Journal ArticleDOI
Carbonyl fluoride of molybdenum
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This article is published in Inorganic Chemistry.The article was published on 1970-11-01. It has received 8 citations till now. The article focuses on the topics: Carbonyl metallurgy & Carbonyl fluoride.read more
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Reactions of arenetricarbonyl-group vib metals with halide and pseudohalide ion̈s
James F. White,Michael F. Farona +1 more
TL;DR: In this paper, a variety of compounds of general formula (R 4 N) 3 [(CO) 3 MX 3 M(CO)3 ](M = Cr, Mo, W; X = F, Cl, Br, I, OH, SCN, N 3, OC 2 H 5 ) were prepared from tetraalkylammonium halide.
Journal ArticleDOI
The preparation of some group VI fluorometal carbonyl derivatives
W.M. Douglas,J. K. Ruff +1 more
TL;DR: In this article, it has been found that fluoride ion can behave as a ligand towards the Group VI metal carbonyls, and the anions Cr(CO) 5 F − and W( CO) 5F − were isolated and characterized.
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Synthesis and Structure of [{Mo(CO)(4)}(2)(cis-m-F(2)SbF(4))(3)](x)()[Sb(2)F(11)](x)(): An Ionic Coordination Polymer.
Raimund Bröchler,Daniel Freidank,Matthias Bodenbinder,Iona H. T. Sham,Helge Willner,Steven J. Rettig,James Trotter,Friedhelm Aubke +7 more
TL;DR: The oxidation of molybdenum hexacarbonyl, Mo(CO)(6), by antimony(V) fluoride, SbF(5), at 60 degrees C in an excess of liquid SbFs, produces polymeric polymeric cation, which is suitable for a single-crystal X-ray diffraction study.
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U2O3F6—Its preparation and properties
TL;DR: The compound U2O3F6 was prepared by thermal decomposition of UOF4 at 290°C and on heating to 380°C it decomposes into UO2F2 and UF6 through a one-step process as mentioned in this paper.
Journal ArticleDOI
Carbonyl fluorides of manganese
TL;DR: The first carbonyl fluorides of manganese Mn(CO) 3 F 3 and [Mn(CO 4 F] 2 have been prepared by treating Mn( CO) 5 Br with AgF as mentioned in this paper.