Journal ArticleDOI
Dilithium derivative of tetraphenylsilole : an eta 1-eta 5 dilithium structure
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This article is published in Journal of the American Chemical Society.The article was published on 1995-11-01. It has received 143 citations till now. The article focuses on the topics: Dilithium & Derivative (chemistry).read more
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Polymer sensors for nitroaromatic explosives detection
Sarah J. Toal,William C. Trogler +1 more
TL;DR: Several polymers have been used to detect nitroaromatic explosives by a variety of transduction schemes as mentioned in this paper, which relies on both electronic and structural interactions between the sensing material and the analyte.
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Detection of nitroaromatic explosives based on photoluminescent polymers containing metalloles.
TL;DR: Fluorescence spectra of polymetalloles or metallole-silane copolymers obtained in either toluene solutions or thin polymer films displayed no shift in the maximum of the emission wavelength, which suggests that the polymetaloles or meetalloles-silanes exhibit neither pi-stacking of polymer chains nor excimer formation.
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Silole-containing σ- and π-conjugated compounds
Shigehiro Yamaguchi,Kohei Tamao +1 more
TL;DR: A series of 2,5- and 1,1-difunctionalized siloles have been prepared based on the intramolecular reductive cyclization of diethynylsilanes as discussed by the authors.
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Detection of TNT and Picric Acid on Surfaces and in Seawater by Using Photoluminescent Polysiloles
TL;DR: Dilute polymer solutions can be employed as a forensic spray-on reagent to visualize TNT or picric acid residues under a UV lamp and the print of a nitrile-gloved hand that had been in contact with TNT is seen.
Journal ArticleDOI
Toward New Materials for Organic Electroluminescent Devices: Synthesis, Structures, and Properties of a Series of 2, 5-Diaryl-3,4-diphenylsiloles
Shigehiro Yamaguchi,Tomonori Endo,Manabu Uchida,Takenori Izumizawa,Kenji Furukawa,Kohei Tamao +5 more
TL;DR: A series of 2,5-diaryl-3,4-diphenylsiloles, with various mono-substituted phenyl groups, extended pi-conjugated groups, and heteroaryl groups as aryl groups at the 2, 5-positions, has been prepared by a one-pot synthesis from bis(phenylethynyl)silanes based on the intramolecular reductive cyclization followed by the palladium-cat