Calixarenes with diphenylphosphoryl acetamide functions at the upper rim. A new class of highly efficient extractants for lanthanides and actinides

TLDR: In this article, various calixarene tetraalkyl ethers and a calix[4]arene pentaalkyl- ether substituted at the upper rim by the CMPO-like functional group were synthesized for the first time and their ability to extract europium, thorium, neptunium, plutonium and americium from aqueous HNO3 into methylene chloride or o-nitrophenyl hexyl ether was studied under various conditions.

Abstract: Various calix[4]arene tetraalkyl ethers and a calix[5]arene pentaalkyl ether substituted at the upper rim by the CMPO-like functional group –NH–C(O)–CH2–P(O)Ph2 as well as some linear model compounds have been synthesized for the first time. Their ability to extract europium, thorium, neptunium, plutonium and americium from 1 mol dm–3 aqueous HNO3 into methylene chloride or o-nitrophenyl hexyl ether was studied under various conditions. All the new oligomeric ligands, but especially the calixarene derivatives, are tremendously strong extractants compared with the commonly used CMPO [(N,N-diisobutylcarbamoylmethyl)octylphenylphosphine oxide]. Also in transport studies through supported liquid membranes their efficiency is higher than that of CMPO which shows lower transport rates even at a 10-fold concentration.