Journal ArticleDOI
954. Chlorine-activation by redox-transfer. Part IV. The addition of sulphonyl chlorides to vinylic monomers and other olefins
M. Asscher,D. Vofsi +1 more
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This article is published in Journal of The Chemical Society (resumed).The article was published on 1964-01-01. It has received 82 citations till now. The article focuses on the topics: Redox & Chlorine.read more
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Journal ArticleDOI
Single-Electron Transfer and Single-Electron Transfer Degenerative Chain Transfer Living Radical Polymerization
Brad M. Rosen,Virgil Percec +1 more
TL;DR: In this article, the authors present the latest progress in two related polymerization methodologies that rely on singleelectron transfer (SET), single-electron-transfer degenerative chain transfer living radical polymerization (SET-DTLRP), and single-Electron Transfer Living Radical Poly(SET-LRP) for the synthesis of tailored polymers.
PatentDOI
Electrochemically mediated atom transfer radical polymerization
Krzysztof Matyjaszewski,Nicola Bortolamei,Andrew J. D. Magenau,Armando Gennaro,Abdirisak Ahmed Isse +4 more
TL;DR: In this article, the reduction of an ATRP catalyst, C 11 Br 2 /Me 6 TREN, is shown to be an efficient process to mediate and execute an AT RP.
Patent
Novel (co)polymers and a novel polymerization process based on atom (or group) transfer radical polymerization
TL;DR: In this paper, a new polymerization process (atom transfer radical polymerization, or ATRP) based on a redox reaction between a transition metal (e.g., Cu(I)/Cu(II)) provides "living" or controlled radical polymerisation of styrene, (meth)acrylates, and other radically polymerizable monomers.
Patent
Improved processes based on atom (or group) transfer radical polymerization and novel (co)polymers having useful structures and properties
Krzysztof Matyjaszewski,Simion Coca,Scott G. Gaynor,Dorota Greszta,Timothy E. Patten,Jin-Shan Wang,Jianhui Xia +6 more
TL;DR: Improved processes for atom (or group) transfer radical polymerization (ATRP) and novel polymers have been developed and described in this paper, where novel copolymers comprising a least one polymeric branch or polymeric block with a predominantly alternating monomer sequence are described.
Patent
Preparation of novel homo- and copolymers using atom transfer radical polymerization
TL;DR: In this paper, an initiating system consisting of an initiator having a radically transferrable atom or group, a transition metal compound, and a ligand was proposed for the synthesis of a block or graft copolymer.
Related Papers (5)
Living radical polymerization of styrene initiated by arenesulfonyl chlorides and CuI(bpy)nCl
Virgil Percec,Bogdan Barboiu +1 more