Journal ArticleDOI
Dissociation of state-selected complex ions studied by mass-selective pulsed field threshold ionization spectroscopy
H. Krause,H. J. Neusser +1 more
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TLDR
In this paper, a vibrationally resolved spectrum of the X 2E1g state of the benzene cation was used for exclusive detection of threshold ions with a resolution of <9 cm−1.Abstract:
Pulsed field threshold ionization leads to a vibrationally resolved spectrum of the X 2E1g state of the benzene cation. It is further used to investigate the state‐selective dissociation of the benzene–Ar+ complex. Exclusive detection of threshold ions with a resolution of <9 cm−1 is achieved by kinetic energy analysis in a reflectron mass spectrometer.read more
Citations
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Journal ArticleDOI
Magnitude of the CH/π Interaction in the Gas Phase: Experimental and Theoretical Determination of the Accurate Interaction Energy in Benzene-methane
TL;DR: The accurate CH/pi interaction energy of the benzene-methane model system was experimentally and theoretically determined and accuracy of the calculated interaction energies by DFT methods using BLYP, B3LYP, PW91 and PBE functionals was discussed.
Journal ArticleDOI
Dissociation energy of neutral and ionic benzene‐noble gas dimers by pulsed field threshold ionization spectroscopy
H. Krause,H. J. Neusser +1 more
TL;DR: In this paper, a delayed pulsed field threshold ionization of clusters excited to high long-lived Rydberg states is used to study their dissociation behavior, which leads to an upper limit of the dissociation energy of benzene-Ar of 340 cm−1 which is probably higher than the true dissociation energies.
Journal ArticleDOI
Magnetic ZEKE experiments with mass analysis
TL;DR: In this paper, a magnetic drift tube was used to deflect the direct ions at the start of a drift tube for ZEKE experiments, and the motional field effect was exploited to yield a value for the ionization potential.
Journal ArticleDOI
High n Rydberg spectroscopy of benzene: Dynamics, ionization energy and rotational constants of the cation
TL;DR: In this paper, a high resolution uv-uv double resonance experiment with two Fourier transform limited nanosecond laser pulses high Rydberg states up to n>100 were selectively excited and detected by ionization in a pulsed electric field.
Journal ArticleDOI
Internal conversion in highly excited benzene and benzene dimer: femtosecond time-resolved photoelectron spectroscopy
W. Radloff,V. Stert,Th. Freudenberg,Ingolf V. Hertel,Christophe Jouvet,C. Dedonder-Lardeux,D. Solgadi +6 more
TL;DR: In this paper, the pump-probe technique was combined with the coincidence detection of ions and electrons in the spectra of benzene molecules and dimers excited to the S2 electronic state by 140 fs laser pulses.
References
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Journal ArticleDOI
High-Resolution Zero Kinetic Energy (ZEKE) Photoelectron Spectroscopy of Molecular Systems
K. Muller-Dethlefs,E. W. Schlag +1 more
Journal ArticleDOI
Mass analyzed threshold ionization spectroscopy
Langchi Zhu,Philip J. M. Johnson +1 more
TL;DR: In this paper, a new mass selective method was developed for the determination of the optical spectra of molecular ions and for the production of state selected ions, which can be used for mass selection.
Journal ArticleDOI
The ionization energy of nitric oxide
TL;DR: In this paper, the authors reported the discovery of high-lying, very-long-lived Rydberg states in NO and determined the ionization potential of NO to be 74721.7 ± 0.4 cm−1.
Journal ArticleDOI
Binding energies of small benzene clusters
TL;DR: In this paper, a stable triangular structure for the neutral benzene trimer was established and a sandwich-like structure for trimer ion was shown to have high binding energy in the presence of a delocalized charge.
Journal ArticleDOI
High resolution zero kinetic energy photoelectron spectroscopy of benzene and determination of the ionization potential
TL;DR: In this article, a two-color high-resolution zero kinetic energy photoelectron spectroscopy (ZEKE-PES) method was employed for the determination of the ionization potential of benzene.
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