Journal ArticleDOI
Abnormal, mesoionic and remote N-heterocyclic carbene complexes
TLDR
In this paper, three structural classes of NHC ligands can be distinguished: normal (nNHC), abnormal (aNHC) and mesoionic (MIC), and remote (rNHC).About:
This article is published in Coordination Chemistry Reviews.The article was published on 2013-02-01. It has received 470 citations till now. The article focuses on the topics: Mesoionic.read more
Citations
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Artificial photosynthesis: molecular systems for catalytic water oxidation.
Journal ArticleDOI
Molecular Catalysts for Water Oxidation
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Beyond click chemistry - supramolecular interactions of 1,2,3-triazoles.
TL;DR: The intention of this review is to provide a detailed analysis of the various supramolecular interactions of triazoles in comparison to established functional units, which may serve as guidelines for further applications.
Journal ArticleDOI
NHCs in Main Group Chemistry.
Vitaly Nesterov,Dominik Reiter,Prasenjit Bag,Philipp Frisch,Richard Holzner,Amelie Porzelt,Shigeyoshi Inoue +6 more
TL;DR: A general overview of the chemistry of low-coordinate main group element compounds, basic synthetic approaches, key features of NHC-main group element adducts, and might be useful for the broad research community are given.
References
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N-heterocyclic carbenes: a new concept in organometallic catalysis.
TL;DR: N-Heterocyclic carbenes have become universal ligands in organometallic and inorganic coordination chemistry as mentioned in this paper, and they not only bind to any transition metal, be it in low or high oxidation states, but also to main group elements such as beryllium, sulfur, and iodine.
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N-Heterocyclic Carbenes in Late Transition Metal Catalysis
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Heterocyclic Carbenes: Synthesis and Coordination Chemistry
TL;DR: New methods for the synthesis of complexes with N-heterocyclic carbene ligands such as the oxidative addition or the metal atom template controlled cyclized isocyanides have been developed recently.
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N-Heterocyclic Carbenes†‡
TL;DR: The chemistry of N-heterocyclic carbenes has long been limited to metal coordination compounds derived from azolium precursors, a development that was started by Ofele and Wanzlick in 1968 as discussed by the authors.
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The Measure of All Rings—N‐Heterocyclic Carbenes
Thomas Dröge,Frank Glorius +1 more
TL;DR: Physicochemical data (electronics, sterics, bond strength) of NHCs that are essential for the design, application, and mechanistic understanding of N-Heterocyclic carbenes in catalysis are provided.