Journal ArticleDOI
Allyl sulfones as synthons for 1,1- and 1,3-dipoles via organopalladium chemistry
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This article is published in Journal of the American Chemical Society.The article was published on 1980-08-01. It has received 122 citations till now. The article focuses on the topics: Organopalladium.read more
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Selectivity in palladium catalysed allylic substitution
TL;DR: Palladium catalysed allylic substitution has emerged as one of the more useful synthetic methods for the construction of C-C and C-X bonds as mentioned in this paper, which offers the advantages of mild reaction conditions, as well as the ability to accomodate a wide range of nucleophiles and their electrophilic partners.
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New general synthetic methods involving π-allylpalladium complexes as intermediates and neutral reaction conditions
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Evolving organic synthesis fostered by the pluripotent phenylsulfone moiety.
TL;DR: A comprehensive program for the synthesis of natural (or unnatural) products is analogous to the construction of a pyramid, where careful planning followed by installation of numerous levels of support are required to complete the edifice.
Journal ArticleDOI
Chemical Chameleons. Organosulfones as Synthetic Building Blocks
TL;DR: An overview of the duality of function of organosulfones as nucleophiles in basic media and electrophiles in Lewis acidic media, a change of reactivity for which they have been dubbed "chemical chameleons" is presented in this article.