Journal ArticleDOI
An electron spin resonance study of the radical anions of two dimethylcyclooctatetraenes
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This article is published in Journal of the American Chemical Society.The article was published on 1976-12-01. It has received 4 citations till now. The article focuses on the topics: Electron paramagnetic resonance.read more
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Isotope Effects on the Ring Inversion of Cyclooctatetraene
TL;DR: In this paper, it was shown that there is an inverse isotope effect on the rate of ring inversion of kH/kD = 0.68−0.57 in the temperature range from −10 to −50 °C.
Journal ArticleDOI
Alkoxycyclooctatetraene Anion Radicals: An Unusual Spin Density Perturbation Due to 1,3-Carbon/Carbon Interactions
TL;DR: In this article, a series of new alkoxycyclooctatetraene ethers was synthesized and their anion radicals generated in hexamethylphosphoramide.
Journal ArticleDOI
Unexpected rearrangements induced by the metal cation in the reduction of cycloocta[b]naphthalene with alkali metals in ethers. An EPR and ENDOR study
TL;DR: A set of structurally different radicals has been detected by EPR in the reduction of cycloocta[b] naphthalene (1) by potassium in 1,2-dimethoxyethane as mentioned in this paper.