Journal ArticleDOI
A new, stereocontrolled synthesis of cis,anti,cis-tricyclo[6.3.0.02,6]undecanes. Total synthesis of (.+-.)-hirsutene
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This article is published in Journal of the American Chemical Society.The article was published on 1979-09-01. It has received 51 citations till now. The article focuses on the topics: Total synthesis.read more
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Photochemical reactions as key steps in natural product synthesis
Thorsten Bach,Jörg P. Hehn +1 more
TL;DR: The most important photochemical transformations that have been employed in natural product synthesis are presented and selected total syntheses are discussed as examples, with particular attention given to the photochemical key step and its stereoselectivity.
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Synthesis of Polyquinane Natural Products: An Update.
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Modern methods for the radical deoxygenation of alcohols
TL;DR: In this article, the authors propose the generation of an intermediaire radicalaire par transfert d'electron, which is based on Desoxygenation photolytique.
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Dicobaltoctacarbonyl-alkyne complexes as intermediates in the synthesis of bicyclo[3.3.0]octenones for the synthesis of coriolin and hirsutic acid
TL;DR: In this article, a mechanistic hypothesis to explain the observed stereospecificity is presented, which is suitable for straightforward elaboration into coriolin and hirsutic acid precursors.
Journal ArticleDOI
Photochemische Reaktionen als Schlüsselschritte in der Naturstoffsynthese
Thorsten Bach,Jörg P. Hehn +1 more
TL;DR: In this article, die wichtigsten Umsetzungen der photochemie vorgestellt, die auf breiter Front Einzug in die Naturstoffsynthese gehalten haben.