Journal ArticleDOI
Alkyl iodide decomposition on copper surfaces: .alpha.-elimination and .beta.-hydride elimination from adsorbed alkyls
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This article is published in Journal of the American Chemical Society.The article was published on 1991-07-01. It has received 51 citations till now. The article focuses on the topics: Beta-Hydride elimination & Iodide.read more
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Mimicking Aspects of Heterogeneous Catalysis: Generating, Isolating, and Reacting Proposed Surface Intermediates on Single Crystals in Vacuum.
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Preparation and reactivity of alkyl groups adsorbed on metal surfaces
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Probing catalytic reactions at surfaces
TL;DR: A review of the major contributions from modern surface science to the understanding of the chemistry of heterogeneous catalysis is provided in this article, where a number of basic concepts, including the nature of surface bonds, the dynamics of surface reactions, and the identification of the intermediates and elemental steps that comprise the catalytic processes, are surveyed.
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Organometallic chemistry and surface science: mechanistic models for the Fischer–Tropsch synthesis
TL;DR: A review of the mechanisms for the Fischer-Tropsch synthesis and the evidence for these mechanisms is presented in this article, where it is generally accepted that the reaction may be viewed as a polymerisation of surface methylene (CH2) species, which are formed by the dissociation and hydrogenation of CO on the catalyst surface.