Journal ArticleDOI
Catalytic oxidation: I. The oxidation of ethylene over Pd and PdAu alloys
TLDR
The gross kinetics for the oxidation of ethylene were determined over Pd and PdAu alloys in a steady-state flow reactor and in a recirculating reactor in which the products were stripped with each pass as mentioned in this paper.About:
This article is published in Journal of Catalysis.The article was published on 1970-02-01. It has received 48 citations till now. The article focuses on the topics: Partial oxidation & Ethylene oxide.read more
Citations
More filters
Journal ArticleDOI
The oxidation of CO and hydrocarbons over noble metal catalysts
TL;DR: In this paper, the authors studied the reaction kinetics of CO, C 3 H 6, 1-hexene, and toluene under excess O 2 and found that the olefin oxidation is strongly self-inhibited by HC and more than first-order in O 2, whereas the opposite was found for Rh.
Journal ArticleDOI
Selectivity in catalysis by alloys
TL;DR: The first period of growing interest was in the thirties when alloys were used to disclose the role of the order-disorder phenomena (see, e.g., Ref. as discussed by the authors ).
Book ChapterDOI
Compensation Effect in Heterogeneous Catalysis
TL;DR: The compensation effect remains largely an empirical method of classifying kinetic observations and this has not been developed into a theoretical representation capable of predicting activities and patterns of reactivity in hitherto untested catalytic processes.
Journal ArticleDOI
Chemical state and reactivity of supported palladium: I. Characterization by XPS and uv-visible spectroscopy
TL;DR: In this article, the chemical state and environment of palladium supported on silica, titania, and alumina have been studied by uv-visible and X-ray photoelectron spectroscopy.
Journal ArticleDOI
The Structure and Catalytic Properties of Palladium-Silver and Palladium-Gold Alloys
E. G. Allison,G. C. Bond +1 more
TL;DR: In this paper, a review of the catalytic activities of the Group VIII and the Group IB alloys is presented, focusing on Pt-Au and Pt-Ag alloys, both of which have miscibility gaps.
References
More filters
Journal ArticleDOI
The Effect of Surface Coverage on the Spectra of Chemisorbed CO.
Journal ArticleDOI
Lattice spacings of gold–palladium alloys
Journal ArticleDOI
Catalytic oxidation. II. Silica supported noble metals for the oxidation of ethylene and propylene
Noel W. Cant,W.Keith Hall +1 more
TL;DR: In this paper, the catalytic properties of C2H4 and C3H6 were investigated over silica-supported Pt, Pd, Ir, Ru, Ru and Rh.
Related Papers (5)
Infrared spectra of carbon monoxide adsorbed on supported palladium and palladium-silver alloys
Y. Soma-Noto,W.M.H. Sachtler +1 more