Journal ArticleDOI
Development of an in-line rheometer suitable for reactive extrusion processes
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TLDR
In this paper, an in-line extrusion rheometer based on the flow of polymer through a wedge (vertically tapered slit) is presented, which is suitable for measuring changes in rheological properties on-line during reactive extrusion, because it can be used to estimate the viscosity for a range of shear rates without the need to change the polymer flow rate.Abstract:
This paper presents the development of a novel in-line extrusion rheometer based on the flow of polymer through a wedge (vertically tapered slit). This rheometer is suitable for measuring changes in rheological properties on-line during reactive extrusion, because it can be used to estimate the viscosity for a range of shear rates without the need to change the polymer flow rate (i.e., extruder throughput). Equations have been developed to estimate the parameters of the power-law equation, used to describe the viscosity-shear rate relationship, from measurements of pressure drops along the wedge. An experimental in-line wedge rheometer has been built and used to measure the viscosity for a series of polypropylenes prepared via reactive extrusion. Viscosity measurements from the experimental in-line wedge rheometer are compared with measurements from a capillary rheometer. Good agreement is found between the capillary and wedge rheometer measurements.read more
Citations
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In-process vibrational spectroscopy and ultrasound measurements in polymer melt extrusion
TL;DR: In this paper, an exploration of the application and assessment of sensitivity of in-process vibrational spectroscopy -on-line mid-infrared (MIR), on-line near infrared (NIR), in-line NIR and inline Raman -for monitoring of single screw extrusion of high-density polyethylene and polypropylene blends is reported.
Journal ArticleDOI
Reactive Processing of Thermoplastic Polymers: A Review of the Fundamental Aspects
TL;DR: In this paper, a review of the state of the art in the domains of rheology, diffusion and mixing in highly viscous reactive or non-reactive media is presented, and 1, 2 and 3-D simulation of the reactive extrusion process in twin-screw extruder is reported.
Journal ArticleDOI
Characterization of thermo-rheological behavior of polymer melts during the micro injection moulding process
Nan Zhang,Michael D. Gilchrist +1 more
TL;DR: In this article, the authors developed an in-line rheology measurement system using a slit die attached to a micro injection molding machine, where a series of dumbbell mold inserts were used to form the slit die with thickness ranging from 600μm to 200μm.
Journal ArticleDOI
Process rheometers for molten plastics: A survey of existing technology
John M. Dealy,Taras O. Broadhead +1 more
TL;DR: A variety of rheological sensors have been described in the patent and research literature, each with its unique advantages and disadvantages, and some of these are finding increased use in the plastics industry to improve product quality and process efficiency as mentioned in this paper.
Journal ArticleDOI
Energy monitoring and quality control of a single screw extruder
Jing Deng,Kang Li,Eileen Harkin-Jones,Mark Price,Nayeem Karnachi,Adrian L. Kelly,Javier Vera-Sorroche,P. D. Coates,E. C. Brown,Minrui Fei +9 more
TL;DR: In this paper, a fuzzy logic controller is developed for a single screw extruder to achieve high melt quality and energy efficiency, without the need to install power meters or develop data-driven models.
References
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Journal ArticleDOI
Production of controlled-rheology polypropylene resins by peroxide promoted degradation during extrusion
TL;DR: In this article, a kinetic model for the peroxide-initiated degradation of polypropylene (PP) is proposed and compared with experimental data for the production of controlled-rheology (CR) resins.
Journal ArticleDOI
Polymer melt rheology with a slit die
TL;DR: In this paper, a piston driven high pressure slit die rheometer with three pressure holes along the die and one in the barrel was used to investigate viscosity, entrance and exit pressure losses.
Journal ArticleDOI
Experimental investigation of the influence of molecular weight distribution on the rheological properties of polypropylene melts
TL;DR: In this article, an experimental study of steady shear and elongational flow properties of polypropylene melts of varying molecular weight and distribution is reported. But the results of this study were limited to a series of polyethylene melts.
Journal ArticleDOI
Effect of molecular weight distribution on the rheological and mechanical properties of polypropylene
TL;DR: In this article, the effect of molecular weight distribution on the rheological and mechanical properties of a series of polypropylenes was evaluated, which were produced by controlled chemical degradation in a single-screw extruder.
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