Showing papers in "Tribology Letters in 2023"

Tribological Performance of Gd-DLC and Eu-DLC Coatings in the Presence of Synthetic Oils Containing Ionic Liquid Additives

Abstract: Abstract The lubrication of gadolinium-doped diamond-like carbon (Gd-DLC) and europium-doped diamond-like carbon (Eu-DLC) coatings with trihexyltetradecylphosphonium bis(2-ethylhexyl) phosphate ([P 66614 ][DEHP]) ionic liquid (IL) as 1 wt% additive in polyalphaolefin (PAO) 8 was studied. The results of the friction tests under boundary lubrication conditions showed that Gd-DLC and Eu-DLC coatings in the presence of the IL exhibit a friction reduction, especially with the high atomic concentration of doped metal. Later, the surface observation after the long-term wear test indicated that Gd-DLC coatings have less abrasive wear and higher anti-wear properties compared to Eu-DLC coatings due to the enhanced formation of tribofilms derived from the phosphorus of the IL on the steel ball as the counter body. From these results, we have concluded that the friction reduction and the anti-wear property in the presence of the IL can be improved by changing the type and the concentration of the doped metals. This clearly shows that the novel lubrication system combining the Gd-DLC and Eu-DLC coatings with the IL allows for guiding future research and development. Graphical abstract

Molecular Dynamics Simulations of the Interaction Between Graphene and Lubricating Oil Molecules

Abstract: The microscopic interaction between graphene and liquid lubricating oil molecules significantly affects the rheological and tribological properties of the solid–liquid lubricating system. In this study, the interaction between graphene and six kinds of alkane oil droplets with different chain lengths was investigated by molecular dynamics simulations. Interaction energy, atomic concentration distribution, mean square distribution, curvature, centroid, and inclination angle were used to quantitatively describe the effect of interaction differences on lubricating performance. The results demonstrated that with the increase of the carbon chain length, the alkane molecules transformed from a spherical oil droplet model to an ordered layered structure. At the same time, the interaction energy and the angle with the Z coordinate axis were further increased. The self-diffusion movement and the degree of molecular bending were reduced during the interaction, indicating that long-chain alkane molecules interact strongly with graphene, and a dense multilayer adsorption film was formed by horizontal adsorption on the surface of graphene, thus exerting a good lubricating effect. In addition, it was found that the increase in temperature was beneficial to the occurrence of the adsorption process, but high temperature is not conducive to the stable adsorption of alkane molecules on the surface of graphene.

On the Use of Surface Roughness Parameters

Abstract: Abstract In most practical applications, surface roughness is characterized by just one or two parameters (numbers). I show that the standard maximum surface height parameters fluctuate strongly between different surface realizations (or measurements), and should not be used in the design of engineering components. I show how some roughness parameters depend on the size of the roll-off region in the surface roughness power spectra, and introduce a new height parameter which is very reproducible. The numerical results presented agree well with experimental observations. Graphical Abstract

Formation of Wear-Protective Tribofilms on Different Steel Surfaces During Lubricated Sliding

Abstract: We report here the impact of different alloying elements in steels on friction and wear behavior by performing ball-on-flat lubricated reciprocating tribotesting experiments on 52100 ball on steel flats with different compositions (52100, 1045, A2, D2, M2, and a specialty Cu-alloyed steel) heat-treated to give similar hardness and microstructure, with polyalphaolefin (PAO-4) as the lubricant. There are small variations of coefficient of friction among these alloys. The major observation is that steels containing high concentrations (≥ 10 wt%) of Cr, Mo, and V gave rise to markedly reduced wear compared with 52100 or plain carbon steels. D2 steel, which contains 11.5 wt% Cr as the major alloying element was the most wear-resistant. The wear resistance is strongly correlated with the efficiency of formation of carbon-containing oligomeric films at specimen surfaces as determined by Raman spectroscopy. This correlation holds for steels heat-treated to have higher hardness and with n-dodecane, a much less viscous lubricant compared with PAO-4. Given the strong affinity of chromium to oxygen, chromium should exist as Cr2O3 at the steel surfaces during testing. We have performed molecular dynamics simulation on Cr2O3 and demonstrated its ability to catalyze the formation of carbon-containing oligomeric films from hydrocarbon molecules, consistent with its known catalytic activity in other hydrocarbon reactions. We believe that chromium-containing alloys, such as D2, and coatings, such as CrN, derive their wear resistance in part from the efficient in situ formation of wear-protective carbon tribofilms at contacting asperities.

The Role of Fragility in Thermal Elastohydrodynamics

Abstract: Temperature primarily influences thermal elastohydrodynamic lubrication (TEHL) through the temperature dependence of the viscosity of the liquid. The pressure and temperature dependences of viscosity increase rapidly as the glassy state is approached from the liquid state, a property known as fragility. The glass temperature increases with pressure and reaches to ordinary temperatures at TEHL pressures. Most TEHL analyses have ignored fragility by utilizing a viscosity correlation incapable of describing this behavior. Here, a low-viscosity, fragile oil is characterized for low-shear viscosity to 1.6 GPa and TEHL line contact simulations show, not only a substantial effect on friction, but also significant differences in minimum film thickness when fragility is not ignored, as is customary in classical TEHL. The influence on friction manifests even under moderate load and speed conditions, while that on film thickness seems to be restricted to high loads.

Surface Roughness-Induced Stress Concentration

Abstract: Abstract When a body is exposed to external forces large local stresses may occur at the surface because of surface roughness. Surface stress concentration is important for many application and in particular for fatigue due to pulsating external forces. For randomly rough surfaces, I calculate the probability distribution of surface stress in response to a uniform external tensile stress with the displacement vector field parallel to the rough surface. I present numerical simulation results for the stress distribution $$\sigma (x,y)$$ σ ( x , y ) and show that in a typical case the maximum local tensile stress may be $$\sim 10$$ ∼ 10 times bigger than the applied stress. I discuss the role of the stress concentration on plastic deformation and surface crack generation and propagation. Graphical Abstract

A Novel Geometry Optimization Approach for Multi-Recess Hydrostatic Bearing Pad Operating in Static and low-Speed Conditions Using CFD Simulation

Abstract: Abstract The design of a hydrostatic bearing pad is limited to simple geometry using analytical equations or one-parameter optimization based on experimental data. This study proposes and investigates a new two-parameter method for estimating optimal hydrostatic bearing pad proportions—recess area and position, using Computational Fluid Dynamics (CFD). In this study, 3D static CFD quarter model of a multi-recess hydrostatic bearing pad assuming laminar flow is used. The CFD model was calibrated based on experimentally obtained results and the literature. The recess pressure and resulting load are evaluated for a variety of recess positions and areas. Performance factors are calculated and interpolated in the MATLAB environment. Using the proposed novel two-parameter optimization, the energetic loss was reduced by 20% compared to the classical one-parameter approach. This methodology allows versatile and effective design of optimal hydrostatic bearings operating in low-speed conditions to achieve minimum energetic loss.

Linking Molecular Structure and Lubrication Mechanisms in Tetraalkylammonium Orthoborate Ionic Liquids

Abstract: While ionic liquids (ILs) have gained wide interest as potential alternative lubricants able to meet the requirements of next-generation tribological systems owing to their unique physico-chemical properties and promising lubricating behavior, our understanding of the mechanisms by which ILs reduce friction and/or wear is still elusive. Here, we combine macroscale tribological experiments with surface-analytical measurements to shed light on the lubrication mechanisms of a class of halogen-free ILs, namely tetraalkylammonium orthoborate ILs, at steel/steel sliding contacts. The tribological results indicate an improvement of the friction-reducing properties of these ILs as the length of the alkyl chains attached to ammonium cations increases. X-ray photoelectron spectroscopy analyses provide further evidence for the dependence of the lubrication mechanism of tetraalkylammonium orthoborate ILs on the IL structure. In the case of tetraalkylammonium orthoborate ILs with asymmetric ammonium cations containing a long alkyl chain, no sacrificial tribofilms were formed on steel surfaces, thus suggesting that the friction-reducing ability of these ILs originates from their propensity to undergo a pressure-induced morphological change at the sliding interface that leads to the generation of a lubricious, solid-like layered structure. Conversely, the higher friction response observed in tribological tests performed with tetraalkylammonium orthoborate ILs containing more symmetric ammonium cations and short alkyl chains is proposed to be due to the inability of this IL to create a transient interfacial layer owing to the reduced van der Waals interactions between the cationic alkyl chains. The resulting hard/hard contact between the sliding surfaces is proposed to lead to the cleavage of boron-oxygen bonds in the presence of water to form species that then adsorb onto the steel surface, including trivalent borate esters and oxalic acid from the decomposition of orthoborate anions, as well as tertiary amines from the degradation of alkylammonium cations induced by hydroxides released during the orthoborate decomposition reaction. The results of this work not only establish links between the molecular structure of a class of halogen-free ILs, their lubricating performance, and lubrication mechanism, but also provide evidence for the existence of multiple mechanisms underpinning the promising lubricating properties of ILs in general.

Wear Reduction via CNT Coatings in Electrical Contacts Subjected to Fretting

Abstract: Abstract Carbon nanotubes (CNT) are of great interest to the research community due to their outstanding mechanical, transport, and optical properties. These nanoparticles have also shown exceptional lubricating capabilities, which coupled with their electrical conductivity show promising results as solid lubricants in electrical contacts. In this study, three different CNT coatings were deposited over copper platelets via electrophoretic deposition and subsequently tribo-electrically characterized including electrical contact resistance evolution during fretting wear, wear protection, chemical analysis of fretting marks, as well as influence of CNT coating thickness, duration and normal load applied during fretting, and atmospheric humidity. Thicker CNT coatings show improved wear protection while retaining similar electrical behavior as uncoated copper, or even improving its electrical contact resistance. Moreover, the compaction of the porous CNT coating is crucial for optimal electrical performance at low humidity. For longer fretting tests (150,000 and 500,000 cycles), the coatings are displaced thus affecting the wear protection offered. However, the coatings stabilize and reduce ECR compared to uncoated samples. Furthermore, thicker CNT coatings can bear higher loads during fretting due to the increased lubricant reservoir, with carbonaceous tribofilm remaining at the contacting interface after 5,000 fretting cycles regardless of normal load. Graphical Abstract

Molecular Structure and Environment Dependence of Shear-Driven Chemical Reactions: Tribopolymerization of Methylcyclopentane, Cyclohexane and Cyclohexene on Stainless Steel

Abstract: Tribochemistry, which is another name for mechanochemistry driven by shear, deals with complex and dynamic interfacial processes that can lead to surface wear or formation of beneficial tribofilms. For better mechanistic understanding of these processes, we investigated the reactivity of tribopolymerization of organic molecules with different internal ring strain (methylcyclopentane, cyclohexane, and cyclohexene) on a stainless steel (SS) surface in inert (N2), oxidizing (O2), and reducing (H2) environments at room temperature. On the clean stainless steel surface, precursor molecules were found to physisorb with a broad range of molecular orientations. In inert and reducing environments, the strain-free cyclohexane showed the lowest tribochemical activity among the three molecules tested. Compared to the N2 environment, the tribochemical activity in H2 was suppressed. In the O2 environment, only cyclohexene produced tribofilms and methylcyclopentane while cyclohexane did not. When tribofilms were analyzed with Raman spectroscopy, the spectral features of diamond-like carbon (DLC) or amorphous carbon (a-C) were observed due to photochemical degradation of triboproducts. Based on infrared spectroscopy, tribofilms were found to be organic polymers containing oxygenated groups. Whenever polymeric tribrofilms were produced, wear volume was suppressed by orders of magnitudes but not completely to zero. These results support previously suggested mechanisms which involve surface oxygen as a reactant species in the tribopolymerization process.

Analyzing Ball Bearing Capacitance Using Single Steel Ball Bearings

Abstract: Abstract A precise modeling of the capacitance of rolling element bearings is of increasing significance over the last years, e.g. in the context of bearing damage estimation in electric drives. The complexity of a steel bearing as an electrical network makes reliable validation of calculation models under realistic operating conditions nearly impossible. A way to reduce complexity in yet realistic conditions is the use of hybrid bearings with a single steel rolling element. This helps to measure only one current path through the bearing at a time and thus, gives a much clearer picture of the contact capacitance of rolling elements in and out of the load zone. The usage of different materials comes with different thermal expansion coefficients and different elasticities, which cause a significant change in load distribution. For the first time, this work considers both of these effects in calculation and validates them with corresponding experiments using single steel ball bearings.

Multiple Scratching: An Atomistic Study

Abstract: Abstract Using molecular dynamics simulation, we investigate multiple scratching processes in which a tip moves through a groove that has already been formed during a previous scratch. We use a conical indenter such that the friction coefficient is independent of the scratch depth. First, a single scratch to a depth of 4 nm is compared with a 2-cycle scratch in which a scratch at depth 2 nm is followed by a second scratch to the full depth of 4 nm. We observe that the second cycle shows a smaller friction coefficient as long as the tip moves through the pre-formed groove without touching the front end. In addition, we studied 5 cycles of scratching, in which the scratch depth was increased by 2 nm in each cycle. These results confirm and generalize the findings for the 2-cycle scratch. A constant-load 2-cycle scratch simulation emphasizes that the reduction in transverse load—and, consequently, in the friction coefficient—is caused by the fact that, despite a large normal area supporting the normal load, only a thin area is available to resist the transverse movement of the scratch tip. The work done during scratching is in good approximation proportional to the scratch volume showing that the transverse hardness is approximately constant in all scratch processes investigated here.

In situ Growth and Characterization of Lubricious Carbon-Based Films Using Colloidal Probe Microscopy

Abstract: Silicon oxide-doped hydrogenated amorphous carbon (a-C:H:Si:O) is an important form of diamond-like carbon (DLC) for tribological applications, primarily because of its enhanced thermal stability and reduced dependence of friction on environmental humidity. As with other DLCs, its mechanisms of lubrication are still an active area of research, though it is now known that surface passivation and tribofilm growth are important factors. In this study, tribofilm formation for a-C:H:Si:O is examined at the microscale by using steel colloid atomic force microscopy probes as the sliding counterface. This approach provides some inherent advantages over macroscale tribology experiments, namely that the tribofilm thickness and stiffness can be tracked in situ and correlated directly with the friction response. The results of these experiments show that the tribofilm grows rapidly on the steel colloid following a period of counterface wear and high friction. The friction drops more than 80% upon nucleation of the tribofilm, which is attributed to a decrease of more than 80% in adhesion combined with a decrease in the estimated interfacial shear strength of at least 65%. Approximately 80% of the friction decrease occurs before the tribofilm reaches a thickness of 2 nm, suggesting that only the near-surface properties of the tribofilm provide the needed functionality for its effective lubrication mechanisms.

Leakage Threshold of a Saddle Point

Abstract: Abstract The threshold condition for leakage inception is of great interest to many engineering applications, and it is essential for seal design. In the current study, the leakage threshold is studied by means of a numerical method for a mechanical contact problem between an elastic bi-sinusoidal surface and a rigid flat surface. The coalesce process of the contact patches is first investigated, and a generalized form of solution for the relation between the contact area ratio and the average applied pressure is acquired. The current study shows that the critical value of the average applied pressure and the corresponding contact area required to close the percolation path can be represented as a power law of a shape parameter, if the effect of the hydrostatic load from the pressurized fluid is ignored. With contact patches merged under a constant applied load, the contact breakup process is investigated with elevated sealed fluid pressure condition, and it is shown that the leakage threshold is a function of the excess pressure, which is defined as a ratio between the average applied pressure and the critical pressure under dry contact conditions. Graphical abstract