–2003 with Presidents An Zhi-Sheng and Ian Smalley. Fink, from Vienna, and Pecsi, from Budapest, gave the LC a distinctly Central European aspect. The nature of loess in Central Europe influenced the nature of the LC but the settings for phases 1 and 2 were quite distinct. Phase 1 was a small scale academic operation, carried out in German. As phase 2 began in 1977 the scope expanded and Central Europe became a base for worldwide loess studies. where the LC language changed to English. Phase 2 was run from a National Geographical Institute and demonstrated a different approach to loess research, although the basic programmes of continent-wide mapping and stratigraphy remained the same. The Commission benefited from this change of style and emphasis. In phase 3 the administration moved away from Central Europe but the Finkian ethos remained solid.

Spectral source parameters for weak local earthquakes in the Pannonian basin

Abstract: Dynamic source parameters are estimated from P-wave displacement spectra for 18 local earthquakes (1.2 < ML < 3.7) that occurred in two seismically active regions of Hungary between 1995 and 2004. Although the geological setting of the two areas is quite different, their source parameters cannot be distinguished. The source dimensions range from 200 to 900 m, the seismic moment from 6.3x1011 to 3.48×1014 Nm, the stress drop from 0.13 to 6.86 bar, and the average displacement is less than 1 cm for all events. The scaling relationship between seismic moment and stress drop indicates a decrease in stress drop with decreasing seismic moment. A linear relationship of Mw = 0.71 ML + 0.92 is obtained between local magnitude and moment magnitude.

The thickest and the most complete loess sequence in the Carpathian basin: the borehole Udvari-2A

Abstract: The key geological borehole Udvari-2A is located in Hungary at the Tolna Hegyhat Hills, in the central part of the Carpathian basin. Its detailed interpretation yielded valuable information on the stratigraphy and the post-Pannonian continental sedimentation regime of this territory. Stratigraphic data provided by the borehole facilitated the drawing up of a more precise picture on the post-Pannonian paleoenvironment and history of the evolution of the area. The borehole cut a thick series of the post-Pannonian Tengelic formation and the overlying, presumably complete sequence of the continental loess sediments of this region. The magnetostratigraphic correlation indicates that the 97 m thick loess sequence in the borehole Udvari-2A is the thickest and most complete so far recorded in Hungary and the deposition of loess started approximately at 1.1 Ma. In this sequence each of the four separable sedimentary periods of the loess are represented by distinct sediments. A theoretical stratigraphic column is also outlined to describe the Paks Loess Formation using data from the SE Transdanubia, defining and characterizing its lithological units. Since the formation is widely known, it was possible to correlate the most complete loess sequence in the Carpathian basin with the Marine Isotope Stages, and this opens up new opportunities for global correlation.

Is Efate (Vanuatu, SW Pacific) a result of subaerial or submarine eruption? An alternative model for the 1 Ma Efate Pumice Formation

Abstract: The Efate Pumice Formation (EPF) is a trachydacitic volcaniclastic succession widespread in the central part of Efate Island and also present on Hat and Lelepa islands to the north The volcanic succession has been inferred to result from a major, entirely subaqueous explosive event north of Efate Island The accumulated pumice-rich units were previously interpreted to be subaqueous pyroclastic density current deposits on the basis of their bedding, componentry and stratigraphic characteristics Here we suggest an alternative eruptive scenario for this widespread succession The major part of the EPF is distributed in central Efate, where pumiceous pyroclastic rock units several hundred meters thick are found within fault scarp cliffs elevated about 800 m above sea level The basal 200 m of the pumiceous succession is composed of massive to weakly bedded pumiceous lapilli units, each 2-3 m thick This succession is interbedded with wavy, undulatory and dune bedded pumiceous ash and fine lapilli units with characteristics of co-ignimbrite surges and ground surges The presence of the surge beds implies that the intervening units comprise a subaerial ignimbrite-dominated succession There are no sedimentary indicators in the basal units examined that are consistent with water-supported transportation and/or deposition The subaerial ignimbrite sequence of the EPF is overlain by a shallow marine volcaniclastic Rentanbau Tuffs The EPF is topped by reef limestone, which presumably preserved the underlying EPF from erosion We here propose that the EPF was formed by a combination of initial subaerial ignimbrite-forming eruptions, followed by caldera subsidence The upper volcaniclastic successions in our model represent intra-caldera pumiceous volcaniclastic deposits accumulated in a shallow marine environment in the resultant caldera The present day elevated position of the succession is a result of a combination of possible caldera resurgence and ongoing arc-related uplift in the region

Trace element behaviour during interaction between basalt and crustal rocks at 0.5-0.8 GPa: an experimental approach

Abstract: We experimentally investigate the major and trace elements behavior during the interaction between two partially molten crustal rocks (meta-anorthosite and metapelite) and a basaltic melt at 0.5–0.8 GPa. Results show that a hybrid melt is formed at the basalt-crust contact, where plagioclase crystallizes. This contact layer is enriched in trace elements which are incompatible with plagioclase crystals. Under these conditions, the trace element diffusion coefficients are one order of magnitude larger than those expected. Moreover, the HFSE diffusivity in the hybrid melt is surprisingly higher than the REE one. Such a feature is related to the plagioclase crystallization that changes the trace elements liquid-liquid partitioning (i.e. diffusivity) over a transient equilibrium that will persist as long as the crystal growth proceeds. These experiments suggests that the behaviour of the trace elements is strongly dependent on the crystallization at the magma-crust interface. Diffusive processes like those investigated can be invoked to explain some unusual chemical features of contaminated magmatic suites.

The Western Pacific Working Group of the INQUA Loess Commission: expansion from Central Europe

Abstract: The INQUA Loess Commission expanded from its Central European base after the 1977 INQUA Congress. The first, furthest, and probably most successful expansion was the Western Pacific Working Group(WPWG). Co-operative loess research between China, Australia and New Zealand demonstrated the ideal working of a dedicated research group within the INQUA protocols. The WPWG functioned from 1978 to about 1988, a critical ten years during which China re-appeared on the world loess scene. The WPWG meeting in China in 1985 was a useful precursor to the INQUA Congress in Beijing in 1991. The main function of the WPWG turned out to be facilitating the return of China to the world of loess scholarship.

Andesites as Magmatic Liquids or Liquid-crystal Mixtures; Insights from Egmont and Ruapehu Volcanoes, New Zealand Research Article

Abstract: Late Quaternary andesitic magmas in New Zealand contain complexly zoned antecrysts and glomerocrysts that are not in equilibrium with either the host whole rock compositions or siliceous groundmass glass and glass inclusions. Glass inclusions represent partial melts of mafic to gabbroic cumulates in the lower crust that mix with restite crystals, or cumulates from earlier magma batches. Assimilation of partial melts of mid-crustal rocks, represented by glass in crustal xenoliths, contributes a crustal component to the andesites. Magmas at Egmont are stored at about the brittle/ductile transition at about 10 km depth and variability in the composition of erupted material is a function of the composition of the recharging magma, and which parts of the storage system are tapped during the eruption. At Taranaki recharge occurs on a c. 1400 year cycle while interactions within the storage give rise to shorter period events. A similar process on a less well constrained timescale operates at Ruapehu. Andesites are therefore complex mixtures of fractionated mantle basalts, siliceous partial melts of both the lower crust and underplated cumulates, restite and cumulate crystals. Further modification occurs by interaction with partial melts of lower to middle crustal basement as geotherms increase with time.